386 research outputs found
Spontaneous thermal expansion of nematic elastomers
We study the monodomain (single-crystal) nematic elastomer materials, all
side-chain siloxane polymers with the same mesogenic groups and crosslinking
density, but differing in the type of crosslinking. Increasing the proportion
of long di-functional segments of main-chain nematic polymer, acting as network
crosslinking, results in dramatic changes in the uniaxial equilibrium thermal
expansion on cooling from isotropic phase. At higher concentration of main
chains their behaviour dominates the elastomer properties. At low concentration
of main-chain material, we detect two distinct transitions at different
temperatures, one attributed to the main-chain, the other to the side-chain
component. The effective uniaxial anisotropy of nematic rubber, r(T)
proportional to the effective nematic order parameter Q(T), is given by the
average of the two components and thus reflects the two-transition nature of
thermal expansion. The experimental data is compared with the theoretical model
of ideal nematic elastomers; applications in high-amplitude thermal actuators
are discussed in the end
UV-isomerisation in nematic elastomers as a route to photo-mechanical transducer
The macroscopic shape of liquid crystalline elastomers strongly depends on
the order parameter of the mesogenic groups. This order can be manipulated if
photoisomerisable groups, e.g. containing N=N bonds, are introduced into the
material. We have explored the large photo-mechanical response of such an
azobenzene-containing nematic elastomer at different temperatures, using force
and optical birefringence measurements, and focusing on fundamental aspects of
population dynamics and the related speed and repeatability of the response.
The characteristic time of ``on'' and ``off'' regimes strongly depends on
temperature, but is generally found to be very long. We were able to verify
that the macroscopic relaxation of the elastomer is determined by the nematic
order dynamics and not, for instance, by the polymer network relaxation.Comment: Latex (EPJE class) 12 figure
Nematic elastomers with aligned carbon nanotubes: new electromechanical actuators
We demonstrate, for the first time, the large electromechanical response in
nematic liquid crystalline elastomers filled with a very low (~0.01%)
concentration of carbon nanotubes, aligned along the nematic director at
preparation. The nanotubes create a very large effective dielectric anisotropy
of the composite. Their local field-induced torque is transmitted to the
rubber-elastic network and is registered as the exerted uniaxial stress of
order ~1kPa in response to a constant field of order ~1MV/m. We investigate the
dependence of the effect on field strength, nanotube concentration and
reproducibility under multiple field-on and -off cycles. The results indicate
the potential of the nanotube-nematic elastomer composites as electrically
driven actuators
Photonic gaps in cholesteric elastomers under deformation
Cholesteric liquid crystal elastomers have interesting and potentially very
useful photonic properties. In an ideal monodomain configuration of these
materials, one finds a Bragg-reflection of light in a narrow wavelength range
and a particular circular polarization. This is due to the periodic structure
of the material along one dimension. In many practical cases, the cholesteric
rubber possesses a sufficient degree of quenched disorder, which makes the
selective reflection broadband. We investigate experimentally the problem of
how the transmittance of light is affected by mechanical deformation of the
elastomer, and the relation to changes in liquid crystalline structure. We
explore a series of samples which have been synthesized with photonic stop-gaps
across the visible range. This allows us to compare results with detailed
theoretical predictions regarding the evolution of stop-gaps in cholesteric
elastomers
Critical fluctuations and random-anisotropy glass transition in nematic elastomers
We carry out a detailed deuterium NMR study of local nematic ordering in
polydomain nematic elastomers. This system has a close analogy to the
random-anisotropy spin glass. We find that, in spite of the quadrupolar nematic
symmetry in 3-dimensions requiring a first-order transition, the order
parameter in the quenched ``nematic glass'' emerges via a continuous phase
transition. In addition, by a careful analysis of the NMR line shape, we deduce
that the local director fluctuations grow in a critical manner around the
transition point. This could be the experimental evidence for the Aizenman-Wehr
theorem about the quenched impurities changing the order of discontinuous
transition
Phase chirality and stereo-selective swelling of cholesteric elastomers
Cholesteric elastomers possess a macroscopic ``phase chirality'' as the
director n rotates in a helical fashion along an optical axis and can be
described by a chiral order parameter. This parameter can be tuned by changing
the helix pitch p and/or the elastic properties of the network. The
cholesterics also possess a local nematic order, changing with temperature or
during solvent swelling. In this paper, by measuring the power of optical
rotation, we discover how these two parameters vary as functions of temperature
or solvent adsorbed by the network. The main result is a finding of pronounced
stereo-selectivity of cholesteric elastomers, demonstrating itself in the
retention of the ``correct'' chirality component of a racemic solvent. It has
been possible to quantify the amount of such stereo-separation, as the basic
dynamics of the effect
Stereo-selective swelling of imprinted cholesteric networks
Molecular chirality, and the chiral symmetry breaking of resulting
macroscopic phases, can be topologically imprinted and manipulated by
crosslinking and swelling of polymer networks. We present a new experimental
approach to stereo-specific separation of chiral isomers by using a cholesteric
elastomer in which a helical director distribution has been topological
imprinted by crosslinking. This makes the material unusual in that is has a
strong phase chirality, but no molecular chirality at all; we study the nature
and parameters controlling the twist-untwist transition. Adding a racemic
mixture to the imprinted network results in selective swelling by only the
component of ``correct'' handedness. We investigate the capacity of demixing in
a racemic environment, which depends on network parameters and the underlying
nematic order
Chirality transfer and stereo-selectivity of imprinted cholesteric networks
Imprinting of cholesteric textures in a polymer network is a method of
preserving a macroscopically chiral phase in a system with no molecular
chirality. By modifying the elastics properties of the network, the resulting
stored helical twist can be manipulated within a wide range since the
imprinting efficiency depends on the balance between the elastics constants and
twisting power at network formation. One spectacular property of phase
chirality imprinting is the created ability of the network to adsorb
preferentially one stereo-component from a racemic mixture. In this paper we
explore this property of chirality transfer from a macroscopic to the molecular
scale. In particular, we focus on the competition between the phase chirality
and the local nematic order. We demonstrate that it is possible to control the
subsequent release of chiral solvent component from the imprinting network and
the reversibility of the stereo-selective swelling by racemic solvents
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