Numerical investigations on the performance and emissions of a turbocharged engine using an ethanol-gasoline blend

Due to a scarcity of fossil fuel supplies and concerns about pollution, the use of ethanol in gasoline has become a priority in the automobile industry. This paper aims to investigate the effect of different ethanol-gasoline fuel blend ratios, namely E20 (% ethanol + % gasoline), E50 (% ethanol + % gasoline), and E75 (75% ethanol + 25% gasoline) on a 1.6 L turbocharged, 4-cylinder, 2017 Proton Preve Premium CFE CVT engine, where E0 (pure gasoline) is taken as reference fuel. In addition, different speed intervals, which include 1000 RPM, 2000 RPM, and 5000 RPM, are employed for each fuel blend. The production of four major emissions, NOx, CO, CO2, and HC, and performance parameters such as thermal efficiency, volumetric efficiency, and brake-specific fuel consumption, are evaluated using SolidWorks for CAD modelling. This then is transferred to ANSYS for emission and performance analysis. According to the findings, increasing ethanol concentration and engine speed increases volumetric efficiency and brake-specific fuel consumption by up to 12.89% and 6.59%, respectively. It was also discovered that ethanol and increasing engine speed had an 11.39% reduction in thermal efficiency. Furthermore, the addition of ethanol occurs, along with an increase in speed, exhaust gas emissions are reduced by up to 21.74% compared to pure gasoline

Overcoming small-bandgap charge recombination in visible and NIR-light-driven hydrogen evolution by engineering the polymer photocatalyst structure

Abstract Designing an organic polymer photocatalyst for efficient hydrogen evolution with visible and near-infrared (NIR) light activity is still a major challenge. Unlike the common behavior of gradually increasing the charge recombination while shrinking the bandgap, we present here a series of polymer nanoparticles (Pdots) based on ITIC and BTIC units with different π-linkers between the acceptor-donor-acceptor (A-D-A) repeated moieties of the polymer. These polymers act as an efficient single polymer photocatalyst for H2 evolution under both visible and NIR light, without combining or hybridizing with other materials. Importantly, the difluorothiophene (ThF) π-linker facilitates the charge transfer between acceptors of different repeated moieties (A-D-A-(π-Linker)-A-D-A), leading to the enhancement of charge separation between D and A. As a result, the PITIC-ThF Pdots exhibit superior hydrogen evolution rates of 279 µmol/h and 20.5 µmol/h with visible (>420 nm) and NIR (>780 nm) light irradiation, respectively. Furthermore, PITIC-ThF Pdots exhibit a promising apparent quantum yield (AQY) at 700 nm (4.76%)