81 research outputs found

    Evaluation of the Efficacy of African Basil (Ocimum gratissimum) Leaf for Disinfecting Well - water obtained from Ekiti State, Nigeria

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    The demand for potable and affordable water led to comparative research of the efficacy of Ocimum gratissimum Leaf (OGL) extract by collecting well water and treated with OGL extract. Both treated and untreated samples were subjected to physiochemical and bacteriological examinations. Data obtained showed that the pH and feacal coliform counts ranged from 6.17 to 6.74 and 0 to 192 CFU/100 mL for well water sample A; 6.56 to 7.24 and 0 to 118 CFU/100 mL for well water samples B; 6.81 to 7.79 and 0 to 75 CFU/100 mL for well water samples C respectively. The OGL extract includes various bioactive components (i.e. steroids, tannins, etc) according to the phytochemical tests. The first feacal coliform count was above the allowed range (i.e. >50 CFU/100 mL) and the pH value tended to be acidic (6.5), with a colour of >15 H.U. and an unclear (brownish) appearance. The Coliform count was lowered with each dosage of OGL extract until it reached zero count after 24 hours’ contact time at an optimum dosage of 5 mL and the total bacteria counts were gone. The beneficial influence (s) from this study confirms the disinfectant potential of OGL extract for well water treatment

    Personality Traits, Perceived Stress and Social Network as Predictors of Alcohol Addiction among Youths in Ibadan, Nigeria

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    The challenge of alcohol use among youths  has been on the increase and the problems are manifested to the individual, the family and the society at large. One such problem is alcohol addiction which has been investigated using different predictors with varying results. Therefore, this study re-examines personality traits, perceived stress and social network as predictors of alcohol addiction among youths in Ibadan, Oyo State, Nigeria. The study adopted cross-sectional survey design while data was collected from 384 youths (males 282, females 102) using validated questionnaires. Data collected were analyzed using zero-order correlation, t-test of independent samples and multiple regressions analysis. Four questions were tested and the results were accepted at a p < 0.05 level of significance. The results showed that personality traits (r = 0.168, p < 0.05) and social network (r = .057, p < 0.05) positively correlated with alcohol addiction while perceived stress negatively correlated with alcohol addiction [r = - 0.029, p < .05]. Also, the result revealed that perceived stress significantly influenced alcohol addiction among youths (t [383] = 0.213, p <. 0.05). However, social networks did not significantly influence alcohol addiction among youths in Ibadan (t [382] = .026, p >. 05). Finally, the results showed the combined effect of personality traits, perceived stress and social network as joint predictors of alcohol addiction among youths in Ibadan [R2= .125, F [5, 378] = 10.771, p < .05). The study concluded that personality traits, perceived stress and social network are good predictors of alcohol addiction among the study participants. The study recommended that mental health workers should carried out personality profiling, used stress therapy and design targeted adverts to help youths who are suffering from alcohol addiction

    Computer Self-Efficacy of Librarians and Users as Influencers of University Libraries’ Information System Security: Evidence from Nigeria

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    Librarians and their users interact with the library’s information systems for different reasons. The need to protect information and information systems from unauthorized access, modification, data loss and destruction by librarians has become topical in recent times, hence this study. Using survey research design of the correlation type, three University libraries in the South-western Nigeria were purposively selected. Structured questionnaires for 48 librarians and 44,508 registered library users were used. Proportionate stratified random sampling technique for library users with Undergraduates, post graduates and staff as the basis for stratification was used. Total enumeration was used to capture all the librarians, total of 845 (95%) for library users and 42 (88%) for librarians were successfully completed and used for the study. Findings revealed that the librarians and library users had high computer self-efficacy levels related to information system security. Furthermore, computer self-efficacy of librarians significantly influence information systems security (ÎČ = .61, t= 4.86, p.05). The study concludes that these two groups have a strong belief in their abilities to use computers effectively to impact on the information system. The librarians’ belief is in the positive; the users’ appears to be for negative reasons. The study recommends very high level of computer and other technologies efficacy for librarians, regular training and retraining while users should be re-orientated to the realities and benefits of secured information systems

    Study of Mechanical Properties of Stabilized Lateritic Soil with Additives.

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    The overdependence on the USAge of industrially manufactured soil improved or conventional additives have resulted in unaffordable cost of construction of better infrastructure in Third World and poor countries which are mostly agriculturally dependent across Globe. This study is aimed at studying the mechanical properties of lateritic soil stabilized with mixture of conventional and locally available additives. Soil samples collected from the study area were subjected to laboratory tests (i.e. Grain Size and Atterberg Limits tests) after stabilized with cement, ESA and RHA additives at proportion of 2% to 10% by sample weight. It is observed that the LL, PL and PI values varied from 30.1% to 35.5%, 9.9% to 12.5% and 20.1% to 23.2% respectively for sample A. While LL, PL and PI values varied from 35.2% to 41.5%, 10.8% to 14.5% and 24.4% to 27.1% respectively for sample B. It could be generally observed that PI values reduced while PL values increased for the soil samples after increase in addition of cement additive from 6% to 8%. All the LL, PL and PI values also reduced as the percentage of RHA additive added increased. Soil sample A has group classifications of A – 2 – 6 while soil sample B has A – 7 and tend towards A – 2 - 6 and A - 6 after stabilization. The stabilization process using local additives as partial replacement of conventional one generally improved the soils Engineering properties. Though it is more felt in ESA than RHA. Further research work should be carried out

    Assessment of Performance Properties of Stabilized Lateritic Soil for Road Construction in Ekiti State.

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    Soil Stabilization usually enhances performance properties of soil. This can foster waste to wealth policy in country like Nigeria. The aim of this study is to assess performance properties of a stabilized lateritic soil with a view to obtain a cheap and more effective additive. Soil samples were collected from the study area and subjected to Compaction and California Bearing Ratio (CBR) laboratory tests with the addition of 2%, 4%, 6%, 8% and 10% Rice Husk Ash (RHA) and Egg Shell Ash (ESA). Results showed that MDD, OMC and CBR values varied from 1575Kg/m3 to 1930Kg/m3, 7.55% to 18.50% and 20% to 131% respectively for sample A. And 1566Kg/m3 to 1896Kg/m3, 7.53% to 16.90% and 16% to 98% respectively for sample B. The MDD values decrease with increase in the additives contents due to the replacement of soil by the additives in the mixture, coating of the soil by additives which resulted in large particles with larger voids and density; and addition of the additives which decreased the quality of free silt, clay fraction and coarse materials with large surface areas formed. OMC values also increase as the additives increase, though, that of RHA increases more than that of ESA. This is due to the increase in additives which resulted to increase in the amount of water required in the system to adequately lubricate all the particles in the mixture equally increase. Generally, CBR values also increase with increase in the additives contents. This could be attributed to gradual formation of cementitious compound between the additives and Calcium Hydroxide (Ca(OH)2) present in the soil, thus increase in coarse particles of the soil through cementation

    Characterization of a thermostable Bacillus subtilis &#946-amylase isolated from decomposing peels of Cassava (Manihot esculenta)

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    &#946-Amylase (å-1, 4 glucan maltohydrolase; E.C:3.2.1.2) is used in the food processing, brewing and distilling industries due to its capacity to produce maltose syrup from starch. Here, we report the purification and characterization of ù-amylase from Bacillus subtilis isolated from cassava peel waste obtained from a milling factory in Ikenne-Remo, Ogun State, Nigeria. The enzyme was extracted, fractionated at 90% (NH4)2SO4 and further purified using DEAE-cellulose ion exchange chromatography. The molecular weight of the purified enzyme was estimated to be 34.67 Kd. The specific activity of the partially purified enzyme was approximately 1.35 units per mg of protein (Umg-1), Kinetic analysis of its starch hydrolysis activity gave a Km value of 2.496 ± 0.025% and a Vmax of 1.136 ± 0.055 units min-1. The optimum pH and temperature were determined to be 5.5 and 70 0C respectively, and the thermal stability curve gave a maximum activity of 9.75 U at 70oC for 60 min of incubation. Bacillus subtilis ù-amylase is valuable for maltose production, which can be hydrolyzed further by other groups of amylase for the production of high cassava glucose syrup used as sweeteners in the food industry

    Household Hazardous Waste Management in Sub‐Saharan Africa

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    Household hazardous wastes (HHWs) have not been given serious attention in sub‐Saharan Africa. There is little or no information on HHWs in many developing countries of the world. This is regardless of the fact that they are very toxic and contain constituents which are persistent in nature. Once released into the environment, they can remain stable for exceptionally long periods of time. They have the potential to be harmful to public health and the environment if not handled, used, and disposed properly. This study reports the level of knowledge and management of HHWs in three tertiary institutions in sub‐Saharan Africa. Several factors were found to be responsible for poor management of HHWs. These include lack of awareness, inadequate treatment technologies, financial constraints, lack of realistic policies and legal frameworks, and unplanned settlements, among others

    AMELIORATION OF ARSENIC-INDUCED TOXICITY BY ETHANOL LEAF EXTRACT OF PHYLLANTUS AMARUS LINN AND VITAMIN C IN MALE ALBINO RATS

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    The ameliorative effect of ethanol leaf extract of Phyllantus amarus (EEPA) and vitamin C in arsenic-induced toxicity was studied. Thirty-six (36) male albino rats divided into six groups of six (6) rats each were used for the study. Arsenic toxicity was induced in three of the groups by daily intake of 100 ppm of arsenic as Dimethylarsenate (DMA) in their drinking water.  Two of the arsenic-exposed groups were treated with 200 and 500 mg/kg bwt of EEPA and vitamin C respectively. The third group was not treated during arsenic exposure. The fourth and fifth groups were positive control for P. amarus and Vitamin C respectively, while another group served as the normal control. All treatments were done orally for six weeks. The effects of treatments on lipid profile, lipid peroxidation and liver function were thereafter studied. Increased levels of total cholesterol, LDL-cholesterol and malondialdehyde (MDA) were observed in plasma and lymphocytes of untreated arsenic-exposed rats compared to the control group. Arsenic increased total cholesterol and LDL-cholesterol concentrations, while triacylglycerol concentration was reduced significantly. Treatments with EEPA and Vitamin C however ameliorated the dyslipidemia observed in arsenic-exposed groups. Exposure to DMA increased plasma activities of alanine aminotransferase (ALT) and aspartate aminotransferase (AST) of the animals, while plasma activity of ALT in rats treated with Vitamin C was not different compared to the control. Both treatments however, had no significant effect (p > 0.05) on the activity of plasma AST. P. amarus may therefore play a role in ameliorating arsenic-induced dyslipidemia in male albino rats.     &nbsp

    Kinetics and mechanistics steps to the electron transfer reaction of peroxo-bridged binuclear cobalt(III) complex of succinimide by glycine in aqueous acidic medium

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    ABSTRACT. The kinetics and mechanistic steps to the electron transfer reaction of the peroxo-bridged binuclear cobalt(III) complex of succinimide [(suc)(en)2Co(O2)Co(en)2(suc)2+] hereafter called peroxo-bridged dicobalt(III) complex ‘[Co(O2)Co2+]’ by glycine have been carried out spectrophotometrically at λ = 420 nm and T = 26 ± 1 oC, [H+] = 1 x 10-3 M and ᶙ = 0.5 M (NaCl) in aqueous acidic medium. The reaction was found to be first order with respect to [Co(O2)Co2+] and [(Gly] and experimental data indicates a second-order overall. The reactions obeyed the general rate law: (d[Co(O2)Co2+]/dt) = (a +b)[H+])[Co(O2)Co2+][Gly]. Varying hydrogen ion concentration accelerated the reaction rate and shows first-order dependence while the reactions also affected by changes in the ionic strength of the reaction medium by giving a non-negative salt effect in the course of the reaction. Free radicals were not detected in the reactions. Spectroscopic investigation and Michaelis-Menten plots suggest the absence of intermediate complex formation. The experimental result obtained in this system is concluded in favor of the outer-sphere mechanism.                     KEY WORDS: Cobalt(III) complex, Kinetic, Electron transfer, Spectroscopic, Mechanistic steps, Michaelis-Menten, Glycine   Bull. Chem. Soc. Ethiop. 2021, 35(2), 425-434. DOI:  https://dx.doi.org/10.4314/bcse.v35i2.1
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