Strength and ductility of bulk nanostructured aluminum processed by mechanical milling

Aluminum\u27s many exceptional properties promote it to be as a strong candidate for several applications in the aerospace, automotive, building and packaging industries to name a few. As a result, strengthening Aluminum has been the interest of many researchers over the time. The most commonly followed approaches are alloying and thermal treatments. However, recently, refining the internal structure of materials until reaching the nano-scale range to improve their mechanical properties has been fostered. Specifically speaking, research adopting this approach on various metals has yielded promising results. One of the techniques used to produce nanostructured Aluminum powders, which is the one employed in this research, is mechanical milling. Aluminum powders were mechanically milled using a high-energy ball mill under argon atmosphere for several milling durations up to 12 hours. The effect of the process control agent used during milling was investigated to determine the suitable amount to be used for best achievable mechanical behavior. Both X-ray diffraction patterns and scanning electron micrographs have revealed the establishment of nanostructured Aluminum by mechanical milling. Bulk samples were synthesized by powder metallurgy. The success of the process of powder consolidation was determined by examining the degree of densification through density measurements. The effect of mechanical milling on the bulk samples has been studied by evaluating the tensile and compressive behaviors of the developed material. The material after milling for 12 hours exhibited a tensile strength that is four folds that of the starting powders. But this elevated strength was at the cost of sacrificing the ductility of the material. Nevertheless, under compressive loading the material behaved in a ductile manner in addition to the improved strength. Peaks for secondary phases have been noticed in the X-ray diffraction patterns for the bulk samples after mechanical milling. The types of these phases remain undetermined, although high suspects of oxides and carbides exist, that might have contributed to the material strengthening. Transmission electron micrographs have ascertained achieving a nanocrystalline structure after milling for 12 hours. The poor ductility of the milled Aluminum acts as a barrier that hinders the utility of the material since almost all the applications require an amount of ductility within certain margins for shaping, manufacturing, and so forth. Hence, post-extrusion annealing was conducted on additional samples in an attempt to improve the ductility. This has been proved quite successful, but still the achieved ductility is nowhere near the range that can help commercialize the newly developed material. It was also remarkable that annealing didn\u27t result in sacrificing the acquired strength; on the contrary, the tensile strength of the material was noticed to have increased. Another approach to compromise the strength and ductility of mechanically milled Aluminum was to mix soft as-received Aluminum powders with the Aluminum powders mechanically milled for 12 hours to produce bi-modally structured Aluminum composite. Two mixing techniques were tried out that are turbula mixer and the high-energy ball mill. Using turbula mixer yielded disappointing results by demonstrating a weak bond between the two constituents. Conversely, using the ball mill for mixing allowed a strong bond to form between the constituents leading to enhancing the ductility of mechanically milled Aluminum for 12 hours without depressing the strength beyond the acceptable range

Additive manufacture of an aluminium alloy: processing, microstructure, and mechanical properties

Additive manufacturing of aluminium alloys using selective laser melting (SLM) is of research interest nowadays because of its potential benefits in industry sectors such as aerospace and automotive. However, in order to demonstrate the credibility of aluminium SLM for industrial needs, a comprehensive understanding of the interrelation between the process parameters, produced microstructure, and mechanical behaviour is still needed. This thesis aims at contributing to developing this comprehensive understanding through studying the various aspects of the process, with investigation of the powder raw material to the near fully dense samples, focussing on the alloy AlSi10Mg. The primary building blocks in the SLM process are the single tracks. Their formation is affected by the physical properties of the material that control the laser-material interactions. Keyhole mode melting was found to be dominant when processing AlSi10Mg, producing conical-shaped melt pools. Porosity was not evident in single tracks and individual layers. Satellites and balling defects, however, were observed on top of the tracks and layers at higher scan speeds, which contribute to porosity formation with layer progression. The combination of process parameters controls the amount of porosity formed, with the scan speed controlling the type of pore; metallurgical or keyhole pore. A pre-melt scan strategy significantly reduced porosity and successfully produced 99.8% dense samples. Furthermore, the pre-melt scan strategy was seen to effectively reduce the number of pores developed when using powder that does not fully comply with the process standards. The gas flow rate within the process chamber controlled laser spatter and condensate removal during processing, which in its turn affected the degree of porosity in the samples. The SLM process resulted in an AlSi10Mg alloy with a characteristically fine microstructure, with fine equiaxed grains at the melt pool core and coarser elongated grains at the boundary. The material showed a strong texture, owing to directional solidification. Cellular dendritic Al with inter-dendritic Si was observed. The material was subjected to a T6 heat treatment that transformed the microstructure into spheroids of Si in the Al matrix. This study investigated, for the first time, the local mechanical properties within the SLM material using nanoindentation. This showed a uniform nano-hardness profile that was attributed to the fine microstructure and good dispersion of the alloying elements. Spatial variation within the material was recorded after the T6 heat treatment due to phase transformation. This study is also the first to report on the compressive behaviour of solid SLM material, which is important for developing prediction and simulation models. The heat treatment softened the material and provided it with an increased ductility under indentation, tensile, and compressive types of loading. In addition, the material showed good fatigue performance, which was further improved by heat treatment and machining to obtain a smoother surface roughness. This investigation has, therefore, developed an understanding of the various aspects of the SLM process yielding near fully dense parts and defined the microstructure-mechanical property interrelation promoting the process for Al alloys in a number of industrial sectors

Additive manufacture of an aluminium alloy: processing, microstructure, and mechanical properties

Additive manufacturing of aluminium alloys using selective laser melting (SLM) is of research interest nowadays because of its potential benefits in industry sectors such as aerospace and automotive. However, in order to demonstrate the credibility of aluminium SLM for industrial needs, a comprehensive understanding of the interrelation between the process parameters, produced microstructure, and mechanical behaviour is still needed. This thesis aims at contributing to developing this comprehensive understanding through studying the various aspects of the process, with investigation of the powder raw material to the near fully dense samples, focussing on the alloy AlSi10Mg. The primary building blocks in the SLM process are the single tracks. Their formation is affected by the physical properties of the material that control the laser-material interactions. Keyhole mode melting was found to be dominant when processing AlSi10Mg, producing conical-shaped melt pools. Porosity was not evident in single tracks and individual layers. Satellites and balling defects, however, were observed on top of the tracks and layers at higher scan speeds, which contribute to porosity formation with layer progression. The combination of process parameters controls the amount of porosity formed, with the scan speed controlling the type of pore; metallurgical or keyhole pore. A pre-melt scan strategy significantly reduced porosity and successfully produced 99.8% dense samples. Furthermore, the pre-melt scan strategy was seen to effectively reduce the number of pores developed when using powder that does not fully comply with the process standards. The gas flow rate within the process chamber controlled laser spatter and condensate removal during processing, which in its turn affected the degree of porosity in the samples. The SLM process resulted in an AlSi10Mg alloy with a characteristically fine microstructure, with fine equiaxed grains at the melt pool core and coarser elongated grains at the boundary. The material showed a strong texture, owing to directional solidification. Cellular dendritic Al with inter-dendritic Si was observed. The material was subjected to a T6 heat treatment that transformed the microstructure into spheroids of Si in the Al matrix. This study investigated, for the first time, the local mechanical properties within the SLM material using nanoindentation. This showed a uniform nano-hardness profile that was attributed to the fine microstructure and good dispersion of the alloying elements. Spatial variation within the material was recorded after the T6 heat treatment due to phase transformation. This study is also the first to report on the compressive behaviour of solid SLM material, which is important for developing prediction and simulation models. The heat treatment softened the material and provided it with an increased ductility under indentation, tensile, and compressive types of loading. In addition, the material showed good fatigue performance, which was further improved by heat treatment and machining to obtain a smoother surface roughness. This investigation has, therefore, developed an understanding of the various aspects of the SLM process yielding near fully dense parts and defined the microstructure-mechanical property interrelation promoting the process for Al alloys in a number of industrial sectors

The application of composite through-thickness assessment to additively manufactured structures

This study looks into the applicability of through-thickness assessment to additive manufacturing (AM) carbon-fibre reinforced polymers (CFRPs). The study utilised a material extrusion printer that uses fused filament fabrication and composite filament fabrication technologies to manufacture functionally-graded polymer and composite polymer parts. The matrix material of choice was nylon 6. Samples were printed exploring a range of reinforcement volume content. In summary, this study presents an assessment of the applicability of through-thickness testing to AM CFRP specimens and provides a performance comparison between AM composite through-thickness properties and the properties of equivalent CM CFRP specimens

The Effects of Feature Sizes in Selectively Laser Melted Ti-6Al-4V Parts on the Validity of Optimised Process Parameters

Ti-6Al-4V is a popular alloy due to its high strength-to-weight ratio and excellent corrosion resistance. Many applications of additively manufactured Ti-6Al-4V using selective laser melting (SLM) have reached technology readiness. However, issues linked with metallurgical differences in parts manufactured by conventional processes and SLM persist. Very few studies have focused on relating the process parameters to the macroscopic and microscopic properties of parts with different size features. Therefore, the aim of this study was to investigate the effect of the size of features on the density, hardness, microstructural evolution, and mechanical properties of Ti-6Al-4V parts fabricated using a fixed set of parameters. It was found that there is an acceptable range of sizes that can be produced using a fixed set of parameters. Beyond a specific window, the relative density decreased. Upon decreasing the size of a cuboid from (5 × 5 × 5 mm) to (1 × 1 × 5 mm), porosity increased from 0.3% to 4.8%. Within a suitable size range, the microstructure was not significantly affected by size; however, a major change was observed outside the acceptable size window. The size of features played a significant role in the variation of mechanical properties. Under tensile loading, decreasing the gauge size, the ultimate and yield strengths deteriorated. This investigation, therefore, presents an understanding of the correlation between the feature size and process parameters in terms of the microscopic and macroscopic properties of Ti-6Al-4V parts manufactured using SLM. This study also highlights the fact that any set of optimized process parameters will only be valid within a specific size window

Reducing porosity in AlSi10Mg parts processed by selective laser melting

Selective laser melting (SLM) is widely gaining popularity as an alternative manufacturing technique for complex and customized parts. SLM is a near net shape process with minimal post processing machining required dependent upon final application. The fact that SLM produces little waste and enables more optimal designs also raises opportunities for environmental advantages. The use of aluminium (Al) alloys in SLM is still quite limited due to difficulties in processing that result in parts with high degrees of porosity. However, Al alloys are favoured in many high-end applications for their exceptional strength and stiffness to weight ratio meaning that they are extensively used in the automotive and aerospace industries. This study investigates the windows of parameters required to produce high density parts from AlSi10Mg alloy using selective laser melting. A compromise between the different parameters and scan strategies was achieved and used to produce parts achieving a density of 99.8%

Selective laser melting of aluminium alloys

Metal additive manufacturing (AM) processes, such as selective laser melting, enable powdered metals to be formed into arbitrary 3D shapes. For aluminium alloys, which are desirable in many high-value applications for their low density and good mechanical performance, selective laser melting is regarded as challenging due to the difficulties in laser melting aluminium powders. However, a number of studies in recent years have demonstrated successful aluminium processing, and have gone on to explore its potential for use in advanced, AM componentry. In addition to enabling the fabrication of highly complex structures, selective laser melting produces parts with characteristically fine microstructures that yield distinct mechanical properties. Research is rapidly progressing in this field, with promising results opening up a range of possible applications across scientific and industrial sectors. This paper reports on recent developments in this area of research as well as highlighting some key topics that require further attention

Nanoindentation shows uniform local mechanical properties across melt pools and layers produced by selective laser melting of AlSi10Mg alloy

Single track and single layer AlSi10Mg has been produced by selective laser melting (SLM) of alloy powder on a AlSi12 cast substrate. The SLM technique produced a cellular-dendritic ultra-fined grained microstructure. Chemical composition mapping and nanoindentation showed higher hardness in the SLM material compared to its cast counterpart. Importantly, although there was some increase of grain size at the edge of melt pools, nanoindentation showed that the hardness (i.e. yield strength) of the material was uniform across overlapping tracks. This is attributed to the very fine grain size and homogeneous distribution of Si throughout the SLM material

3D printing of Aluminium alloys: Additive Manufacturing of Aluminium alloys using selective laser melting

© 2019 The Authors Metal Additive Manufacturing (AM) processes, such as selective laser melting (SLM), enable the fabrication of arbitrary 3D-structures with unprecedented degrees of freedom. Research is rapidly progressing in this field, with promising results opening up a range of possible applications across both scientific and industrial sectors. Many sectors are now benefiting from fabricating complex structures using AM technologies to achieve the objectives of light-weighting, increased functionality, and part number reduction, among others. AM also lends potential in fulfilling demands for reducing the cost and design-to-manufacture time. Aluminium alloys are of the main material systems receiving attention in SLM research, being favoured in many high-value applications. However, processing them is challenging due to the difficulties associated with laser-melting aluminium where parts suffer various defects. A number of studies in recent years have developed approaches to remedy them and reported successful SLM of various Al-alloys and have gone on to explore its potential application in advanced componentry. This paper reports on recent advancements in this area and highlights some key topics requiring attention for further progression. It aims to develop a comprehensive understanding of the interrelation between the various aspects of the subject, as this is essential to demonstrate credibility for industrial needs

Mechanical Properties of Selective Laser Melted AlSi10Mg: Nano, Micro, and Macro Properties

The selective laser melting (SLM) of aluminium alloys is of great current interest at both the industrial and research levels. Aluminium poses a challenge to SLM compared with other candidate materials, such as titanium alloys, stainless steels, and nickel-based alloys, because of its high thermal diffusivity and low infrared absorptivity and tendency to result in relatively porous parts. However, recent studies have reported the successful production of dense AlSi10Mg parts using SLM. In this study, we report on the nano, micro, and macroscopic mechanical properties of dense AlSi10Mg samples fabricated by SLM. Nanoindentation revealed the hardness profile across individual melt pools building up the parts to be uniform. This is due to the fine microstructure and uniform chemical elements distribution developed during the process due to rapid solidification. Micro-hardness testing showed anisotropy in properties according to the build orientation driven by the texture produced during solidification. Lastly, the tensile and compressive behaviours of the parts were examined showing high strength under both loading conditions as well as adequate amounts of strain. These superior mechanical properties compared to those achieved via conventional manufacturing promote SLM as promising for several applications.Mechanical Engineerin