Actinide chemistry using singlet-paired coupled cluster and its combinations with density functionals

Singlet-paired coupled cluster doubles (CCD0) is a simplification of CCD that relinquishes a fraction of dynamic correlation in order to be able to describe static correlation. Combinations of CCD0 with density functionals that recover specifically the dynamic correlation missing in the former have also been developed recently. Here, we assess the accuracy of CCD0 and CCD0+DFT (and variants of these using Brueckner orbitals) as compared to well-established quantum chemical methods for describing ground-state properties of singlet actinide molecules. The $f^0$ actinyl series (UO$_2^{2+}$, NpO$_2^{2+}$, PuO$_2^{2+}$), the isoelectronic NUN, and Thorium (ThO, ThO$^{2+}$) and Nobelium (NoO, NoO$_2$) oxides are studied.Comment: 8 page

Dynamical star-disk interaction in the young stellar system V354 Mon

The main goal of this work is to characterize the mass accretion and ejection processes of the classical T Tauri star V354 Mon, a member of the young stellar cluster NGC 2264. In March 2008, photometric and spectroscopic observations of V354 Mon were obtained simultaneously with the CoRoT satellite, the 60 cm telescope at the Observat\'orio Pico dos Dias (LNA - Brazil) equipped with a CCD camera and Johnson/Cousins BVRI filters, and the SOPHIE \'echelle spectrograph at the Observatoire de Haute-Provence (CNRS - France). The light curve of V354 Mon shows periodical minima (P = 5.26 +/- 0.50 days) that vary in depth and width at each rotational cycle. From the analysis of the photometric and spectroscopic data, it is possible to identify correlations between the emission line variability and the light-curve modulation of the young system, such as the occurrence of pronounced redshifted absorption in the H_alpha line at the epoch of minimum flux. This is evidence that during photometric minima we see the accretion funnel projected onto the stellar photosphere in our line of sight, implying that the hot spot coincides with the light-curve minima. We applied models of cold and hot spots and a model of occultation by circumstellar material to investigate the source of the observed photometric variations. We conclude that nonuniformly distributed material in the inner part of the circumstellar disk is the main cause of the photometric modulation, which does not exclude the presence of hot and cold spots at the stellar surface. It is believed that the distortion in the inner part of the disk is created by the dynamical interaction between the stellar magnetosphere, inclined with respect to the rotation axis, and the circumstellar disk, as also observed in the classical T Tauri star AA Tau and predicted by magnetohydrodynamical numerical simulations.Comment: Accepted by Astronomy and Astrophysic

Pragas do melao e alternativas de controle.

Mosca branca; Brocas das cucurbitaceas; Pulgão; Moscas das frutas; Mosca minadora; Lagarta rosada; Vaquinha.bitstream/item/136248/1/ID-8813.pdfApostila do I Curso sobre o Cultivo do Melao, 2000, Petrolina

Near-Infrared Time-Series Photometry in the Field of Cygnus OB2 Association I - Rotational Scenario For Candidate Members

In the last decades, the early pre main sequence stellar rotational evolution picture has been constrained by studies targeting different young regions at a variety of ages. Observational studies suggest a mass-rotation dependence, and for some mass ranges a connection between rotation and the presence of a circumstellar disk. Not still fully explored, though, is the role of environmental conditions on the rotational regulation. We investigate the rotational properties of candidate members of the young massive association Cygnus OB2. The Stetson variability index, Lomb-Scargle periodogram, Saunders statistics, string/rope length method, and visual verification of folded light curves were applied to select 1224 periodic variable stars. Completeness and contamination of the periodic sample was derived from Monte Carlo simulations, out of which 894 periods were considered reliable. Our study was considered reasonably complete for periods from 2 to 30 days. The general rotational scenario seen in other young regions is confirmed by Cygnus OB2 period distributions, with disked stars rotating on average slower than non-disked stars. A mass-rotation dependence was also verified, but as in NGC 6530, lower mass stars are rotating on average slower than higher mass stars, with an excess of slow rotators among the lower mass population. The effect of the environment on the rotational properties of the association was investigated by re-analysing the results while taking into account the incident UV radiation arising from O stars in the association. Results compatible with the disk-locking scenario were verified for stars with low UV incidence, but no statistical significant relation between rotation and disk presence was verified for stars with high UV incidence suggesting that massive stars can have an important role on regulating the rotation of nearby low mass stars.Comment: Submitted on December 23, 201

Object orientation without extending Z

The good news of this paper is that without extending Z, we can elegantly specify object-oriented systems, including encapsulation, inheritance and subtype polymorphism (dynamic dispatch). The bad news is that this specification style is rather different to normal Z specifications, more abstract and axiomatic, which means that it is not so well supported by current Z tools such as animators. It also enforces behavioural subtyping, unlike most object-oriented programming languages. This paper explains the proposed style, with examples, and discusses its advantages and disadvantages