Investigation on microstructure and oxidation behavior of Cr-modified aluminide coating on γ-TiAl alloys

Microstructure and oxidation behavior of aluminide coating has been investigated. The layers were examined by optical microscopy, scanning electron microscopy (SEM) equipped with EDS and X-ray diffraction method. The isothermal oxidation behaviors of samples were investigated at 950°C for 200 h. The results indicated that TiAl₃ were formed on substrate. In addition, aluminide coating improved the oxidation resistance of γ-TiAl alloys by forming a protective alumina scale. Moreover, during oxidation treatment the interdiffusion of TiAl₃ layer with γ-TiAl substrate results in depletion of aluminum in the TiAl₃ layer and growth of TiAl₂ layer. After oxidation treatment the coating layer maintained a microstructure with phases including TiAl₃, TiAl₂ and Al₂O₃.Досліджено мікроструктуру алюмінідного покриву та його поведінку під час високотемпературного окислення. Шари алюмінідів титану вивчали за допомогою оптичної мікроскопії, сканівної електронної мікроскопії (SЕМ) з використанням дисперсного рентгеноспектрометра (EDS) та рентгенівським дифракційним методом. Випробовування проводили при 950°C впродовж 200 h. Встановлено, що на підкладці з титанового сплаву утворився TiAl₃. Покрив з алюмініду титану покращує стійкість до окислення сплавів з γ-TiAl, утворюючи захисну плівку з оксиду алюмінію. Під час окислення дифузійна взаємодія TiAl₃ з підкладкою γ-TiAl спричиняє зменшення кількості алюмінію у шарі TiAl₃ та збільшення шару TiAl₂. Після окислення в покриві утворюється мікроструктура з фазами, що містять TiAl₃, TiAl₂ та Al₂O₃.Исследовано микроструктуру алюминидного покрытия и его поведение при высокотемпературном окислении. Слои алюминида титана изучали с помощью оптической микроскопии, сканирующей электронной микроскопии (SЕМ) с использованием дисперсного рентгеноспектрометра (EDS) и рентгеновским дифракционным методом. Испытания проводили при 950°C в течение 200 h. Установлено, что на подкладке из титанового сплава образовался TiAl₃. Покрытие из алюминида титана улучшает стойкость к окислению сплавов из γ-TiAl, образовывая защитную пленку из окисла алюминия. Во время окисления диффузионное взаимодействие TiAl₃ с подкладкой γ-TiAl влечет уменьшение количества алюминия в слое TiAl₃ и увеличение слоя TiAl₂. После окисления в покрытии образуется микроструктура с фазами, которые содержат TiAl₃, TiAl₂ и Al₂O₃

Developments in Corrosion Protection

One of the first thing that comes to your mind after hearing the term “corrosion” is corrosion of a metal. Corrosion is a basically harmful phenomenon, but it can be useful in some cases. For instance, environment’s pollution with corrosion products and damage to the performance of a system are among its harmful effects, whereas electric energy generation in a battery and cathodic protection of many structures are among its advantages. However, these advantages are almost nothing as compared to the costs and effects imposed by its detrimental influences. The enormous costs of this phenomenon can be better understand through studying the published statistics on direct and indirect corrosion damages on economy of governments. The direct cost of corrosion is near 3 % of the gross domestic product (GDP) of USA. Considering this huge cost, it is necessary to develop and expand the corrosion science and its protection technologies

EFFECT OF PULSE DUTY CYCLE ON PROPERTIES OF HARD NANOCRYSTALLINE SURFACE FABRICATED BY DUPLEX TREATMENTS

Up to fourth moment distribution of carbide nanocrystallites produced by duplex treatments of surface nanocrystallization and pulsed plasma electrolytic carbonitriding on AISI 1010 mild steel was investigated by the means of figure analysis with high precision. Skewness and kurtosis study of the Gaussian distribution have been studied and the effect of duty cycle of pulsed current has been determined. The usage of lower duty cycles of pulsed current is more suitable for achieving lower sizes of carbide nanocrystallites. Surface roughness of treated samples was measured and it has been observed that there is an optimum level of duty cycle of pulsed current for surface roughness increasing (difference between two measured data).Duty cycle of pulsed current, nanostructures, plasma electrolytic carbonitriding, kurtosis, skewness

Corrosion properties of electrodeposited nanocrystalline and amorphous patterned Ni-W alloy

Nickel-tungsten with satisfactory corrosion properties is a promising alloy to replace hard chromium. Relatively high adhesion between copper substrate and electrodeposited Ni-W alloy results in patterned morphology due to crack formation. In this work, corrosion resistance of patterned Ni-W alloys comprising 0-26 at.%.W were studied by potentiodynamic polarization and EIS in a medium containing Cl-. It is shown that corrosion resistance of single phase Ni-W is superior to amorphous and dual phase coated layers. It is also found that crack density is the dominant affecting factor on corrosion resistance of amorphous Ni-W alloys. (C) 2008 Elsevier Ltd. All rights reserved