Photocatalytic degradation of metoprolol tartrate in suspensions of two TiO2-based photocatalysts with different surface area. Identification of intermediates and proposal of degradation pathways.

This study investigates the efficiency of the photocatalytic degradation of metoprolol tartrate (MET), a widely used β 1-blocker, in TiO 2 suspensions of Wackherr's " Oxyde de titane standard" and Degussa P25. The study encompasses transformation kinetics and efficiency, identification of intermediates and reaction pathways. In the investigated range of initial concentrations (0.01-0.1mM), the photocatalytic degradation of MET in the first stage of the reaction followed approximately a pseudo-first order kinetics. The TiO 2 Wackherr induced a significantly faster MET degradation compared to TiO 2 Degussa P25 when relatively high substrate concentrations were used. By examining the effect of ethanol as a scavenger of hydroxyl radicals (OH), it was shown that the reaction with OH played the main role in the photocatalytic degradation of MET. After 240min of irradiation the reaction intermediates were almost completely mineralized to CO 2 and H 2O, while the nitrogen was predominantly present as NH4+. Reaction intermediates were studied in detail and a number of them were identified using LC-MS/MS (ESI+), which allowed the proposal of a tentative pathway for the photocatalytic transformation of MET as a function of the TiO 2 specimen

Bilateral anatomic variation in the relation of the upper trunk of the brachial plexus to the anterior scalene muscle

The brachial plexus represents a field of many anatomical variations with impor- tant clinical implications, especially in the diagnosis and treatment of the thoracic outlet syndrome (TOS). The case described in this paper presented a novel bilateral variation in the relation of the upper trunk of the brachial plexus to the anterior scalene muscle. The ventral rami of the C5 and C6 spinal nerves perforated the anterior scalene muscle simultaneously through a common opening, and joined to form the upper trunk. Previous literature reports described variations of the brachial plexus and the scalene muscles, as well as the embryological basis for their presence. The case reported herein helps to improve the comprehension of the TOS, as well as the diagnostic and therapeutical approach to this syndrome

Removing non-stationary, non-harmonic external interference from gravitational wave interferometer data

We describe a procedure to identify and remove a class of non-stationary and non-harmonic interference lines from gravitational wave interferometer data. These lines appear to be associated with the external electricity main supply, but their amplitudes are non-stationary and they do not appear at harmonics of the fundamental supply frequency. We find an empirical model able to represent coherently all the non-harmonic lines we have found in the power spectrum, in terms of an assumed reference signal of the primary supply input signal. If this signal is not available then it can be reconstructed from the same data by making use of the coherent line removal algorithm that we have described elsewhere. All these lines are broadened by frequency changes of the supply signal, and they corrupt significant frequency ranges of the power spectrum. The physical process that generates this interference is so far unknown, but it is highly non-linear and non-stationary. Using our model, we cancel the interference in the time domain by an adaptive procedure that should work regardless of the source of the primary interference. We have applied the method to laser interferometer data from the Glasgow prototype detector, where all the features we describe in this paper were observed. The algorithm has been tuned in such a way that the entire series of wide lines corresponding to the electrical interference are removed, leaving the spectrum clean enough to detect signals previously masked by them. Single-line signals buried in the interference can be recovered with at least 75 % of their original signal amplitude.Comment: 14 pages, 5 figures, Revtex, psfi

Deuterium temperature, drift velocity, and density measurements in non-Maxwellian plasmas at ASDEX Upgrade

We measure the deuterium density, the parallel drift velocity, and parallel and perpendicular temperatures (T∥, T⊥) in non-Maxwellian plasmas at ASDEX Upgrade. This is done by taking moments of the ion velocity distribution function measured by tomographic inversion of five simultaneously acquired spectra of Dα-light. Alternatively, we fit the spectra using a bi-Maxwellian distribution function. The measured kinetic temperatures (T∥ = 9 keV, T⊥ = 11 keV) reveal the anisotropy of the plasma and are substantially higher than the measured boron temperature (7 keV). The Maxwellian deuterium temperature computed with TRANSP (6 keV) is not uniquely measurable due to the fast ions. Nevertheless, simulated kinetic temperatures accounting for fast ions based on TRANSP (T∥= 8.3 keV, T⊥ = 10.4 keV) are in excellent agreement with the measurements. Similarly, the Maxwellian deuterium drift velocity computed with TRANSP (300 km s-1) is not uniquely measurable, but the simulated kinetic drift velocity accounting for fast ions agrees with the measurements (400 km s-1) and is substantially larger than the measured boron drift velocity (270 km s-1). We further find that ion cyclotron resonance heating elevates T∥ and T⊥ each by 2 keV without evidence for preferential heating in the Dα spectra. Lastly, we derive an expression for the 1D projection of an arbitrarily drifting bi-Maxwellian onto a diagnostic line-of-sight

Electron-cyclotron-resonance heating in Wendelstein 7-X: A versatile heating and current-drive method and a tool for in-depth physics studies

For stellarators, which need no or only small amounts of current drive, electron-cyclotron-resonance heating (ECRH) is a promising heating method even for the envisaged application in a fusion power plant. Wendelstein 7-X (W7-X) is equipped with a steady-state capable ECRH system, operating at 140 GHz, which corresponds to the 2nd cyclotron harmonic of the electrons at a magnetic field of 2.5 T. Ten gyrotrons are operational and already delivered 7MW to W7-X plasmas. Combined with pellet injection, the highest triple product (0.68×10²⁰ keVm¯³s), observed up to now in stellarators, was achieved (Sunn Pedersen et al 2018 Plasma Phys. Control. Fusion 61 014035). For the first time, W7-X plasmas were sustained by 2nd harmonic O-mode heating, approaching the collisionality regime for which W7-X was optimized. Power deposition scans did not show any indication of electron temperature profile resilience. In low-density, low-power plasmas a compensation of the bootstrap current with electron-cyclotron current drive (ECCD) was demonstrated. Sufficiently strong ECCD close to the plasma centre produced periodic internal plasma-crash events, which coincide with the appearance of low order rationals of the rotational transform

Impact of diets with different proportions of linseed and sunflower oils on the growth, liver histology, immunological and chemical blood parameters, and proximate composition of pikeperch Sander lucioperca (L.)

The aim of the study was to determine the impact of applying different proportions of linseed (LO) and sunflower (SFO) oils in pikeperch diets on growth, histological changes in the liver, immunological and blood chemical parameters. The fish were fed isoenergetic and isoprotein feeds containing SFO (group 100SFO) or LO (group 100LO) in quantities of 67 g kg/feed, and a mixture of oils: 47 g SFO and 20 g LO kg/feed (group 70SFO/30LO) and 20 g SFO and 47 g LO kg/feed (group 30SFO/70LO). Dietary ratios of polyunsaturated fatty acids from the n-3 and n-6 series (n3/n6 index) were 0.36–2.15. Pikeperch were reared for 56 days in three replicates for each dietary treatment. Various dietary oils and ratios of n3/n6 did not impact fish growth, feed conversion ratio, viscerosomatic and hepatosomatic index, and size of the hepatocytes. Feeding the fish high quantities of LO and SO oils (groups 100LO and 100SFO) reduced the immunological response of the phagocytes and lymphocytes in the fish. Moreover, this resulted in significant differences among groups in the quantity of linolenic and linoleic acid in whole fish bodies, viscera, fillets, and livers. Various quantities of vegetable oils in the fish diets did not impact the quantity of arachidonic, eicosapentaenoic and docosahexaenoic acid in the fillets and livers. The immunological index and low quantities of linoleic acid in the fillets obtained in group 30SFO/70LO indicate that the n3/n6 dietary ratio of 1.35 was the most advantageous for feeding juvenile pikeperch feeds with vegetable oils