37 research outputs found
Will spin-relaxation times in molecular magnets permit quantum information processing?
Using X-band pulsed electron spin resonance, we report the intrinsic
spin-lattice () and phase coherence () relaxation times in molecular
nanomagnets for the first time. In Cr heterometallic wheels, with = Ni
and Mn, phase coherence relaxation is dominated by the coupling of the electron
spin to protons within the molecule. In deuterated samples reaches 3
s at low temperatures, which is several orders of magnitude longer than
the duration of spin manipulations, satisfying a prerequisite for the
deployment of molecular nanomagnets in quantum information applications.Comment: 4 pages, 3 figures, in press at Physical Review Letter
Measuring errors in single qubit rotations by pulsed electron paramagnetic resonance
The ability to measure and reduce systematic errors in single-qubit logic
gates is crucial when evaluating quantum computing implementations. We describe
pulsed electron paramagnetic resonance (EPR) sequences that can be used to
measure precisely even small systematic errors in rotations of
electron-spin-based qubits. Using these sequences we obtain values for errors
in rotation angle and axis for single-qubit rotations using a commercial EPR
spectrometer. We conclude that errors in qubit operations by pulsed EPR are not
limiting factors in the implementation of electron-spin based quantum
computers
High Fidelity Single Qubit Operations using Pulsed EPR
Systematic errors in spin rotation operations using simple RF pulses place
severe limitations on the usefulness of the pulsed magnetic resonance methods
in quantum computing applications. In particular, the fidelity of quantum logic
operations performed on electron spin qubits falls well below the threshold for
the application of quantum algorithms. Using three independent techniques, we
demonstrate the use of composite pulses to improve this fidelity by several
orders of magnitude. The observed high-fidelity operations are limited by pulse
phase errors, but nevertheless fall within the limits required for the
application of quantum error correction.Comment: 4 pages, 3 figures To appear in Phys. Rev. Let
Stark Tuning of Donor Electron Spins in Silicon
We report Stark shift measurements for 121Sb donor electron spins in silicon
using pulsed electron spin resonance. Interdigitated metal gates on top of a
Sb-implanted 28Si epi-layer are used to apply electric fields. Two Stark
effects are resolved: a decrease of the hyperfine coupling between electron and
nuclear spins of the donor and a decrease in electron Zeeman g-factor. The
hyperfine term prevails at X-band magnetic fields of 0.35T, while the g-factor
term is expected to dominate at higher magnetic fields. A significant linear
Stark effect is also resolved presumably arising from strain.Comment: 10 pages, 4 figures, to be submitted to PR
Electron spin relaxation of N@C60 in CS2
We examine the temperature dependence of the relaxation times of the
molecules N@C60 and N@C70 (which comprise atomic nitrogen trapped within a
carbon cage) in liquid CS2 solution. The results are inconsistent with the
fluctuating zero field splitting (ZFS) mechanism, which is commonly invoked to
explain electron spin relaxation for S > 1/2 spins in liquid solution, and is
the mechanism postulated in the literature for these systems. Instead, we find
a clear Arrhenius temperature dependence for N@C60, indicating the spin
relaxation is driven primarily by an Orbach process. For the asymmetric N@C70
molecule, which has a permanent non-zero ZFS, we resolve an additional
relaxation mechanism caused by the rapid reorientation of its ZFS. We also
report the longest coherence time (T2) ever observed for a molecular electron
spin, being 0.25 ms at 170K.Comment: 6 pages, 6 figures V2: Updated to published versio
Coherent state transfer between an electron- and nuclear spin in 15N@C60
Electron spin qubits in molecular systems offer high reproducibility and the
ability to self assemble into larger architectures. However, interactions
between neighbouring qubits are 'always-on' and although the electron spin
coherence times can be several hundred microseconds, these are still much
shorter than typical times for nuclear spins. Here we implement an
electron-nuclear hybrid scheme which uses coherent transfer between electron
and nuclear spin degrees of freedom in order to both controllably turn on/off
dipolar interactions between neighbouring spins and benefit from the long
nuclear spin decoherence times (T2n). We transfer qubit states between the
electron and 15N nuclear spin in 15N@C60 with a two-way process fidelity of
88%, using a series of tuned microwave and radiofrequency pulses and measure a
nuclear spin coherence lifetime of over 100 ms.Comment: 5 pages, 3 figures with supplementary material (8 pages