22 research outputs found
From Luttinger to Fermi liquids in organic conductors
This chapter reviews the effects of interactions in quasi-one dimensional
systems, such as the Bechgaard and Fabre salts, and in particular the Luttinger
liquid physics. It discusses in details how transport measurements both d.c.
and a.c. allow to probe such a physics. It also examine the dimensional
crossover and deconfinement transition occurring between the one dimensional
case and the higher dimensional one resulting from the hopping of electrons
between chains in the quasi-one dimensional structure.Comment: To be published In the book "The Physics of Organic Conductors and
Superconductors", Springer, 2007, ed. A. Lebe
Competing magnetostructural phases in a semiclassical system
The interplay between charge, structure, and magnetism gives rise to rich phase diagrams in complex materials with exotic properties emerging when phases compete. Molecule-based materials are particularly advantageous in this regard due to their low energy scales, flexible lattices, and chemical tunability. Here, we bring together high pressure Raman scattering, modeling, and first principles calculations to reveal the pressure-temperature-magnetic field phase diagram of Mn[N(CN)2]2. We uncover how hidden soft modes involving octahedral rotations drive two pressure-induced transitions triggering the low ??? high magnetic anisotropy crossover and a unique reorientation of exchange planes. These magnetostructural transitions and their mechanisms highlight the importance of spin-lattice interactions in establishing phases with novel magnetic properties in Mn(II)-containing systems
Unravelling surface and interfacial structures of a metal–organic framework by transmission electron microscopy
Metal-organic frameworks (MOFs) are crystalline porous materials with designable topology, porosity and functionality, having promising applications in gas storage and separation, ion conduction and catalysis. It is challenging to observe MOFs with transmission electron microscopy (TEM) due to the extreme instability of MOFs upon electron beam irradiation. Here, we use a direct-detection electron-counting camera to acquire TEM images of the MOF ZIF-8 with an ultralow dose of 4.1 electrons per square ångström to retain the structural integrity. The obtained image involves structural information transferred up to 2.1 Å, allowing the resolution of individual atomic columns of Zn and organic linkers in the framework. Furthermore, TEM reveals important local structural features of ZIF-8 crystals that cannot be identified by diffraction techniques, including armchair-type surface terminations and coherent interfaces between assembled crystals. These observations allow us to understand how ZIF-8 crystals self-assemble and the subsequent influence of interfacial cavities on mass transport of guest molecules