Differences in grain growth of calcite: a field-based modeling approach

Normal grain growth of calcite was investigated by combining grain size analysis of calcite across the contact aureole of the Adamello pluton, and grain growth modeling based on a thermal model of the surroundings of the pluton. In an unbiased model system, i.e., location dependent variations in temperature-time path, 2/3 and 1/3 of grain growth occurs during pro- and retrograde metamorphism at all locations, respectively. In contrast to this idealized situation, in the field example three groups can be distinguished, which are characterized by variations in their grain size versus temperature relationships: Group I occurs at low temperatures and the grain size remains constant because nano-scale second phase particles of organic origin inhibit grain growth in the calcite aggregates under these conditions. In the presence of an aqueous fluid, these second phases decay at a temperature of about 350°C enabling the onset of grain growth in calcite. In the following growth period, fluid-enhanced group II and slower group III growth occurs. For group II a continuous and intense grain size increase with T is typical while the grain growth decreases with T for group III. None of the observed trends correlate with experimentally based grain growth kinetics, probably due to differences between nature and experiment which have not yet been investigated (e.g., porosity, second phases). Therefore, grain growth modeling was used to iteratively improve the correlation between measured and modeled grain sizes by optimizing activation energy (Q), pre-exponential factor (k0) and grain size exponent (n). For n=2, Q of 350kJ/mol, k0 of 1.7×1021μmns−1 and Q of 35kJ/mol, k0 of 2.5×10-5μmns−1 were obtained for group II and III, respectively. With respect to future work, field-data based grain growth modeling might be a promising tool for investigating the influences of secondary effects like porosity and second phases on grain growth in nature, and to unravel differences between nature and experimen

Stability and isotopic dating of monazite and allanite in partially molten rocks: examples from the Central Alps

We investigated the stability of monazite and allanite as a function of bulk rock composition within several types of Tertiary Alpine anatexites, characterized by different compositions and melting reactions, but similar P-T conditions of melting. The investigated rocks consist of: (1) orthogneisses in which the melting reaction was triggered by water infiltration from the Bergell pluton; (2) anatectic tonalites, which were affected by water-assisted melting; and (3) metapelitic migmatites, which underwent muscovite dehydration melting. The studied anatexites cover a large range of Ca contents and water activities during partial melting, and allow an assessment of how much these parameters affect the stability of accessory phases. The different melting reactions that affected these rocks generated different water activities during the melt-present stage; they were highest in the water-saturated, contact metamorphic anatexites, and lowest in the metapelitic anatexites that underwent dehydration melting. These differences go together with different accessory phases within the migmatites. Whereas metapelitic anatexites only contain monazite, anatexites derived from tonalitic and granodioritic protoliths mainly contain allanite. This is consistent with observations made on Tertiary Alpine anatexites, suggesting that the growth of specific accessory phases is determined by the water activity and Ca content during melting. We measured single-grain monazite U/Pb isotope ages. One grain has relics of old cores, which have also been detected in Y-zonation patterns of the monazite. The data of unzoned monazites indicate partial melting in the Southern Steep Belt between 30.78 ± 0.14 and 28.10 ± 0.28M

The composition and evolution of an Oligocene regolith on top of the Sesia-Lanzo Zone (Western Alps)

An Oligocene paleosurface (regolith) lies on top of the high-pressure metamorphic rocks of the Sesia-Lanzo Zone near Biella, NW Italy. Only the saprock, the lowermost part in a regolith profile, is preserved. No evidence for any paleosoil can be observed. Field observations indicate that the regolith developed through in situ mechanical fracturing of the rocks of the Sesia-Lanzo Zone in a continental environment. Density estimations of the regolith and the underlying rocks of the Sesia-Lanzo Zone confirm the field observations and imply that a relatively small amount of alteration minerals was formed. The main detected alteration phases are chlorite, various carbonates, quartz, clay minerals, Fe-oxides, and Fe-hydroxides. Chlorite differing in chemistry and crystallographic ordering demonstrates different stages of alteration. Oxygen and carbon isotopic composition of carbonates suggests temperatures higher than surface conditions. Illite and chlorite thermometry indicates temperatures related to the anchizone (~250-300°C). These data are considered as a robust indication of the re-burial of the regolith together with its substrate and its volcanic cover. The burial is closely related to the tilting of the preserved stratigraphic sequence formed by the rocks of the Sesia-Lanzo Zone, the regolith, and the rocks of the Biella Volcanic Suite (Lanza, in Schweiz Miner Petrogr MItt 57: 281-290, 1977; Lanza, in Geologishe Rundschau 68: 83-92, 1979). Furthermore, the burial is consistent with this sequence of subaerial rocks being very close to the intrusion depth of the Valle del Cervo Pluton at the time of its emplacement (4-7km; Zanoni et al., in Rend Online SGI Note Brevi 1: 199-202, 2008; Zanoni et al., in Int Geol Rev 52: 1244-1267, 2010 and references therein

A new perspective on the significance of the Ranotsara shear zone in Madagascar

The Ranotsara shear zone in Madagascar has been considered in previous studies to be a >350-km-long, intracrustal strike-slip shear zone of Precambrian/Cambrian age. Because of its oblique strike to the east and west coast of Madagascar, the Ranotsara shear zone has been correlated with shear zones in southern India and eastern Africa in Gondwana reconstructions. Our assessment using remote sensing data and field-based investigations, however, reveals that what previously has been interpreted as the Ranotsara shear zone is in fact a composite structure with a ductile deflection zone confined to its central segment and prominent NW-SE trending brittle faulting along most of its length. We therefore prefer the more neutral term "Ranotsara Zone”. Lithologies, tectonic foliations, and axial trace trajectories of major folds can be followed from south to north across most of the Ranotsara Zone and show only a marked deflection along its central segment. The ductile deflection zone is interpreted as a result of E-W indentation of the Antananarivo Block into the less rigid, predominantly metasedimentary rocks of the Southwestern Madagascar Block during a late phase of the Neoproterozoic/Cambrian East African Orogeny (c. 550-520Ma). The Ranotsara Zone shows significant NW-SE striking brittle faulting that reactivates part of the NW-SE striking ductile structures in the flexure zone, but also extends along strike toward the NW and toward the SE. Brittle reactivation of ductile structures along the central segment of the Ranotsara Zone, confirmed by apatite-fission track results, may have led to the formation of a shallow Neogene basin underlying the Ranotsara plain. The present-day drainage pattern suggests on-going normal fault activity along the central segment. The Ranotsara Zone is not a megascale intracrustal strike-slip shear zone that crosscuts the entire basement of southern Madagascar. It can therefore not be used as a piercing point in Gondwana reconstruction

From subduction to collision: Thermal overprint of HP/LT meta-sediments in the north-eastern Lepontine Dome (Swiss Alps) and consequences regarding the tectono-metamorphic evolution of the Alpine orogenic wedge

The Cenozoic-age metamorphic structure of the Alps consists of a throughgoing pressure-dominated belt (blueschists and eclogites) that strikes parallel to the orogen and was later truncated by two thermal domes characterised by Barrow-type metamorphism (Lepontine dome and Tauern window). This study documents for the first time that relics of Fe-Mg carpholite occur also within meta-sedimentary units that are part of the north-eastern Lepontine structural and metamorphic dome, where so far exclusively Barrovian assemblages were found. They occur in meta-sediments of both Valais Oceanderived Lower Penninic Bündnerschiefer and structurally lower Europe-derived Sub-Penninic cover nappes and slices. These high-pressure units were subsequently overprinted by a thermal event, as is documented by the growth of new minerals typical for Barrovian metamorphism. We present evidence for a two-stage metamorphic evolution in the northern part of the Lepontine dome: (1) Early subduction-related syn-D1 (Safien phase) HP/LT metamorphism under blueschist facies conditions (350-400°C and 1.2-1.4 GPa) was immediately followed by "cold” isothermal (or cooling) decompression during D2 nappe-stacking (Ferrera phase). (2) Collisionrelated Barrovian overprint (500-570°C and 0.5-0.8 GPa) postdates the D3 nappe-refolding event (Domleschg phase) and represents a late heating pulse, separated by D2 and D3 from the D1 high-pressure event. It occurred before and/or during the initial stages of D4 (Chiéra phase) representing a second nappe-refolding event. In discussing possible heat sources for the late Barrow-type heating pulse it is argued that heat release from radioactive decay of accreted material may play an important role in contributing much to heat production. Based on the field evidence, we conclude that heat transfer was essentially conductive during these latest stages of the thermal evolutio

The role of the Ranotsara Zone in southern Madagascar for Gondwana correlations

The Precambrian basement of southern Madagascar was reworked at high-grade metamorphic conditions during the East African Orogen (EAO of Stern, 1994) that formed during assembly of Gondwana in late Neoproterozoic/early Paleozoic times. At the end of the EAO, Madagascar is generally thought to be sandwiched between southern India and eastern Africa. Constraints on its paleoposition are often inferred from similarities in structural features on now dispersed continental fragments, in particular high-strain zones. Major zones with (sub)vertical foliation planes can be traced over hundreds of kilometres in southern Madagascar and have been interpreted as major vertical ductile shear zones (e.g. Windley et al. 1994; Martelat, 1998). The NW–SE trending Ranotsara Zone (dashed rectangle in Fig. 1) is regarded as an intracrustal mega strike-slip shear zone with a sinistral sense of shear that formed at the end of the Proterozoic (e.g. Nicollet, 1990; de Wit et al., 2001). A large number of studies have used the Ranotsara Zone to propose Gondwana reconstructions. The Ranotsara Zone has been correlated with various ductile shear zones in southern India, e.g. with the Bhavani Shear Zone or the Moyar Shear Zone (Katz & Premoli, 1979), the Palghat-Cauvery Shear Zone (de Wit et al., 1995), the Karur-Kamban- Painavum-Trichur Shear Zone (de Wit et al., 2001; Ghosh et al. 2004) or with the Achankovil Shear Zone (Windley et al., 1994; Martelat, 1998). Within Madagascar, the Ranotsara Zone has been correlated along strike with the more N–S trending Bongolava Zone in central-western Madagascar (Hottin 1976), and the Bongolava- Ranotsara Zone has been further traced into the Surma Shear Zone (Windley et al. 1994) and its along-strike continuation, the Aswa Shear Zone in eastern Africa (Müller 2000). Chetty (2003) suggested that the Ranotsara Zone is not only a mega shear zone, but also a terrane boundary separating a region with Archean crust to the north from a region with Neoproterozoic crust to the south. Our remote sensing and field studies of southern Madagascar indicate that the Ranotsara Zone is neither a major terrane boundary nor an intracrustal mega strike-slip shear zone and therefore can not be used as a ‘piercing point’ in Gondwana reconstructions...conferenc

Protracted fluid-induced melting during Barrovian metamorphism in the Central Alps

The timing and dynamics of fluid-induced melting in the typical Barrovian sequence of the Central Alps has been investigated using zircon chronology and trace element composition. Multiple zircon domains in leucosomes and country rocks yield U-Pb ages spanning from ∼32 to 22 Ma. The zircon formed during Alpine melting can be distinguished from the inherited and detrital cores on the basis of their age, Th/U (<0.1) and trace element composition. Ti-in-zircon thermometry indicates crystallization temperatures around 620-700°C. Their composition allows discriminating between (1) zircon formation in the presence of early garnet, (2) zircon in equilibrium with abundant L-MREE-rich accessory phases (allanite, titanite and apatite) typical of metatonalites, and (3) zircon formed during melting of metasediments in feldspar-dominated assemblages. The distribution of zircon overgrowths and ages indicate that repeated melting events occurred within a single Barrovian metamorphic cycle at roughly constant temperature; that in the country rocks zircon formation was limited to the initial stages of melting, whereas further melting concentrated in the segregated leucosomes; that melting occurred at different times in samples a few meters apart because of the local rock composition and localized influx of the fluids; and that leucosomes were repeatedly melted when fluids became available. The geochronological data force a revision of the temperature-time path of the migmatite belt in the Central Alps. Protracted melting over 10 My followed the fast exhumation of Alpine eclogites contained within the same region and preceded fast cooling in the order of 100°C/Ma to upper crustal levels

Tracing wedge-internal deformation by means of strontium isotope systematics of vein carbonates

Radiogenic strontium isotopes (87Sr/86Sr) of vein carbonates play a central role in the tectonometamorphic study of fold-and-thrust belts and accretionary wedges and have been used to document fluid sources and fluxes, for example, along major fault zones. In addition, the 87Sr/86Sr ratios of vein carbonates can trace the diagenetic to metamorphic evolution of pore fluids in accreted sediments. Here we present 87Sr/86Sr ratios of vein carbonates from the Infrahelvetic flysch units of the central European Alps (Glarus Alps, Switzerland), which were accreted to the North Alpine fold-and-thrust belt during the early stages of continental collision. We show that the vein carbonates trace the Sr isotopic evolution of pore fluids from an initial seawater-like signature towards the Sr isotopic composition of the host rock with increasing metamorphic grade. This relationship reflects the progressive equilibration of the pore fluid with the host rock and allows us to constrain the diagenetic to low-grade metamorphic conditions of deformation events, including bedding-parallel shearing, imbricate thrusting, folding, cleavage development, tectonic mélange formation and extension. The strontium isotope systematics of vein carbonates provides new insights into the prograde to early retrograde tectonic evolution of the Alpine fold-and-thrust belt and helps to understand the relative timing of deformation events. © The Author(s), 2022. Published by Cambridge University Press

Tracing wedge-internal deformation by means of strontium isotope systematics of vein carbonates

Radiogenic strontium isotopes (87Sr/86Sr) of vein carbonates play a central role in the tectonometamorphic study of fold-and-thrust belts and accretionary wedges and have been used to document fluid sources and fluxes, for example, along major fault zones. In addition, the 87Sr/86Sr ratios of vein carbonates can trace the diagenetic to metamorphic evolution of pore fluids in accreted sediments. Here we present 87Sr/86Sr ratios of vein carbonates from the Infrahelvetic flysch units of the central European Alps (Glarus Alps, Switzerland), which were accreted to the North Alpine fold-and-thrust belt during the early stages of continental collision. We show that the vein carbonates trace the Sr isotopic evolution of pore fluids from an initial seawater-like signature towards the Sr isotopic composition of the host rock with increasing metamorphic grade. This relationship reflects the progressive equilibration of the pore fluid with the host rock and allows us to constrain the diagenetic to low-grade metamorphic conditions of deformation events, including bedding-parallel shearing, imbricate thrusting, folding, cleavage development, tectonic mélange formation and extension. The strontium isotope systematics of vein carbonates provides new insights into the prograde to early retrograde tectonic evolution of the Alpine fold-and-thrust belt and helps to understand the relative timing of deformation events