874 research outputs found
Spectral diffusion and 14N quadrupole splittings in absorption detected magnetic resonance hole burning spectra of photosynthetic reaction centers
Zero field absorption detected magnetic resonance hole burning measurements were performed on photosynthetic reaction centers of the bacteria Rhodobacter sphaeroides R26 and Rhodopseudomonas viridis. Extrapolation to zero microwave power yielded pseudohomogeneous linewidths of 2.0 MHz for Rhodopseudomonas viridis, 1.0 and 0.9 MHz for the protonated forms of Rhodobacter sphaeroides R26 with and without monomer bacteriochlorophyll exchanged, and 0.25 MHz as an upper limit for fully deuterated reaction centers of Rhodobacter sphaeroides R26. The measured linewidths were interpreted as being due to unresolved hyperfine interaction between the nuclear spins and the triplet electron spin, the line shape being determined by spectral diffusion among the nuclei. The difference in linewidths between Rhodobacter sphaeroides R26 and Rhodopseudomonas viridis is then explained by triplet delocalization on the special pair in the former, and localization on one dimer half on the latter. In the fully deuterated sample, four quadrupole satellites were observed in the hole spectra arising from the eight 14N nitrogens in the special pair. The quadrupole parameters seem to be very similar for all nitrogens and were determined to =1.25±0.1 MHz and =0.9±0.1 MHz. The Journal of Chemical Physics is copyrighted by The American Institute of Physics
Dynamics of an exclusion process with creation and annihilation
We examine the dynamical properties of an exclusion process with creation and
annihilation of particles in the framework of a phenomenological domain-wall
theory, by scaling arguments and by numerical simulation. We find that the
length- and time scale are finite in the maximum current phase for finite
creation- and annihilation rates as opposed to the algebraically decaying
correlations of the totally asymmetric simple exclusion process (TASEP).
Critical exponents of the transition to the TASEP are determined. The case
where bulk creation- and annihilation rates vanish faster than the inverse of
the system size N is also analyzed. We point out that shock localization is
possible even for rates proportional to 1/N^a, 1<a<2.Comment: 16 pages, 8 figures, typos corrected, references added, section 4
revise
Discrete stochastic models for traffic flow
We investigate a probabilistic cellular automaton model which has been
introduced recently. This model describes single-lane traffic flow on a ring
and generalizes the asymmetric exclusion process models. We study the
equilibrium properties and calculate the so-called fundamental diagrams (flow
vs.\ density) for parallel dynamics. This is done numerically by computer
simulations of the model and by means of an improved mean-field approximation
which takes into account short-range correlations. For cars with maximum
velocity 1 the simplest non-trivial approximation gives the exact result. For
higher velocities the analytical results, obtained by iterated application of
the approximation scheme, are in excellent agreement with the numerical
simulations.Comment: Revtex, 30 pages, full postscript version (including figures)
available by anonymous ftp from "fileserv1.mi.uni-koeln.de" in the directory
"pub/incoming/" paper accepted for publication in Phys.Rev.
A prototype liquid Argon Time Projection Chamber for the study of UV laser multi-photonic ionization
This paper describes the design, realization and operation of a prototype
liquid Argon Time Projection Chamber (LAr TPC) detector dedicated to the
development of a novel online monitoring and calibration system exploiting UV
laser beams. In particular, the system is intended to measure the lifetime of
the primary ionization in LAr, in turn related to the LAr purity level. This
technique could be exploited by present and next generation large mass LAr TPCs
for which monitoring of the performance and calibration plays an important
role. Results from the first measurements are presented together with some
considerations and outlook.Comment: 26 pages, 27 figure
The asymmetric simple exclusion process: an integrable model for non-equilibrium statistical mechanics
The asymmetric simple exclusion process (ASEP) plays the role of a paradigm
in non-equilibrium statistical mechanics. We review exact results for the ASEP
obtained by Bethe ansatz and put emphasis on the algebraic properties of this
model. The Bethe equations for the eigenvalues of the Markov matrix of the ASEP
are derived from the algebraic Bethe ansatz. Using these equations we explain
how to calculate the spectral gap of the model and how global spectral
properties such as the existence of multiplets can be predicted. An extension
of the Bethe ansatz leads to an analytic expression for the large deviation
function of the current in the ASEP that satisfies the Gallavotti-Cohen
relation. Finally, we describe some variants of the ASEP that are also solvable
by Bethe ansatz.
Keywords: ASEP, integrable models, Bethe ansatz, large deviations.Comment: 24 pages, 5 figures, published in the "special issue on recent
advances in low-dimensional quantum field theories", P. Dorey, G. Dunne and
J. Feinberg editor
Exact dynamics of a reaction-diffusion model with spatially alternating rates
We present the exact solution for the full dynamics of a nonequilibrium spin
chain and its dual reaction-diffusion model, for arbitrary initial conditions.
The spin chain is driven out of equilibrium by coupling alternating spins to
two thermal baths at different temperatures. In the reaction-diffusion model,
this translates into spatially alternating rates for particle creation and
annihilation, and even negative ``temperatures'' have a perfectly natural
interpretation. Observables of interest include the magnetization, the particle
density, and all correlation functions for both models. Two generic types of
time-dependence are found: if both temperatures are positive, the
magnetization, density and correlation functions decay exponentially to their
steady-state values. In contrast, if one of the temperatures is negative,
damped oscillations are observed in all quantities. They can be traced to a
subtle competition of pair creation and annihilation on the two sublattices. We
comment on the limitations of mean-field theory and propose an experimental
realization of our model in certain conjugated polymers and linear chain
compounds.Comment: 13 pages, 1 table, revtex4 format (few minor typos fixed). Published
in Physical Review
An exactly solvable dissipative transport model
We introduce a class of one-dimensional lattice models in which a quantity,
that may be thought of as an energy, is either transported from one site to a
neighbouring one, or locally dissipated. Transport is controlled by a
continuous bias parameter q, which allows us to study symmetric as well as
asymmetric cases. We derive sufficient conditions for the factorization of the
N-body stationary distribution and give an explicit solution for the latter,
before briefly discussing physically relevant situations.Comment: 7 pages, 1 figure, submitted to J. Phys.
The stochastic pump current and the non-adiabatic geometrical phase
We calculate a pump current in a classical two-state stochastic chemical
kinetics by means of the non-adiabatic geometrical phase interpretation. The
two-state system is attached to two particle reservoirs, and under a periodic
perturbation of the kinetic rates, it gives rise to a pump current between the
two-state system and the absorbing states. In order to calculate the pump
current, the Floquet theory for the non-adiabatic geometrical phase is extended
from a Hermitian case to a non-Hermitian case. The dependence of the pump
current on the frequency of the perturbative kinetic rates is explicitly
derived, and a stochastic resonance-like behavior is obtained.Comment: 11 page
Minimal Unitary Models and The Closed SU(2)-q Invariant Spin Chain
We consider the Hamiltonian of the closed invariant chain. We
project a particular class of statistical models belonging to the unitary
minimal series. A particular model corresponds to a particular value of the
coupling constant. The operator content is derived. This class of models has
charge-dependent boundary conditions. In simple cases (Ising, 3-state Potts)
corresponding Hamiltonians are constructed. These are non-local as the original
spin chain.Comment: 19 pages, latex, no figure
Single-Bottleneck Approximation for Driven Lattice Gases with Disorder and Open Boundary Conditions
We investigate the effects of disorder on driven lattice gases with open
boundaries using the totally asymmetric simple exclusion process as a
paradigmatic example. Disorder is realized by randomly distributed defect sites
with reduced hopping rate. In contrast to equilibrium, even macroscopic
quantities in disordered non-equilibrium systems depend sensitively on the
defect sample. We study the current as function of the entry and exit rates and
the realization of disorder and find that it is, in leading order, determined
by the longest stretch of consecutive defect sites (single-bottleneck
approximation, SBA). Using results from extreme value statistics the SBA allows
to study ensembles with fixed defect density which gives accurate results, e.g.
for the expectation value of the current. Corrections to SBA come from
effective interactions of bottlenecks close to the longest one. Defects close
to the boundaries can be described by effective boundary rates and lead to
shifts of the phase transitions. Finally it is shown that the SBA also works
for more complex models. As an example we discuss a model with internal states
that has been proposed to describe transport of the kinesin KIF1A.Comment: submitted to J. Stat. Mec
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