2,422 research outputs found
Observation of an incoherent thermally activated proton hopping process in calix-[4]-arene by means of anelastic spectroscopy
The anelastic spectrum of calix[4]arene was measured at two different
vibrational frequencies. Three thermally activated peaks were detected. The
lowest temperature peak can be described considering a continous distribution
function of activation energies for the relaxation. This anelastic peak can be
ascribed to a thermally activated hopping process of H atoms of the OH groups,
corresponding to a flip-flop of the OH bond. From the results of the present
study, it seems that anelastic spectroscopy is a good experimental technique to
study atomic motion inside molecules at a mesoscopic (few molecules) level.Comment: 5 pages, 4 figures, submitted to Phys. Rev.
Anelastic relaxation process of polaronic origin in La{2-x}Sr{x}CuO{4}: interaction between the charge stripes and pinning centers
The evolution of an anelastic relaxation process occurring around 80 K in
La{2-x}Sr{x}CuO{4} at a measuring frequency of ~1 kHz has been followed from x
= 0.0075 to the overdoped region, x = 0.2, where it disappears. The dependence
of the peak intensity on doping is consistent with a polaronic mechanism,
identified with the disordered charge stripes overcoming pinning centers. A
marked decrease of the peak amplitude occurs at x > 0.045, the same doping
range where a change of the stripe order from parallel to diagonal with respect
to the Cu-O bonds has been observed by neutron diffraction. Both the energy
barrier and peak amplitude also exhibit a rise near x = 1/8.Comment: 5 pages, 4 figure
Perturbation damage indicators based on complex modes
The papers focusing on dynamic identification of structural damages usually rely on the comparison of two or more responses of the structure; the measure of damage is related to the differences of the vibration signals. Almost all literature methods assume damping proportionality to mass and stiffness; however, this is acceptable for new, undamaged structures, but not for existing, potentially damaged structures, especially when localised damages occur. It is well-known that in non-proportionally damped systems the modes are no longer the same of the undamped system: thus, some authors proposed to use modal complexity as a damage indicator. This contribution presents a perturbation approach that can easily reveal such a modal complexity
Perturbation methods for bifurcation analysis from multiple nonresonant complex eigenvalues
It is shown that the logical bases of the static perturbation method, which is currently used in static bifurcation analysis, can also be applied to dynamic bifurcations. A two-time version of the Lindstedt–Poincare ́ Method and the Multiple Scale Method are employed to analyze a bifurcation problem of codimension two. It is found that the Multiple Scale Method furnishes, in a straightforward way, amplitude modulation equations equal to normal form equations available in literature. With a remarkable computational improvement, the description of the central manifold is avoided. The Lindstedt–Poincare ́ Method can also be employed if only steady-state solutions have to be determined. An application is illustrated for a mechanical system subjected to aerodynamic excitation
Phonon-Metamorphosis in Ferromagnetic Manganite Films: Probing the Evolution of an Inhomogeneous State
The analysis of phonon anomalies provides valuable information about the
cooperative dynamics of lattice, spin and charge degrees of freedom.
Significant is the anomalous temperature dependence of the external modes
observed in LaSrMnO (LSMO) films. The two external modes
merge close to the ferromagnetic to paramagnetic transition at and,
moreover, two new modes evolve in this temperature range with strong resonances
at slightly higher frequencies. We propose that this observed phonon
metamorphosis probes the inhomogeneous Jahn-Teller distortion, manifest on the
temperature scale . The analysis is based on the first observation of all
eight phonon modes in the metallic phase of LSMO and on susceptibility
measurements which identify a Griffiths-like phase.Comment: 4 pages, 4 figure
Hydrogen absorption properties of amorphous (Ni0.6Nb0.4−yTay)100−xZrx membranes
Ni based amorphous materials have great potential as hydrogen purification membranes. In the present work
the melt spun (Ni0.6Nb0.4−yTay)100−xZrx with y=0, 0.1 and x=20, 30 was studied. The result of X-ray diffraction
spectra of the ribbons showed an amorphous nature of the alloys. Heating these ribbons below T < 400 °C, even
in a hydrogen atmosphere (1−10 bar), the amorphous structure was retained. The crystallization process was
characterized by differential thermal analysis and the activation energy of such process was obtained. The
hydrogen absorption properties of the samples in their amorphous state were studied by the volumetric method,
and the results showed that the addition of Ta did not significantly influence the absorption properties, a clear
change of the hydrogen solubility was observed with the variation of the Zr content. The values of the
hydrogenation enthalpy changed from ~37 kJ/mol for x=30 to ~9 kJ/mol for x=20. The analysis of the
volumetric data provides the indications about the hydrogen occupation sites during hydrogenation, suggesting
that at the beginning of the absorption process the deepest energy levels are occupied, while only shallower
energy levels are available at higher hydrogen content, with the available interstitial sites forming a continuum
of energy levels
Observation of the cluster spin-glass phase in La_{2-x}Sr_{x}CuO_{4} by anelastic spectroscopy
An increase of the acoustic absorption is found in La_{2-x}Sr_{x}CuO_{4} (x =
0.019, 0.03 and 0.06) close to the temperatures at which freezing of the spin
fluctuations in antiferromagnetic-correlated clusters is expected to occur. The
acoustic absorption is attributed to changes of the sizes of the quasi-frozen
clusters induced by the vibration stress through magnetoelastic coupling.Comment: LaTeX, 2 PostScript figures, submitted to Phys. Rev.
Optimal sensors placement in dynamic damage detection of beams using a statistical approach
Structural monitoring plays a central role in civil engineering; in particular, optimal sensor positioning is essential for correct monitoring both in terms of usable data and for optimizing the cost of the setup sensors. In this context, we focus our attention on the identification of the dynamic response of beam-like structures with uncertain damages. In particular, the non-localized damage is described using a Gaussian distributed random damage parameter. Furthermore, a procedure for selecting an optimal number of sensor placements has been presented based on the comparison among the probability of damage occurrence and the probability to detect the damage, where the former can be evaluated from the known distribution of the random parameter, whereas the latter is evaluated exploiting the closed-form asymptotic solution provided by a perturbation approach. The presented case study shows the capability and reliability of the proposed procedure for detecting the minimum number of sensors such that the monitoring accuracy (estimated by an error function measuring the differences among the two probabilities) is not greater than a control small value
Calibration of material parameters for the Chang-Mander model for unconfined concrete
The current basic OpenSees distribution includes several uniaxial models for concrete. Among them, the model proposed by Chang and Mander in 1994 offers a comprehensive setting applicable both to confined and unconfined concrete, by a proper selection of material parameters. The model offers the possibility to smoothly combine Tsai equation, for the first part of the curve, with a linear branch for the final part. This option is useful to model spalling of unconfined concrete while keeping the smoothness of the curve.
Two basic parameters of the Chang-Mander model for compression, denoted by n and r, govern initial and post-peak stiffness of the Tsai equation, respectively. Besides them, there is a further parameter, denoted by α, which received less attention in the literature and determines the position of the switch between nonlinear and linear parts of the curve.
In the first part of this work, the calibration of the parameters n and r is discussed in some detail. In the second part, the problem of the calibration of α is analyzed. Changes in the value of α may produce large variations in the evaluation of the spalling strain for unconfined concrete. After some comparative analyses with existing models, a simple expression to calibrate α parameter is finally proposed
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