The method of structural study of aggregates of plasmonic gold nanoparticles by UV/visible spectroscopy

The problem of obtaining nanostructured silicate glasses containing silver or gold particles and their agglomerates in recent years is one of the topical directions of photonics. The main advantage of gold in glass nanoparticles is the localized surface plasmon resonance (SPR). Due to their unique optical properties, these objects are used for optoelectronics devices as nanoantennas and biosensors. The position and shape of the SPR can be tuned to the desired wavelength in the visible and near infrared regions, varying the size, interparticle distances, and the dielectric medium in which the particles are located. The aim of this work is to analyze the optical spectra of gold nanoparticles implanted in silicate glass by irradiation with an ultraviolet laser and subsequent purification, and to determine of interparticle distances and particle sizes from the SPR spectra. For the theoretical description of optical spectra, the T-matrix approach was used, which allows to model the scattering of an electromagnetic wave by agglomerates of spheres, which correspond to studied agglomerates of nanoparticles. The application of this approach allowed to determine the structural parameters of aggregates, including averaged size of particles, average interparticle distance, statistical distributions over sizes and interparticle distances.This work was supported by a grant from the Southern Federal University (-07/2017-06)

Spinodal decomposition, nuclear fog and two characteristic volumes in thermal multifragmentation

Thermal multifragmentation of hot nuclei is interpreted as the nuclear liquid-fog phase transition inside the spinodal region. The experimental data for p(8.1GeV) + Au collisions are analyzed within the framework of the statistical multifragmentation model (SMM) for the events with emission of at least two IMFs. It is found that the partition of hot nuclei is specified after expansion to a volume equal to Vt = (2.6+-0.3) Vo, with Vo as the volume at normal density. However, the freeze-out volume is found to be twice as large: Vf = (5+-1) Vo.Comment: 8 pages, 6 figures, to be published in Nucl.Phys.

Chemical freeze-out of light nuclei in high energy nuclear collisions and resolution of the hyper-Triton chemical freeze-out puzzle

Indexación ScopusWe present a summary of the recent results obtained with the novel hadron resonance gas model with the multicomponent hard-core repulsion which is extended to describe the mixtures of hadrons and light (anti-, hyper-)nuclei. A very accurate description is obtained for the hadronic and the light nuclei data measured by STAR at the collision energy The most striking result discussed here is that for the most probable chemical freeze-out scenario for the STAR energy the found parameters allow us to reproduce the values of the experimental ratios S 3 and without fitting. © Published under licence by IOP Publishing Ltd.https://iopscience-iop-org.recursosbiblioteca.unab.cl/article/10.1088/1742-6596/1690/1/01212

Calculation of the Flux of Atmospheric Neutrinos

Atmospheric neutrino-fluxes are calculated over the wide energy range from 30 MeV to 3,000 GeV for the study of neutrino-physics using the data from underground neutrino-detectors. The atmospheric muon-flux at high altitude and at sea level is studied to calibrate the neutrino-fluxes at low energies and high energies respectively. The agreement of our calculation with observations is satisfactory. The uncertainty of atmospheric neutrino-fluxes is also studied.Comment: 51 page

Formation and implantation of gold nanoparticles by ArF excimer laser irradiation of gold coated float glass

To develop a technique for the production of submicron line patterns and directed arrays of plasmonic nanoparticles, the generation and implantation of gold nanoparticles into float glass surfaces was studied by means of ArF-excimer laser irradiation (193 nm) below the ablation threshold of the glass which was sputter coated with a gold layer with a thickness of 70 nm. The formation of gold particles was confirmed by the characteristic surface plasmon resonance (SPR) peak at ∼550 nm. The intensity of the SPR peak of gold particles embedded in the glass matrix increases with the number of applied laser pulses, indicating a different degree of implantation of the gold nanoparticles into the glass surface. It was revealed that the laser implantation of the generated gold particles into the glass is supported on the tin-bath side by the enhanced absorption of tin ions. The dependences of SPR parameters upon the number of laser pulses at different fluences were obtained. Using the methods of X-ray diffraction and extended X-ray absorption fine structure, the mean size of implanted gold particles was estimated at 15–20 nm. This particle size was confirmed by analytical (scanning) transmission electron microscopy, but a small fraction of single particles with a size of ∼50 nm have also been observed. The particles arrangement was further examined by the fitting of experimental optical extinction spectra, varying the particles sizes and interparticle distances within the direct calculations of spectra by the multi-spheres T-matrix method, considering the possible agglomerations of particles. The applied experimental technique provides the creation of arrays of gold nanoparticles in the near-surface region of the glass, which can be used as the substrates or nuclei in the glass for producing bimetallic nanoparticles with gold as the core and SPR characteristics varied in a wide range of visual wavelengths