7 research outputs found
Mechanical, electrical and electro-mechanical properties of thermoplastic elastomer styreneâbutadieneâstyrene/multiwall carbon nanotubes composites
Composites of styrene-butadiene-styrene (SBS) block copolymer with multiwall carbon
nanotubes (MWCNT) were processed by solution casting in order to investigate the
influence of filler content, the different ratio of styrene/butadiene in the copolymer and
the architecture of the SBS matrix on the electrical, mechanical and electro-mechanical
properties of the composites. It was found that filler content and elastomer matrix
architecture influence the percolation threshold and consequently the overall composite
electrical conductivity. The mechanical properties are mainly affected by the styrene
and filler content. Hopping between nearest fillers is proposed as the main mechanism
for the composite conduction. The variation of the electrical resistivity is linear with the
deformation. This fact, together with the gauge factor values in the range of 2 to 18,
results in appropriate composites to be used as (large) deformation sensors.This work was funded by FEDER funds through the "Programa Operacional Factores de
Competitividade â COMPETE" and by national funds by FCT - Fundação para a
CiĂȘncia e a Tecnologia, through project references PTDC/CTM/69316/2006,
PTDC/CTM/73465/2006, PTDC/CTM-NAN/112574/2009, and NANO/NMed-
SD/0156/2007. PC, JS and VS also thank FCT for the SFRH/BD/64267/2009,
SFRH/BD/60623/2009 and SFRH/BPD/63148/2009 grants, respectively. The authors
also thank support from the COST Action MP1003 âEuropean Scientific Network for
Artificial Musclesâ and the COST action MP0902 âComposites of Inorganic Nanotubes
and Polymers (COINAPO)
Strengthening of Glass Composite by Multilayer Carbon Nanotubes Aligned by a Constant Electric Field
Simultaneously improving the mechanical and electrical properties of poly(vinyl alcohol) composites by high-quality graphitic nanoribbons
Fabrication and characterization of elastomeric semiconductive thiophene polymers by peroxide crosslinking
AC electrokinetic immobilization of organic dye molecules
The application of inhomogeneous AC electric fields for molecular immobilization is a very fast and simple method that does not require any adaptions to the moleculeâs functional groups or charges. Here, the method is applied to a completely new category of molecules: small organic fluorescence dyes, whose dimensions amount to only 1 nm or even less. The presented setup and the electric field parameters used allow immobilization of dye molecules on the whole electrode surface as opposed to pure dielectrophoretic applications, where molecules are attracted only to regions of high electric field gradients, i.e., to the electrode tips and edges. In addition to dielectrophoresis and AC electrokinetic flow, molecular scale interactions and electrophoresis at short time scales are discussed as further mechanisms leading to migration and immobilization of the molecules
Synthesis of polyvinyl alcohol (PVA) infiltrated MWCNTs buckypaper for strain sensing application
Buckypaper (BP)/polymer composites are viewed as a viable option to improve the strain transfer across the buckypaper strain sensor by means of providing better interfacial bonding between the polymer and carbon nanotubes (CNTs). Multiwall carbon nanotubes (MWCNTs) BP/polyvinyl alcohol (PVA) composites were fabricated by a sequence of vacuum filtration and polymer intercalation technique. The optimized conditions for achieving a uniform and stable dispersion of MWCNTs were found to be using ethanol as a dispersion medium, 54?”m ultrasonic amplitude and 40?min sonication time. FTIR analysis and SEM spectra further confirmed the introduction of oxygenated groups (-COOH) on the surface of MWCNTs BP and the complete infiltration of PVA into the porous MWCNTs network. At MWCNTs content of 65 wt. %, the tensile strength, Young's modulus and elongation-at-break of PVA-infiltrated MWCNTs BP achieved a maximum value of 156.28?MPa, 4.02?GPa and 5.85%, improved by 189%, 443% and 166% respectively, as compared to the MWCNTs BP. Electrical characterization performed using both two-point probe method and Hall effect measurement showed that BP/PVA composites exhibited reduced electrical conductivity. From the electromechanical characterization, the BP/PVA composites showed improved sensitivity with a gauge factor of about 1.89-2.92. The cyclic uniaxial tensile test validated the high reproducibility and hysteresis-free operation of 65-BP/PVA composite under 3 loading-unloading cycles. Characterization results confirmed that the flexible BP/PVA composite (65 wt. %) with improved mechanical and electromechanical properties is suitable for strain sensing applications in structural health monitoring and wearable technology, as an alternative choice to the fragile nature of conventional metallic strain sensors