573 research outputs found

    Multi-agent systems for power engineering applications - part 1 : Concepts, approaches and technical challenges

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    This is the first part of a 2-part paper that has arisen from the work of the IEEE Power Engineering Society's Multi-Agent Systems (MAS) Working Group. Part 1 of the paper examines the potential value of MAS technology to the power industry. In terms of contribution, it describes fundamental concepts and approaches within the field of multi-agent systems that are appropriate to power engineering applications. As well as presenting a comprehensive review of the meaningful power engineering applications for which MAS are being investigated, it also defines the technical issues which must be addressed in order to accelerate and facilitate the uptake of the technology within the power and energy sector. Part 2 of the paper explores the decisions inherent in engineering multi-agent systems for applications in the power and energy sector and offers guidance and recommendations on how MAS can be designed and implemented

    Multi-agent systems for power engineering applications - part 2 : Technologies, standards and tools for building multi-agent systems

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    This is the second part of a 2-part paper that has arisen from the work of the IEEE Power Engineering Society's Multi-Agent Systems (MAS) Working Group. Part 1 of the paper examined the potential value of MAS technology to the power industry, described fundamental concepts and approaches within the field of multi-agent systems that are appropriate to power engineering applications, and presented a comprehensive review of the power engineering applications for which MAS are being investigated. It also defined the technical issues which must be addressed in order to accelerate and facilitate the uptake of the technology within the power and energy sector. Part 2 of the paper explores the decisions inherent in engineering multi-agent systems for applications in the power and energy sector and offers guidance and recommendations on how MAS can be designed and implemented. Given the significant and growing interest in this field, it is imperative that the power engineering community considers the standards, tools, supporting technologies and design methodologies available to those wishing to implement a MAS solution for a power engineering problem. The paper describes the various options available and makes recommendations on best practice. It also describes the problem of interoperability between different multi-agent systems and proposes how this may be tackled

    The LSST Data Mining Research Agenda

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    We describe features of the LSST science database that are amenable to scientific data mining, object classification, outlier identification, anomaly detection, image quality assurance, and survey science validation. The data mining research agenda includes: scalability (at petabytes scales) of existing machine learning and data mining algorithms; development of grid-enabled parallel data mining algorithms; designing a robust system for brokering classifications from the LSST event pipeline (which may produce 10,000 or more event alerts per night); multi-resolution methods for exploration of petascale databases; indexing of multi-attribute multi-dimensional astronomical databases (beyond spatial indexing) for rapid querying of petabyte databases; and more.Comment: 5 pages, Presented at the "Classification and Discovery in Large Astronomical Surveys" meeting, Ringberg Castle, 14-17 October, 200

    An inelastic neutron scattering investigation of the temporal behaviour of the hydrocarbonaceous overlayer of a prototype Fischer-Tropsch to olefins catalyst

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    Sasol Ltd., the University of Glasgow and the EPSRC [award reference EP/P505534/1] are thanked for the provision of a postgraduate studentship (ALD). The Royal Society is thanked for the provision of an Industry Fellowship (PBW).A dual sodium and sulfur promoted haematite, representative of a candidate Fischer-Tropsch to olefins (FTO) catalyst, is prepared and contrasted with the performance of an unpromoted hematite sample in the ambient pressure CO hydrogenation reaction at 623 K as a function of time-on-stream (0–24 h). In-situ post-reaction temperature-programmed oxidation measurements show the carbon evolutionary phase of the catalyst conditioning process to be retarded for the FTO catalyst. Ex-situ inelastic neutron scattering measurements show the promoters perturb the formation of a previously described hydrocarbonaceous overlayer. Specifically, whilst the sp3 hybridised C–H modes of the hydrocarbonaceous overlayer are almost unaffected by the additives, the formation of the overlayer’s sp2 hybridised C–H modes are noticeably impeded. The results are discussed in terms of the Na/S promoters disturbing the formation of an ordered hydrocarbonaceous overlayer that is thought to constrain the supply of adsorbed hydrogen atoms, which favours the formation of unsaturated hydrocarbons associated with the FTO process.Publisher PDFPeer reviewe

    Gauged Dimension Bubbles

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    Some of the peculiar electrodynamical effects associated with gauged ``dimension bubbles'' are presented. Such bubbles, which effectively enclose a region of 5d spacetime, can arise from a 5d theory with a compact extra dimension. Bubbles with thin domain walls can be stabilized against total collapse by the entrapment of light charged scalar bosons inside the bubble, extending the idea of a neutral dimension bubble to accommodate the case of a gauged U(1) symmetry. Using a dielectric approach to the 4d dilaton-Maxwell theory, it is seen that the bubble wall is almost totally opaque to photons, leading to a new stabilization mechanism due to trapped photons. Photon dominated bubbles very slowly shrink, resulting in a temperature increase inside the bubble. At some critical temperature, however, these bubbles explode, with a release of radiation.Comment: 14 pages, no figures; to appear in Phys.Rev.

    Exchange Interaction in Binuclear Complexes with Rare Earth and Copper Ions: A Many-Body Model Study

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    We have used a many-body model Hamiltonian to study the nature of the magnetic ground state of hetero-binuclear complexes involving rare-earth and copper ions. We have taken into account all diagonal repulsions involving the rare-earth 4f and 5d orbitals and the copper 3d orbital. Besides, we have included direct exchange interaction, crystal field splitting of the rare-earth atomic levels and spin-orbit interaction in the 4f orbitals. We have identified the inter-orbital 4f4f repulsion, Uff_{ff} and crystal field parameter, Δf\Delta_f as the key parameters involved in controlling the type of exchange interaction between the rare earth 4f4f and copper 3d spins. We have explored the nature of the ground state in the parameter space of Uff_{ff}, Δf\Delta_f, spin-orbit interaction strength λ\lambda and the 4f4f filling nf_f. We find that these systems show low-spin or high-spin ground state depending on the filling of the 4f4f levels of the rare-earth ion and ground state spin is critically dependent on Uff_{ff} and Δf\Delta_f. In case of half-filling (Gd(III)) we find a reentrant low-spin state as Uff_{ff} is increased, for small values of Δf\Delta_f, which explains the recently reported apparent anomalous anti-ferromagnetic behaviour of Gd(III)-radical complexes. By varying Uff_{ff} we also observe a switch over in the ground state spin for other fillings . We have introduced a spin-orbit coupling scheme which goes beyond L-S or j-j coupling scheme and we find that spin-orbit coupling does not significantly alter the basic picture.Comment: 22 pages, 11 ps figure

    To quantum mechanics through random fluctuations at the Planck time scale

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    We show that (in contrast to a rather common opinion) QM is not a complete theory. This is a statistical approximation of classical statistical mechanics on the {\it infinite dimensional phase space.} Such an approximation is based on the asymptotic expansion of classical statistical averages with respect to a small parameter α.\alpha. Therefore statistical predictions of QM are only approximative and a better precision of measurements would induce deviations of experimental averages from quantum mechanical ones. In this note we present a natural physical interpretation of α\alpha as the time scaling parameter (between quantum and prequantum times). By considering the Planck time tPt_P as the unit of the prequantum time scale we couple our prequantum model with studies on the structure of space-time on the Planck scale performed in general relativity, string theory and cosmology. In our model the Planck time tPt_P is not at all the {\it "ultimate limit to our laws of physics"} (in the sense of laws of classical physics). We study random (Gaussian) infinite-dimensional fluctuations for prequantum times stPs\leq t_P and show that quantum mechanical averages can be considered as an approximative description of such fluctuations.Comment: Discussion on the possibility to go beyond Q

    The application of an alumina-supported Ni catalyst for the hydrogenation of nitrobenzene to aniline

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    Connecting to a methodology developed for defining the relationship between catalyst morphology, adsorbate orientation/location and product distributions with Pd/Al2O3 catalysts, a commercial grade 20 wt% Ni/Al2O3 catalyst (HTC-500), is investigated for gas phase nitrobenzene hydrogenation at elevated temperatures. The morphology of Ni crystallites is assessed via infrared spectroscopy utilising CO as a probe molecule, with 5 separate CO adsorption sites identified. Nitrobenzene hydrogenation data is presented for a 15-hour catalyst conditioning phase, during which nitrobenzene hydrogenation was monitored at 60 oC, and at elevated temperatures post-conditioning: 100, 140, 180 and 200 oC. Nitrobenzene conversion declined with time on stream during the conditioning phase and was only recovered with reaction temperatures ≥ 180 oC. Aniline selectivity seemingly exceeded 100% for reaction temperatures ≥ 100 oC; consideration of the associated mass balance profile for the 35-hour experiment indicated that elevating the reaction temperature facilitated the desorption of aniline, retained from the moderate temperature conditioning phase, from the catalyst. These outcomes outline the impact of temperature on nitrobenzene hydrogenation with HTC-500 and highlight the intricate competitive adsorption phenomena between reagents and products during reaction over this catalyst

    Association of Prenatal Maternal Depression and Anxiety Symptoms with Infant White Matter Microstructure

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    Importance: Maternal depression and anxiety can have deleterious and lifelong consequences on child development. However, many aspects of the association of early brain development with maternal symptoms remain unclear. Understanding the timing of potential neurobiological alterations holds inherent value for the development and evaluation of future therapies and interventions. Objective: To examine the association between exposure to prenatal maternal depression and anxiety symptoms and offspring white matter microstructure at 1 month of age. Design, Setting, and Participants: This cohort study of 101 mother-infant dyads used a composite of depression and anxiety symptoms measured in mothers during the third trimester of pregnancy and measures of white matter microstructure characterized in the mothers' 1-month offspring using diffusion tensor imaging and neurite orientation dispersion and density imaging performed from October 1, 2014, to November 30, 2016. Magnetic resonance imaging was performed at an academic research facility during natural, nonsedated sleep. Main Outcomes and Measures: Brain mapping algorithms and statistical models were used to evaluate the association between maternal depression and anxiety and 1-month infant white matter microstructure as measured by diffusion tensor imaging and neurite orientation dispersion and density imaging findings. Results: In the 101 mother-infant dyads (mean [SD] age of mothers, 33.22 [3.99] years; mean age of infants at magnetic resonance imaging, 33.07 days [range, 18-50 days]; 92 white mothers [91.1%]; 53 male infants [52.5%]), lower 1-month white matter microstructure (decreased neurite density and increased mean, radial, and axial diffusivity) was associated in right frontal white matter microstructure with higher prenatal maternal symptoms of depression and anxiety. Significant sex × symptom interactions with measures of white matter microstructure were also observed, suggesting that white matter development may be differentially sensitive to maternal depression and anxiety symptoms in males and females during the prenatal period. Conclusions and Relevance: These data highlight the importance of the prenatal period to early brain development and suggest that the underlying white matter microstructure is associated with the continuum of prenatal maternal depression and anxiety symptoms

    Leptogenesis and rescattering in supersymmetric models

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    The observed baryon asymmetry of the Universe can be due to the BLB-L violating decay of heavy right handed (s)neutrinos. The amount of the asymmetry depends crucially on their number density. If the (s)neutrinos are generated thermally, in supersymmetric models there is limited parameter space leading to enough baryons. For this reason, several alternative mechanisms have been proposed. We discuss the nonperturbative production of sneutrino quanta by a direct coupling to the inflaton. This production dominates over the corresponding creation of neutrinos, and it can easily (i.e. even for a rather small inflaton-sneutrino coupling) lead to a sufficient baryon asymmetry. We then study the amplification of MSSM degrees of freedom, via their coupling to the sneutrinos, during the rescattering phase which follows the nonperturbative production. This process, which mainly influences the (MSSM) DD-flat directions, is very efficient as long as the sneutrinos quanta are in the relativistic regime. The rapid amplification of the light degrees of freedom may potentially lead to a gravitino problem. We estimate the gravitino production by means of a perturbative calculation, discussing the regime in which we expect it to be reliable.Comment: (20 pages, 6 figures), references added, typos corrected. Final version in revte
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