29,567 research outputs found

    Coherent States for Generalized Laguerre Functions

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    We explicitly construct a Hamiltonian whose exact eigenfunctions are the generalized Laguerre functions. Moreover, we present the related raising and lowering operators. We investigate the corresponding coherent states by adopting the Gazeau-Klauder approach, where resolution of unity and overlapping properties are examined. Coherent states are found to be similar to those found for a particle trapped in a P\"oschl-Teller potential of the trigonometric type. Some comparisons with Barut-Girardello and Klauder-Perelomov methods are noticed.Comment: 12 pages, clarifications and references added, misprints correcte

    Structural, spectral studies and catalytic activity of copper (II) complex of valine-containing polymer

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    A new copper complex of valine-containing polymer was prepared to mimic an active site center in the metalloenzymes. The valine containing polymer VPAV was prepared by modifying the vinyl pyridine-acrylamide copolymer. The polymer VPAV was investigated using IR, 1H-nmr, and thermal analysis then, the structure was proposed based on the theoretical calculation. The copper complex CuII-VPAV was fully characterized by means of different physicochemical methods such as IR, electronic spectroscopy, EPR and thermal analysis. The catalyst CuII-VPAV was used in the oxidation of poly phenol trihydroxybenzene in the presence and absence of H2O2. The catalysis shows a catalytic efficiency of 1.2 × 104 times in terms of first-order rate constant relative to auto-oxidation of the substrates in an aqueous environment in the presence of H2O2 and under mild conditions. Key words; valine; copolymer; oxidation; polyphenol; modifyin

    Dynamics of plasma blobs in a shear flow

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    The global dynamic of plasma blobs in a shear flow is investigated in a simple magnetized torus using the spatial Fourier harmonics (k-space) framework. Direct experimental evidence of a linear drift in k space of the density fluctuation energy synchronized with blob events is presented. During this drift, an increase of the fluctuation energy and a production of the kinetic energy associated with blobs are observed. The energy source of the blob is analyzed using an advection-dissipation-type equation that includes blob-flow exchange energy, linear drift in k space, nonlinear processes, and viscous dissipations. We show that blobs tap their energy from the dominant E B vertical background flow during the linear drift stage. The exchange of energy is unidirectional as there is no evidence that blobs return energy to the flow

    Hydraulic and Electrokinetic Delivery of Remediants for In-situ Remediation

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    Nano-scale zero valent iron (nZVI) has shown promising mobility and in-situ reactivity with chlorinated volatile organic compounds when injected into saturated porous media. The current study evaluated nZVI mobility and subsequent reactivity with in-situ contaminants in a variably saturated porous media. The nZVI particles, synthesized onsite at subzero temperatures, demonstrated complete trichloroethene (TCE) degradation within the target area. Furthermore, a three dimensional finite difference model (CompSim) was utilized to investigate nZVI mobility in variably saturated zones. Model predicted well head data were in very good agreement with field observations. Simulation results showed that the injected slurry migrated radially outward from the injection well and that nZVI travel distance increases were not proportional to the increase in injected nZVI volume. This study suggested that the numerical simulator can be a practical tool for optimal design of nZVI field applications. The second study aimed at alleviating back diffusion from low permeability porous media observed at numerous field studies. Experiments were conducted in a two-dimensional sandbox with alternate vertical layers of coarse sand and silt flooded with TCE at aqueous solubility. Electrokinetics (EK) was used to enhance permanganate delivery through the silt layers. The suite of experiments demonstrated that EK was able to drive more permanganate at a faster rate throughout the silt layers in comparison to no-EK experiments. The combined EK and permanganate application resulted in 4.4 orders of magnitude reduction in TCE concentrations compared to a 3.5 orders of magnitude reduction without EK application. This experiment demonstrated that EK coupled with permanganate application can be used to remediate low permeability strata. The third study investigated a novel approach of EK assisted persulfate delivery followed by electrical resistance heating (ERH) for persulfate activation for low permeability soil remediation. The study showed that EK delivered persulfate throughout the silt. The application of ERH was successfully able to activate the persulfate within the porous matrix leading to complete in-situ tetrachlorothene (PCE) degradation. To the authors’ knowledge, this study was the first to combine EK and ERH for persulfate delivery and activation for low permeability soil remediation

    Effectiveness of percutaneous nephrostomy in reversing obstructive renal failure

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    A retrospective analysis of 34 patients of obstructive renal failure, initially managed by percutaneous nephrostomy was performed. Pre procedure blood biochemical profile was compared with upto one week follow-up of blood chemistry. There was a decline of 71.1% and 56.08% (P-values 0.0001 and 0.0028) in the mean values of serum creatinine and blood urea nitrogen respectively at 7 days after the procedure. Improvement in blood biochemical profile was solely dependent on performance of percutaneous nephrostomy
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