Simulating H/V spectral ratios (HVSR) of ambient vibrations: a comparison among numerical models

The use of H/V spectral ratios (HVSR) of ambient vibrations to constrain the local seismo-stratigraphical configuration relies on numerical forward models able to connect observations with subsoil seismic properties. Several models were proposed to this purpose in the last decades, which are based on different assumptions about the nature of the ambient vibration wavefield. Performances of nine numerical tools implementing these models have been checked by considering 1600 realistic 1-D subsoil configurations mostly relative to A, B and C Eurocode8 soil classes. Resultant HVSR curves predicted by the models are quite similar both in their general shape and in predicting the resonant soil frequencies, possibly because all of them share the same basic representation of the subsoil as a 1-D stack of flat uniform viscoelastic layers. The common sensitivity to transmission/reflection matrices resulting from that representation explains the well-known correspondence of HVSR maxima to 1-D resonance frequency estimates, regardless of the physical assumptions (about source distribution, radiation pattern, dominating seismic phases, etc.) behind the computational model adopted for simulating HVSR curves. On the other hand, the computational models here considered provide quite different amplitudes for HVSR values corresponding to the resonance frequencies. However, since experimental HVSR amplitudes at the same site are affected by an inherent variability (e.g. due to the possible lack of ergodicity of the ambient vibration stochastic wavefield, non-ideal experimental settings, etc.) and uncertainty about the local seismo-stratigraphical profile (attenuation, 2-D/3-D effects, etc.) observations cannot be used for general scoring of the considered computational models on empirical basis. In this situation, the ‘optimal’ numerical tool to be considered for the forward HVSR modelling must be defined case by case

Visible light communication with efficient far-red/near-infrared polymer light-emitting diodes

Visible light communication (VLC) is a wireless technology that relies on optical intensity modulation and is potentially a game changer for internet-of-things (IoT) connectivity. However, VLC is hindered by the low penetration depth of visible light in non-transparent media. One solution is to extend operation into the “nearly (in)visible” near-infrared (NIR, 700–1000 nm) region, thus also enabling VLC in photonic bio-applications, considering the biological tissue NIR semitransparency, while conveniently retaining vestigial red emission to help check the link operativity by simple eye inspection. Here, we report new far-red/NIR organic light-emitting diodes (OLEDs) with a 650–800 nm emission range and external quantum efficiencies among the highest reported in this spectral range (>2.7%, with maximum radiance and luminance of 3.5 mW/cm2 and 260 cd/m2, respectively). With these OLEDs, we then demonstrate a “real-time” VLC setup achieving a data rate of 2.2 Mb/s, which satisfies the requirements for IoT and biosensing applications. These are the highest rates ever reported for an online unequalised VLC link based on solution-processed OLEDs

Towards efficient near-infrared fluorescent organic light-emitting diodes

The energy gap law (EG-law) and aggregation quenching are the main limitations to overcome in the design of near-infrared (NIR) organic emitters. Here, we achieve unprecedented results by synergistically addressing both of these limitations. First, we propose porphyrin oligomers with increasing length to attenuate the effects of the EG -law by suppressing the non-radiative rate growth, and to increase the radiative rate via enhancement of the oscillator strength. Second, we design side chains to suppress aggregation quenching. We find that the logarithmic rate of variation in the non-radiative rate vs. EG is suppressed by an order of magnitude with respect to previous studies, and we complement this breakthrough by demonstrating organic light-emitting diodes with an average external quantum efficiency of ~1.1%, which is very promising for a heavy-metal-free 850 nm emitter. We also present a novel quantitative model of the internal quantum efficiency for active layers supporting triplet-to-singlet conversion. These results provide a general strategy for designing high-luminance NIR emitters

a review and some new issues on the theory of the h v technique for ambient vibrations

In spite of the Horizontal-to-Vertical Spectral Ratio (HVSR or H/V) technique obtained by the ambient vibrations is a very popular tool, a full theoretical explanation of it has been not reached yet. A short excursus is here presented on the theoretical models explaining the H/V spectral ratio that have been development in last decades. It leads to the present two main research lines: one aims at describing the H/V curve by taking in account the whole ambient-vibration wavefield, and another just studies the Rayleigh ellipticity. For the first theoretical branch, a comparison between the most recent two models of the ambient-vibration wavefield is presented, which are the Distributed Surface Sources (DSS) one and the Diffuse Field Approach (DFA). A mention is done of the current developments of these models and of the use of the DSS for comparing the H/V spectral ratio definitions present in literature. For the second research branch, some insights about the connection between the so-called osculation points of the Rayleigh dispersion curves and the behaviour of the H/V curve are discussed

Towards efficient near-infrared fluorescent organic light-emitting diodes

The energy gap law (EG-law) and aggregation quenching are the main limitations to overcome in the design of near-infrared (NIR) organic emitters. Here, we achieve unprecedented results by synergistically addressing both of these limitations. First, we propose porphyrin oligomers with increasing length to attenuate the effects of the EG -law by suppressing the non-radiative rate growth, and to increase the radiative rate via enhancement of the oscillator strength. Second, we design side chains to suppress aggregation quenching. We find that the logarithmic rate of variation in the non-radiative rate vs. EG is suppressed by an order of magnitude with respect to previous studies, and we complement this breakthrough by demonstrating organic light-emitting diodes with an average external quantum efficiency of ~1.1%, which is very promising for a heavy-metal-free 850 nm emitter. We also present a novel quantitative model of the internal quantum efficiency for active layers supporting triplet-to-singlet conversion. These results provide a general strategy for designing high-luminance NIR emitters

Diffuse elastic wavefield within a simple crustal model. Some consequences for low and high frequencies

The reliability of usual assumptions regarding the wavefield composition in applications of the Diffuse Field Approach (DFA) to passive seismic prospecting is investigated. Starting from the more general formulation of the DFA for full wavefield (FW), the contribution of each wave to the horizontal- and vertical-component power spectra at surface are analyzed for a simple elastic waveguide representing the continental crust-upper mantle interface. Special attention is paid to their compositions at low and high frequencies, and the relative powers of each surface wave (SW) type are identified by means of a semianalytical analysis. If body waves are removed from the analysis, the high-frequency horizontal asymptote of the H/V spectral ratio decreases slightly (from 1.33 for FW to around 1.14 for SW) and shows dependence on both the Poisson’s ratio of the crust and the S wave velocity contrast (while FW-H/V asymptote depends on the former only). Experimental tests in a local broadband network provide H/V curves compatible with any of these values in the band 0.2–1Hz, approximately, supporting the applicability of the DFA approximation. Coexistence of multiple SW modes produces distortion in the amplitudes of vertical and radial component Aki’s coherences, in comparison with the usual predictions based on fundamental modes. At high frequencies, this effect consists of a decrement by a constant scaling factor, being very remarkable in the radial case. Effects on the tangential coherence are severe, including a π/4 phase shift, slower decay rate of amplitude versus frequency, and contribution of several velocities for large enough distances