Reaction Kinetics in the Production of Pd Nanoparticles in Reverse Microemulsions. Effect on Particle Size

In the synthesis of metallic nanoparticles in microemulsions, we hypothesized that particle size is mainly controlled by the reaction rate. Thus, the changes observed on the particle sizes as reaction conditions, such as concentrations, temperature, type of surfactant used, etc., are varied should not be correlated directly to the modification of those conditions but indirectly to the changes they produce on the reaction rates. By means of time resolved UV-vis spectroscopy, we measured the reaction rates in the production of Pd nanoparticles inside microemulsions at different reactant concentrations, keeping all the other parameters constant. The measured reaction rates were then correlated with the particle sizes measured by transmission electron microscopy (TEM). We found that nanoparticle size increases linearly as the reaction rates increases, independently of the actual reactant concentrations. We proposed that the kinetics is controlled mainly by the diffusion of the reducing agent through the surfactant monolayer covering the microemulsion membrane. With this model, we predicted that particle size should depend indirectly, via the reaction kinetics, on the micelle radius (v0 ~ r^-3), the water volume (v0~vw^3) and the total microemulsion volume (v0~vT^-3), and temperature (Arrhenius). Some of these predictions were explored in this article

Curvature(s) of a light wavefront in a weak gravitational field

The geometry of a light wavefront evolving from a flat wavefront under the action of weak gravity field in the 3-space associated to a post-Newtonian relativistic spacetime, is studied numerically by means of the ray tracing method.Comment: 3 pages, 1 fig, Talk given by JFPS at the 12th Marcel Grossmann conference (Paris, July, 2009), submitted to the Proceeding

Geometry of an accelerated rotating disk

We analyze the geometry of a rotating disk with a tangential acceleration in the framework of the Special Theory of Relativity, using the kinematic linear differential system that verifies the relative position vector of time-like curves in a Fermi reference. A numerical integration of these equations for a generic initial value problem is made up and the results are compared with those obtained in other works.Comment: 10 pages, LaTeX, 2 eps figs; typos corrected, added reference, minor changes; submitte

Cherenkov telescope array extragalactic survey discovery potential and the impact of axion-like particles and secondary gamma rays

The Cherenkov Telescope Array (CTA) is about to enter construction phase and one of its main key science projects is to perform an unbiased survey in search of extragalactic sources. We make use of both the latest blazar gamma--ray luminosity function and spectral energy distribution to derive the expected number of detectable sources for both the planned Northern and Southern arrays of the CTA observatory. We find that a shallow, wide survey of about 0.5 hour per field of view would lead to the highest number of blazar detections. Furthermore, we investigate the effect of axion-like particles and secondary gamma rays from propagating cosmic rays on the source count distribution, since these processes predict different spectral shape from standard extragalactic background light attenuation. We can generally expect more distant objects in the secondary gamma-ray scenario, while axion-like particles do not significantly alter the expected distribution. Yet, we find that, these results strongly depend on the assumed magnetic field strength during the propagation. We also provide source count predictions for the High Altitude Water Cherenkov observatory (HAWC), the Large High Altitude Air Shower Observatory (LHAASO) and a novel proposal of a hybrid detector.Comment: 16 pages, 4 figures, ApJ 2017 in pres

Geminiviral protein Rep interferes in PCNA sumoylation

Rep is a multifunctional protein essential for replication of geminivirus that interferes with the sumoylation of a key protein in the DNA replication, PCNA (Proliferating Cell Nuclear Antigen). It is known that Rep is capable of interacting with a plethora of plant proteins, including PCNA. Despite the biological significance remains unknown, it’s thought that this interaction should play a key role for generating new copies of the virus genome. Therefore, in order to characterize this interaction, we study which lysines are sumoylated in tomato PCNA (SlPCNA). Considering conservation, location and presence of sumoylation domain criteria, we have identified some candidate lysines and studied how its mutation affects this protein sumoylation in Escherichia coli assays. Finally, we plan to confirm and characterize the Rep interference on SlPCNA sumoylation and determine if this interference occurs in planta.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech