Enhancing the rheological properties and shale inhibition behavior of water-based mud using nanosilica, multi-walled carbon nanotube, and graphene nanoplatelet

Five different drilling mud systems namely potassium chloride (KCl) as a basic mud, KCl/partial hydrolytic polyacrylamide (PHPA), KCl/graphene nanoplatelet (GNP), KCl/nanosilica and KCl/multi-walled carbon nano tube (MWCNT) were prepared and investigated for enhancement of rheological properties and shale inhibition. Nanoparticles were characterized in drilling mud using transmission electron microscope (TEM) analysis. Mineralogical analysis of shale was examined by X-ray diffraction (XRD). Five shale plugs were prepared using compactor cell for the determination of shale swelling. Shale swelling was determined using the linear swell meter (LSM) for 20 hours. Results revealed that basic mud and KCl/polymer mud systems shows 30% and 24% change in shale volume. MWCNT, nanosilica and GNP were added separately in the KCl mud system. 0.1 ppb of each MWCNT and nanosilica showed 32% and 33% change in shale volume. However, when the shale was interacted with WBM containing 0.1 ppb of GNP, it was found that only 10% change in shale volume occurred. The results showed that the addition of nanoparticles in the KCl mud system improved the shale inhibition. API, HPHT filtrate loss volume, plastic viscosity (PV) and yield point (YP) were improved using GNP. It is learned from the experimental work that small concentration of KCl with GNP can mitigate shale swelling compared to the mud contains higher concentration of KCl and PHPA in WBM. Thus, GNP can be a better choice for enhancement of WBM performance

Inelastic neutron scattering in random binary alloys : an augmented space approach

Combining the augmented space representation for phonons with a generalized version of Yonezawa-Matsubara diagrammatic technique, we have set up a formalism to seperate the coherent and incoherent part of the total intensity of thermal neutron scattering from disordered alloys. This is done exacly without taking any recourse to mean-field like approximation (as done previously). The formalism includes disorder in masses, force constants and scattering lengths. Implementation of the formalism to realistic situations is performed by an augmented space Block recursion which calculates entire Green matrix and self energy matrix which in turn is needed to evaluate the coherent and incoherent intensities. we apply the formalism to NiPd and NiPt alloys. Numerical results on coherent and incoherent scattering cross sections are presented along the highest symmetry directions. Finally the incoherent intensities are compared with the CPA and also with experiments.Comment: 18 pages, 13 figure

Soil-Pile Interaction Parameters in Vertical and Torsional Vibrations

In this paper, two lumped parameter analogues with the inclusion of constant friction damping are suggested to explain the dynamic behavior of pile supported footings during vertical as well as torsional modes of vibrations. Simple theoretical procedures have been described by which the constant frictional force and the constant frictional moment of the friction damping can be evaluated during vertical and torsional vibrations respectively. The suggested procedures into consideration the relevant physical characteristics of the interface between the pile and the soil, as also the length to diameter (L/d) ratio of the pile. Field vibratory teats have been carried out on model pile supported footings under steady state vertical and torsional excitation. The test data obtained are compared with the values predicted by the proposed theory and the agreement between the two is found to be satisfactory

Site-preference and valency for rare-earth sites in (R-Ce)2Fe14B magnets

Rare-earth (R) permanent magnets of R2Fe14B have technological importance due to their high energy products, and they have two R-sites (Wyckoff 4f and 4g, with four-fold multiplicity) that affect chemistry and valence. Designing magnetic behavior and stability via alloying is technologically relevant to reduce critical (expensive) R-content while retaining key properties;cerium, an abundant (cheap) R-element, offers this potential. We calculate magnetic propertiesand Ce site preference in ( R1−xCex) 2Fe14B [R = La,Nd] using density functional theory (DFT)methods—including a DFT + U scheme to treat localized 4f-electrons. Fe moments compare well with neutron data—almost unaffected by Hubbard U, and weakly affected by spin-orbit coupling.In La2Fe14B, Ce alloys for 0≤x≤1 and prefers smaller R(4f) sites, as observed, a trend we find unaffected by valence. Whereas, in Nd2Fe14B, Ce is predicted to have limited alloying ( x≤0.3 ) with a preference for larger R(4g) sites, resulting in weak partial ordering and segregation. The Curie temperatures versus x for (Nd,Ce) were predicted for a typical sample processing and verified experimentally

Modification of cellulose ether with organic carbonate for enhanced thermal and rheological properties: Characterization and analysis

Reduction in viscosity at higher temperatures is the main limitation of utilizing cellulose ethers in high thermal reservoir conditions for petroleum industry applications. In this study, cellulose ether (hydroxyethyl methyl cellulose (HEMC)) is modified using organic carbonates, i.e., propylene carbonate (PC) and diethyl carbonate (DEC), to overcome the limitation of reduced viscosity at high temperatures. The polymer composites were characterized through various analytical techniques, including Fourier-transform infrared (FTIR), H-NMR, X-ray diffraction (XRD), scanning electron microscope (SEM), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), -potential measurement, molecular weight determination, and rheology measurements. The experimental results of structural and morphological characterization confirm the modification and formation of a new organic carbonate-based cellulose ether. The thermal analysis revealed that the modified composites have greater stability, as the modified samples demonstrated higher vaporization and decomposition temperatures. -potential measurement indicates higher stability of DEC- and PC-modified composites. The relative viscometry measurement revealed that the modification increased the molecular weight of PC- and DEC-containing polymers, up to 93,000 and 99,000 g/moL, respectively. Moreover, the modified composites exhibited higher levels of stability, shear strength and thermal resistance as confirmed by viscosity measurement through rheology determination. The observed increase in viscosity is likely due to the enhanced inter- and intramolecular interaction and higher molecular weight of modified composites. The organic carbonate performed as a transesterification agent that improves the overall properties of cellulose ether (HEMC) at elevated temperatures as concluded from this study. The modification approach in this study will open the doors to new applications and will be beneficial for substantial development in the petroleum industry

Vibrational properties of phonons in random binary alloys: An augmented space recursive technique in the k-representation

We present here an augmented space recursive technique in the k-representation which include diagonal, off-diagonal and the environmental disorder explicitly : an analytic, translationally invariant, multiple scattering theory for phonons in random binary alloys.We propose the augmented space recursion (ASR) as a computationally fast and accurate technique which will incorporate configuration fluctuations over a large local environment. We apply the formalism to $Ni_{55}Pd_{45}$, Ni_{88}Cr_12} and $Ni_{50}Pt_{50}$ alloys which is not a random choice. Numerical results on spectral functions, coherent structure factors, dispersion curves and disordered induced FWHM's are presented. Finally the results are compared with the recent itinerant coherent potential approximation (ICPA) and also with experiments.Comment: 20 pages, LaTeX, 23 figure

Bacterial sensitivity to chlorhexidine and povidone-iodine antiseptics over time: a systematic review and meta-analysis of human-derived data

Surgical site infection (SSI) is the most common complication of surgery, increasing healthcare costs and hospital stay. Chlorhexidine (CHX) and povidone-iodine (PVI) are used for skin antisepsis, minimising SSIs. There is concern that resistance to topical biocides may be emergeing, although the potential clinical implications remain unclear. The objective of this systematic review was to determine whether the minimum bactericidal concentration (MBC) of topical preparations of CHX or PVI have changed over time, in microbes relevant to SSI. We included studies reporting the MBC of laboratory and clinical isolates of common microbes to CHX and PVI. We excluded studies using non-human samples and antimicrobial solvents or mixtures with other active substances. MBC was pooled in random effects meta-analyses and the change in MBC over time was explored using meta-regression. Seventy-nine studies were included, analysing 6218 microbes over 45 years. Most studies investigated CHX (93%), with insufficient data for meta-analysis of PVI. There was no change in the MBC of CHX to Staphylococci or Streptococci over time. Overall, we find no evidence of reduced susceptibility of common SSI-causing microbes to CHX over time. This provides reassurance and confidence in the worldwide guidance that CHX should remain the first-choice agent for surgical skin antisepsis