Eco-friendly preparation of electrically conductive chitosan - reduced graphene oxide flexible bionanocomposites for food packaging and biological applications

Electrically conductive materials have been highlighted in the biomedical and food packaging areas. Conventional electrically conductive polymers have limited biodegradability and biocompatibility and should be replaced by suitable biomaterials. Herein, electrically conductive bionanocomposites of chitosan and reduced graphene oxide were produced by a green methodology. The reduced graphene oxide was hydrothermally reduced in the presence of caffeic acid and was dispersed into chitosan. The final bionanocomposites achieved an electrical conductivity of 0.7 S/m in-plane and 2.1 × 10−5 S/m through-plane. The reduced graphene oxide promoted a great enhancement of antioxidant activity and a mechanical reinforcement of chitosan matrix, increasing the tensile strength and decreasing the water solubility. The electrical conductivity, mechanical properties and antioxidant activity of the bionanocomposites can be tuned according to the filler content. These active bionanocomposites, prepared using a green methodology, revealed good electrical and mechanical properties, which make them promising materials for food packaging and biological applications.publishe

Mass Flow Monitoring by Distributed Fiber Optical Temperature Sensing

We developed a novel method to monitor mass flow based on distributed fiber optical temperature sensing. Examination of the temporal and spatial temperature distribution along the entire length of a locally heated fluidic conduit reveals heat flow under forced convection. Our experimental results are in good agreement with two-dimensional finite element analysis that couples fluid dynamic and heat transfer equations. Through analysis of the temperature distribution bidirectional flow rates can be measured over three orders of magnitude. The technique is not flow intrusive, works in harsh conditions, including high-temperatures, high pressures, corrosive media, and strong electromagnetic environments. We demonstrate a first experimental implementation on a short fluidic system with a length of one meter. This range covers many applications such as low volume drug delivery, diagnostics, as well as process and automation technology. Yet, the technique can, without restrictions, be applied to long range installations. Existing fiber optics infrastructures, for instance on oil pipelines or down hole installations, would only require the addition of a heat source to enable reliable flow monitoring capability

Fabrication of Optical Fibers with Multiple Coatings for Swelling-Based Chemical Sensing

We discuss distributed chemical sensing based on the swelling of coatings of optical fibers. Volume changes in the coating induce strain in the fiber’s glass core, provoking a local change in the refractive index which is detectable by distributed fiber optical sensing techniques. We describe methods to realize different coatings on a single fiber. Simultaneous detection of swelling processes all along the fiber opens the possibility to interrogate thousands of differently functionalized sections on a single fiber. Principal component analysis is used to enable sensors for environmental monitoring, food analysis, agriculture, water quality monitoring, or medical diagnostics

Realization of a polarization-insensitive optical frequency-domain reflectometer using an I/Q homodyne detection

We report on the development and implementation of an optical frequency-domain reflectometer (OFDR) sensing platform. OFDR allows to measure changes in strain and temperature using optical fibers with a length of several tens of meters with very high spatial resolution. We discuss the operation principles and challenges to implement an OFDR system using optical homodyne detection based on a dual-polarization 90° optical hybrid. Our setup exhibits polarization and phase diversity, fully automated data acquisition and data processing using a LabVIEW-based implemented software environment. Using an optical hybrid enables to discriminate phase, amplitude and polarization by interfering the Rayleigh scatter signal and a local oscillator with four 90° phase stepped interferences between the two signals. Without averaging and a fast acquisition time of 230 ms, our preliminary results show a spatial resolution of 5 cm and a temperature resolution of about 0.1 Kelvin on a 3 m-long fiber

High-Order Polynomial Fitting Assistance for Fast Double-Peak Finding in Brillouin-Distributed Sensing

A high-order polynomial fitting method is proposed to accelerate the computation of double-Gaussian fitting in the retrieval of the Brillouin frequency shifts (BFS) in optical fibers showing two local Brillouin peaks. The method is experimentally validated in a distributed Brillouin sensor under different signal-to noise ratios and realistic spectral scenarios. Results verify that a sixth-order polynomial fitting can provide a reliable initial estimation of the dual local BFS values, which can be subsequently used as initial parameters of a nonlinear double-Gaussian fitting. The method demonstrates a 4.9-fold reduction in the number of iterations required by double-Gaussian fitting and a 3.4-fold improvement in processing time

Swelling-Based Distributed Chemical Sensing with Standard Acrylate Coated Optical Fibers

Distributed chemical sensing is demonstrated using standard acrylate coated optical fibers. Swelling of the polymer coating induces strain in the fiber’s silica core provoking a local refractive index change which is detectable all along an optical fiber by advanced distributed sensing techniques. Thermal effects can be discriminated from strain using uncoated fiber segments, leading to more accurate strain readings. The concept has been validated by measuring strain responses of various aqueous and organic solvents and different chain length alkanes and blends thereof. Although demonstrated on a short range of two meters using optical frequency-domain reflectometry, the technique can be applied to many kilometer-long fiber installations. Low-cost and insensitive to corrosion and electromagnetic radiation, along with the possibility to interrogate thousands of independent measurement points along a single optical fiber, this novel technique is likely to find applications in environmental monitoring, food analysis, agriculture, water quality monitoring, or medical diagnostics

Surface Topography of Si/TiO2 Stacked Layers on Silicon Substrate Deposited by KrF Excimer Laser Ablation

This study investigates the surface topography of the deposited thin films versus the distance between target and substrate (dTS) inside a laser ablation equipment. The profile of the rough surface was obtained by atomic force microscopy data analysis based on power spectral density and the roughness-length scale (RLS) functions. The roughing on the top film is analyzed considering the previous topography of the underneath surface for each consecutive TiO2 and Si deposition onto Si (100) wafer. The buried oxide layer inside of Si/TiO2/c-Si structure, obtained by KrF excimer laser ablation was characterized by complementary techniques as spectral ellipsometry, X-ray reflectometry, and X-ray diffraction