Ni-In Synergy in CO2Hydrogenation to Methanol

Indium oxide (In2O3) is a promising catalyst for selective CH3OH synthesis from CO2but displays insufficient activity at low reaction temperatures. By screening a range of promoters (Co, Ni, Cu, and Pd) in combination with In2O3using flame spray pyrolysis (FSP) synthesis, Ni is identified as the most suitable first-row transition-metal promoter with similar performance as Pd-In2O3. NiO-In2O3was optimized by varying the Ni/In ratio using FSP. The resulting catalysts including In2O3and NiO end members have similar high specific surface areas and morphology. The main products of CO2hydrogenation are CH3OH and CO with CH4being only observed at high NiO loading (≥75 wt %). The highest CH3OH rate (∼0.25 gMeOH/(gcath), 250 °C, and 30 bar) is obtained for a NiO loading of 6 wt %. Characterization of the as-prepared catalysts reveals a strong interaction between Ni cations and In2O3at low NiO loading (≤6 wt %). H2-TPR points to a higher surface density of oxygen vacancy (Ov) due to Ni substitution. X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and electron paramagnetic resonance analysis of the used catalysts suggest that Ni cations can be reduced to Ni as single atoms and very small clusters during CO2hydrogenation. Supportive density functional theory calculations indicate that Ni promotion of CH3OH synthesis from CO2is mainly due to low-barrier H2dissociation on the reduced Ni surface species, facilitating hydrogenation of adsorbed CO2on Ov © 2021 The Authors. Published by American Chemical Societ

Quantum impurity in an antiferromagnet: non-linear sigma model theory

We present a new formulation of the theory of an arbitrary quantum impurity in an antiferromagnet, using the O(3) non-linear sigma model. We obtain the low temperature expansion for the impurity spin susceptibilities of antiferromagnets with magnetic long-range order in the ground state. We also consider the bulk quantum phase transition in d=2 to the gapped paramagnet (d is the spatial dimension): the impurity is described solely by a topological Berry phase term which is an exactly marginal perturbation to the critical theory. The physical properties of the quantum impurity near criticality are obtained by an expansion in (d-1).Comment: 14 pages, 7 figures; (v2) added re

Cosmic Rays during BBN as Origin of Lithium Problem

There may be non-thermal cosmic rays during big-bang nucleosynthesis (BBN) epoch (dubbed as BBNCRs). This paper investigated whether such BBNCRs can be the origin of Lithium problem or not. It can be expected that BBNCRs flux will be small in order to keep the success of standard BBN (SBBN). With favorable assumptions on the BBNCR spectrum between 0.09 -- 4 MeV, our numerical calculation showed that extra contributions from BBNCRs can account for the $^7$Li abundance successfully. However $^6$Li abundance is only lifted an order of magnitude, which is still much lower than the observed value. As the deuteron abundance is very sensitive to the spectrum choice of BBNCRs, the allowed parameter space for the spectrum is strictly constrained. We should emphasize that the acceleration mechanism for BBNCRs in the early universe is still an open question. For example, strong turbulent magnetic field is probably the solution to the problem. Whether such a mechanism can provide the required spectrum deserves further studies.Comment: 34 pages, 21 figures, published versio

Long distance regularization in chiral perturbation theory with decuplet

We investigate the use of long distance regularization in SU(3) baryon chiral perturbation theory with decuplet fields. The one-loop decuplet contributions to the octet baryon masses, axial couplings, S-wave nonleptonic hyperon decays and magnetic moments are evaluated in a chirally consistent fashion by employing a cutoff to implement long distance regularization. The convergence of the chiral expansions of these quantities is improved compared to the dimensionally regularized version which indicates that the propagation of Goldstone bosons over distances smaller than a typical hadronic size, which is beyond the regime of chiral perturbation theory but included by dimensional regularization, is removed by use of a cutoff.Comment: 31 page

Spin battery operated by ferromagnetic resonance

Precessing ferromagnets are predicted to inject a spin current into adjacent conductors via Ohmic contacts, irrespective of a conductance mismatch with, for example, doped semiconductors. This opens the way to create a pure spin source spin battery by the ferromagnetic resonance. We estimate the spin current and spin bias for different material combinations.Comment: The estimate for the magnitude of the spin bias is improved. We find that it is feasible to get a measurable signal of the order of the microwave frequency already for moderate rf intensitie

Spin-1/2 frustrated antiferromagnet on a spatially anisotopic square lattice: contribution of exact diagonalizations

The phase diagram of a spin-1/2 $J-J'-J_2$ model is investigated by means of exact diagonalizations on finite samples. This model is a generalization of the $J_1-J_2$ model on the square lattice with two different nearest-neighbor couplings $J,J'$ and may be also viewed as an array of coupled Heisenberg chains. The results suggest that the resonnating valence bond state predicted by Nersesyan and Tsvelik [Phys. Rev. B {\bf 67}, 024422 (2003)] for $J_2=0.5J' \ll J$ is realized and extends beyond the limit of small interchain coupling along a curve nearly coincident with the line where the energy per spin is maximum. This line is likely bordered on both side by a columnar dimer long range order. This columnar order could extends for $J'\to J$ which correspond to the $J_1-J_2$ model.Comment: 14 pages, 21 figures, final versio

Sensitivity of deexcitation energies of superdeformed secondary minima to the density dependence of symmetry energy with the relativistic mean-field theory

The relationship between deexcitation energies of superdeformed secondary minima relative to ground states and the density dependence of the symmetry energy is investigated for heavy nuclei using the relativistic mean field (RMF) model. It is shown that the deexcitation energies of superdeformed secondary minima are sensitive to differences in the symmetry energy that are mimicked by the isoscalar-isovector coupling included in the model. With deliberate investigations on a few Hg isotopes that have data of deexcitation energies, we find that the description for the deexcitation energies can be improved due to the softening of the symmetry energy. Further, we have investigated deexcitation energies of odd-odd heavy nuclei that are nearly independent of pairing correlations, and have discussed the possible extraction of the constraint on the density dependence of the symmetry energy with the measurement of deexcitation energies of these nuclei.Comment: 14 pages, 3 figure

A Naturally Narrow Positive Parity Theta^+

We present a consistent color-flavor-spin-orbital wave function for a positive parity Theta^+ that naturally explains the observed narrowness of the state. The wave function is totally symmetric in its flavor-spin part and totally antisymmetric in its color-orbital part. If flavor-spin interactions dominate, this wave function renders the positive parity Theta^+ lighter than its negative parity counterpart. We consider decays of the Theta^+ and compute the overlap of this state with the kinematically allowed final states. Our results are numerically small. We note that dynamical correlations between quarks are not necessary to obtain narrow pentaquark widths.Comment: 10 pages, 1 figure, Revtex4, two-column format, version to be published in Phys. Rev. D, includes numerical estimates of decay width

Pulsar Timing and its Application for Navigation and Gravitational Wave Detection

Pulsars are natural cosmic clocks. On long timescales they rival the precision of terrestrial atomic clocks. Using a technique called pulsar timing, the exact measurement of pulse arrival times allows a number of applications, ranging from testing theories of gravity to detecting gravitational waves. Also an external reference system suitable for autonomous space navigation can be defined by pulsars, using them as natural navigation beacons, not unlike the use of GPS satellites for navigation on Earth. By comparing pulse arrival times measured on-board a spacecraft with predicted pulse arrivals at a reference location (e.g. the solar system barycenter), the spacecraft position can be determined autonomously and with high accuracy everywhere in the solar system and beyond. We describe the unique properties of pulsars that suggest that such a navigation system will certainly have its application in future astronautics. We also describe the on-going experiments to use the clock-like nature of pulsars to "construct" a galactic-sized gravitational wave detector for low-frequency (f_GW ~1E-9 - 1E-7 Hz) gravitational waves. We present the current status and provide an outlook for the future.Comment: 30 pages, 9 figures. To appear in Vol 63: High Performance Clocks, Springer Space Science Review

High-contrast imaging constraints on gas giant planet formation - The Herbig Ae/Be star opportunity

Planet formation studies are often focused on solar-type stars, implicitly considering our Sun as reference point. This approach overlooks, however, that Herbig Ae/Be stars are in some sense much better targets to study planet formation processes empirically, with their disks generally being larger, brighter and simply easier to observe across a large wavelength range. In addition, massive gas giant planets have been found on wide orbits around early type stars, triggering the question if these objects did indeed form there and, if so, by what process. In the following I briefly review what we currently know about the occurrence rate of planets around intermediate mass stars, before discussing recent results from Herbig Ae/Be stars in the context of planet formation. The main emphasis is put on spatially resolved polarized light images of potentially planet forming disks and how these images - in combination with other data - can be used to empirically constrain (parts of) the planet formation process. Of particular interest are two objects, HD100546 and HD169142, where, in addition to intriguing morphological structures in the disks, direct observational evidence for (very) young planets has been reported. I conclude with an outlook, what further progress we can expect in the very near future with the next generation of high-contrast imagers at 8-m class telescopes and their synergies with ALMA.Comment: Accepted by Astrophysics and Space Science as invited short review in special issue about Herbig Ae/Be stars; 12 pages incl. 5 figures, 2 tables and reference