18 research outputs found
New Avenue for Appendage of Graphene Quantum Dots on Halloysite Nanotubes as Anode Materials for High Performance Supercapacitors
Graphene
quantum dots (GQDs) are a newly developed graphene family with good
electrical conductivity and high theoretical capacitance, while halloysite
nanotubes (HNTs) are naturally occurring layered mineral materials
containing high active sites for energy storage support. The combination
of HNTs and GQDs can offer a new strategy on the fabrication of eco-friendly
electrode materials for high performance supercapacitor applications.
Herein, an environmentally friendly GQD-HNT nanocomposite is fabricated
in the presence of (3-aminopropyl)-triethoxysilane to provide increased
charge storage sites as well as to allow for the fast charge transport
for supercapacitor application. Morphological and surface analytical
results show that 5–10 nm GQDs are homogeneously distributed
on the surface of APTES-coated HNTs via amide linkage. This new and
novel layered nanocomposite can provide accessible electroactive sites
and low resistance to accelerate the electrons and electrolyte ion
transport, resulting in excellent specific capacitance and high energy
density. The specific capacitances of 363–216 F/g at current
densities of 0.5–20 A/g are obtained. In addition, the GQD-HNTs
exhibit excellent energy density of 30–50 Wh/kg. Results obtained
in this study clearly demonstrate the feasibility of using GQD-HNTs
as alternative energy storage materials with increased charge storage
sites and fast charge transport for high energy density supercapacitor
applications
N‑Doped Graphene Quantum Dots-Decorated V<sub>2</sub>O<sub>5</sub> Nanosheet for Fluorescence Turn Off–On Detection of Cysteine
The
development of a fast-response sensing technique for detection of
cysteine can provide an analytical platform for prescreening of disease.
Herein, we have developed a fluorescence turn off–on fluorescence
sensing platform by combining nitrogen-doped graphene quantum dots
(N-GQDs) with V<sub>2</sub>O<sub>5</sub> nanosheets for the sensitive
and selective detection of cysteine in human serum samples. V<sub>2</sub>O<sub>5</sub> nanosheets with 2–4 layers are successfully
synthesized via a simple and scalable liquid exfoliation method and
then deposited with 2–8 nm of N-GQDs as the fluorescence turn
off–on nanoprobe for effective detection of cysteine in human
serum samples. The V<sub>2</sub>O<sub>5</sub> nanosheets serve as
both fluorescence quencher and cysteine recognizer in the sensing
platform. The fluorescence intensity of N-GQDs with quantum yield
of 0.34 can be quenched after attachment onto V<sub>2</sub>O<sub>5</sub> nanosheets. The addition of cysteine triggers the reduction of V<sub>2</sub>O<sub>5</sub> to V<sup>4+</sup> as well as the release of
N-GQDs within 4 min, resulting in the recovery of fluorescence intensity
for the turn off–on detection of cysteine. The sensing platform
exhibits a two-stage linear response to cysteine in the concentration
range of 0.1–15 and 15–125 μM at pH 6.5, and the
limit of detection is 50 nM. The fluorescence response of N-GQD@V<sub>2</sub>O<sub>5</sub> exhibits high selectivity toward cysteine over
other 22 electrolytes and biomolecules. Moreover, this promising platform
is successfully applied in detection of cysteine in human serum samples
with excellent recovery of (95 ± 3.8) – (108 ± 2.4)%.
These results clearly demonstrate a newly developed redox reaction-based
nanosensing platform using N-GQD@V<sub>2</sub>O<sub>5</sub> nanocomposites
as the sensing probe for cysteine-associated disease monitoring and
diagnosis in biomedical applications, which can open an avenue for
the development of high performance and robust sensing probes to detect
organic metabolites