An evaluation of halitosis using Oral Chroma Data Manager, organoleptic scores and patients' subjective opinions

BACKGROUND: Halitosis or breath odor, is defined as an unpleasant or offensive odor emanating from the mouth. Three forms are distinguished: genuine halitosis, pseudohalitosis and halitophobia. The source of 85% of all cases of halitosis lies in the oral cavity. According to the literature, between 10% and 50% of the population suffers from halitosis. The objective of this study was to provide an assessment of halitosis using an organoleptic method, Oral Chroma™ Data Manager and patients’ subjective assessments of their condition. MATERIALS AND METHODS: A total of 30 adult patients took part in the study. The patients were examined by a trained and licensed dentist. An organoleptic assessment was made of a patient’s breath (scale 0-5) and a test performed on air samples from the oral cavity using the Oral Chroma™ Data Manager. The organoleptic score was rated according to the Rosenberg Scale. Next, the patient had to fill out a Halitosis Associated Life-quality Test (HALT) questionnaire. A statistical analysis was performed using a Microsoft Excel spreadsheet and SPSS 17.0 statistical software. P < 0.05 was considered as significant. RESULTS: According to the Tau b Kendall test, the correlation coefficient between the organoleptic assessment and the patient’s own assessment was 8.1%, while the rho Spearman correlation coefficient was 10.4%. In the majority of cases, the patient’s own assessment was higher than the organoleptic assessment. The HALT questionnaire revealed a Cronbach’s coefficient alpha was of 0.929. CONCLUSIONS: Halitosis requires not only professional care provided by dental specialists, but also psychological support

N,N′-Bis[(2-hydroxy­phen­yl)(phen­yl)methyl­idene]propane-1,2-diamine

In the the title compound, C29H26N2O2, two strong intra­molecular O—H⋯N hydrogen bonds involving the hydr­oxy and imine groups generate S(6) ring motifs. The dihedral angles between the pairs of terminal benzene rings are 89.8 (2) and 87.8 (2)°

2,2′-[(Propane-1,3-diyldinitrilo)bis­(phenyl­methyl­idyne)]diphenol

In the title mol­ecule, C29H26N2O2, there are two strong intra­molecular O—H⋯N hydrogen bonds involving the hydr­oxy and imine groups, forming S(6) ring motifs. The dihedral angles between adjacent phenyl rings and phenol-containing planes are 85.27 (19) and 91.38 (18)°. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds connect mol­ecules into a two-dimensional network

Bis(μ₂-2,2′-((2-(hydroxy)propane-1,3-diyl)bis((nitrilo)eth-1-yl-1-ylidene))diphenolato)-dicobalt(III)

A new cobalt(III) complex with a pentadentate Schiff base was synthesized using a reaction of 2,2′-{(2-hydroxypropane-1,3-diyl)bis(nitriloeth-1-yl-1-ylidene)}diphenol (H3L) and cobalt(II) acetate in a methanolic solution. This synthesis resulted in the isolation of dinuclear compound [CoIII2L2] (1), which was characterized using elemental analyses and XRF, FTIR, and TG/DSC techniques. The molecular structure of the complex was confirmed using single-crystal X-ray diffraction. The structure of 1 consists of a centrosymmetric dimer in which two crystallographically equivalent cobalt(III) ions are bridged by two alkoxido oxygen atoms. In addition, each metal center is coordinated by two Schiff bases

REGIONAL TRANSPORTATION – REACTIVATION

Passenger quantity histogram was used to measure the character of passengers’ migration, pick commuter times, equal intensity and minimal commuter numbers. The measurement was done pre and post changes introduced to the train timetable for both working days and weekends (Saturdays and Sundays). The small numbers of passengers made this connection unsustainable without substantial financial support from the government. The changes introduced to the timetable failed to generate increased demand for the service. The Pareto chart clearly illustrates the changes introduced to the timetable over the period of this research. Other disadvantages of the new timetable were also pointed out in this paper

<i>N</i>,<i>N</i>′-Bis(3-ethoxy-2-hydroxybenzylidene)-phenylene-1,3-diamine Methanol Solvate

A crystal structure and thermal characterization of a multisite Schiff base containing N2O2-inner and O4-outer coordination sites are reported. The title compound was characterized by X-ray structure analysis, 1H-NMR, 13C-NMR and ATR-FTIR spectroscopy, TG/DSC and TG-FTIR techniques. The compound crystallizes as a methanol solvate in the triclinic system, space group P1¯. The stable at room temperature compound, during heating in the air, first loses a methanol molecule. At higher temperature, the sample decomposition is associated with a strong exothermic effect and the emission of large amounts of carbon dioxide, carbon monoxide and ammonia

New Heterotrinuclear CuIILnIIICuII (Ln = Ho, Er) Compounds with the Schiff Base: Syntheses, Structural Characterization, Thermal and Magnetic Properties

New heterotrinuclear complexes with the general formula [Cu2Ln(H2L)(HL)(NO3)2]&middot;MeOH (Ln = Ho (1), Er (2), H4L = N,N&prime;-bis(2,3-dihydroxybenzylidene)-1,3-diaminopropane) were synthesized using compartmental Schiff base ligand in conjugation with auxiliary ligands. The compounds were characterized by elemental analysis, ATR-FTIR spectroscopy, X-ray diffraction, TG, DSC, TG-FTIR and XRD analysis. The N2O4 salen-type ligand coordinates 3d and 4f metal centers via azomethine nitrogen and phenoxo oxygen atoms, respectively, to form heteropolynuclear complexes having CuO2Ln cores. In the crystals 1 and 2, two terminal Cu(II) ions are penta-coordinated with a distorted square-pyramidal geometry and a LnIII ion with trigonal dodecahedral geometry is coordinated by eight oxygen atoms from [CuII(H2L)(NO3)]&minus; and [CuII(HL)(NO3)]2&minus; units. Compounds 1 and 2 are stable at room temperature. During heating, they decompose in a similar way. In the first decomposition step, they lose solvent molecules. The exothermic decomposition of ligands is connected with emission large amounts of gaseous products e.g., water, nitric oxides, carbon dioxide, carbon monoxide. The final solid products of decomposition 1 and 2 in air are mixtures of CuO and Ho2O3/Er2O3. The measurements of magnetic susceptibilities and field dependent magnetization indicate the ferromagnetic interaction between CuII and HoIII ions 1

The formation of a neutral manganese(III) complex containing a tetradentate Schiff base and a ketone – synthesis and characterization

<div><p>2-Benzoylphenolato-(2,2′-((2,2-dimethylpropane-1,3-diyl)bis((nitrilo)(phenylmethylidyne)))-diphenolato-manganese(III) methanol solvate, [Mn(C₃₁H₂₈N₂O₂)(C₁₃H₉O₂)]·CH₃OH (<b>1</b>), was synthesized and characterized by FTIR, UV–vis, TG-FTIR, TG/DSC, molar conductivity, magnetic moment measurement, and quantum chemical calculations. During the synthesis, partial hydrolysis of ligand is observed. The compound was obtained as amorphous, dark-brown powder. The effects of organic solvents of various polarities on the UV–vis spectra of ligands and complex were investigated. In addition, the IR and UV–vis spectra were also calculated and compared with the experimental data. A single crystal for analysis was obtained by dissolving the amorphous complex in methanol, and slow evaporation of solvent at 4 °C. Single-crystal X-ray analysis indicated that the methanol molecules are not incorporated into the crystal lattice after the recrystallization process ([Mn(C₃₁H₂₈N₂O₂)(C₁₃H₉O₂)] (<b>2</b>)). In the structure Mn(III) is surrounded by two nitrogens and four oxygens of deprotonated Schiff base and α-hydroxy ketone ligands, and adopts a distorted octahedral geometry.</p></div