Molecular beam epitaxy of highly mismatched N-rich GaNSb and InNAs alloys

GaN materials alloyed with group V anions form the so-called highly mismatched alloys (HMAs). Recently, the authors succeeded in growing N-rich GaNAs and GaNBi alloys over a large composition range by plasma-assisted molecular beam epitaxy (PA-MBE). Here, they present first results on PA-MBE growth and properties of N-rich GaNSb and InNAs alloys and compare these with GaNAs and GaNBi alloys. The enhanced incorporation of As and Sb was achieved by growing the layers at extremely low growth temperatures. Although layers become amorphous for high As, Sb, and Bi content, optical absorption measurements show a progressive shift of the optical absorption edge to lower energy. The large band gap range and controllable conduction and valence band positions of these HMAs make them promising materials for efficient solar energy conversion devices

LNG fueled barge for cold ironing: feasibility study for the emission abatement in the Port of Genoa

The scientific analysis presented in this paper aims at studying some maritime technical solutions for the electric energy generation and delivery to ships moored in port by means of LNG fueled generators installed onboard a floating unit. Two different scenarios regarding the LNG supply chain are supposed and some options for producing cleaner electric energy are then investigated. The reference area considered in this study is the old port of Genoa where the traffic of both passenger and cargo ships takes place. The paper presents an analysis concerning the main technical features of the considered solutions for an actual port calls scenario. The results regard dimensions and weights of the proposed floating units and the most significant characteristics of the generation equipment, as far as average load factor, fuel consumption and cost are concerned

Subduction-driven recycling of continental margin lithosphere

Whereas subduction recycling of oceanic lithosphere is one of the central themes of plate tectonics, the recycling of continental lithosphere appears to be far more complicated and less well understood(1). Delamination and convective downwelling are two widely recognized processes invoked to explain the removal of lithospheric mantle under or adjacent to orogenic belts(2-5). Here we relate oceanic plate subduction to removal of adjacent continental lithosphere in certain plate tectonic settings. We have developed teleseismic body wave images from dense broadband seismic experiments that show higher than expected volumes of anomalously fast mantle associated with the subducted Atlantic slab under northeastern South America and the Alboran slab beneath the Gibraltar arc region(6,7); the anomalies are under, and are aligned with, the continental margins at depths greater than 200 kilometres. Rayleigh wave analysis(8,9) finds that the lithospheric mantle under the continental margins is significantly thinner than expected, and that thin lithosphere extends from the orogens adjacent to the subduction zones inland to the edges of nearby cratonic cores. Taking these data together, here we describe a process that can lead to the loss of continental lithosphere adjacent to a subduction zone. Subducting oceanic plates can viscously entrain and remove the bottom of the continental thermal boundary layer lithosphere from adjacent continental margins. This drives surface tectonics and pre-conditions the margins for further deformation by creating topography along the lithosphere-asthenosphere boundary. This can lead to development of secondary downwellings under the continental interior, probably under both South America and the Gibraltar arc(8,10), and to delamination of the entire lithospheric mantle, as around the Gibraltar arc(11). This process reconciles numerous, sometimes mutually exclusive, geodynamic models proposed to explain the complex oceanic-continental tectonics of these subduction zones(12-17)This research was supported by US National Science Foundation grants EAR 0003572, 0607801 and 0808939 (A.L.), EAR 0808931 (E.D.H.), EAR 0809023 and 1054638 (M.S.M.), the Venezuelan National Fund for Science, Technology and Innovation grant G-2002000478 and PDVSA-INTEVEP-FUNVISIS cooperative agreement 2004-141 (M.S.), the Spanish Ministry of Science and Innovation grants CSD2006-00041, CGL2009-09727 and CGL2010-15146 (J.G. and R.C.), and by an A. v. Humboldt Foundation Research Prize (A.L.).Peer Reviewe

The Crust beneath Morocco: From the surface topography to the upper mantle a 700 km long seismic section across Morocco.

The most characteristic topographic features of Morocco are the Atlas Mountains and the Rif Coordillera. These two orogenic belts are the response of different geodynamic processes acting at lithospheric scale caused by a complex plate interaction. Both are located within the diffuse plate boundary zone separating Africa and Europe. The boundary zone is characterized by a relatively broad zone of deformation that includes mountain chains in southern Iberia, the Betics and in Morocco, the Rif Cordillera, separated by the Alboran basin. The zone delineates an arcuate arc system known as the Gibraltar arc. The area is characterized by a relatively large amount of earthquake activity at various depths and with a broad spectra of focal mechanisms. Within the last decade a large international effort have been devoted to the area. The topic has fostered a strong collaborations between Spanish and international research teams form Europe and USA. Key multi-seismic projects have been developed that aim to constrain the structure, composition and tectonic scenario from south of the Atlas to the Betics, across the Rif cordillera and the Alboran basin. The multidisciplinary research program included: natural source (earthquakes) recording with temporal deployments of broad band (BB) instrumentation and, controlled source seismic acquisition experiments where, spatially dense recording of wide-angle seismic reflection shot gathers were acquired. The natural source experiments consisted on a transect from Merzouga across the Gibraltar Arc and into the Iberian Peninsula (until south of Toledo) and, a nearly regular grid of BB. The controlled source data-sets were able to constrain the crustal structure and provide seismic P-wave propagation velocity models from the coast across the Rif and the Atlas. From south to north the crust features a relatively moderate crustal root beneath the Middle Atlas which can reach 40 km clearly differing from the 35 km thickness value observed at both sides of this root. Travel time inversion results position the crustal root just south of the High Atlas defining a thrusted mantle wedge and, also a limited crustal imbrication is suggested in the Middle Atlas. The most surprising feature is a prominent and unexpected crustal root (over 50 km) located beneath the external Rif and identified by both the wide-angle data and receiver function studies. To the east of this feature the crust thins rapidly by 20 km across the Nekkor fault zone, suggested to be related to the sharp change in crustal thickness. On shore-offshore recording of marine shots reveal further complexities in the transition to the Alboran basin. The low values of the Bouguer gravity anomalies beneath the Rif Cordillera are consistent with the crustal models derived from the new seismic data. The detailed knowledge on the crustal structure achieved by this high resolution imaging geophysical techniques is an asset to evaluate the earthquake and potential tsunami hazard for the coasts of North Africa and western Europe.This work has been primarily funded by the Spanish MEC project CGL2007–63889. Additional funding was provided by projects CGL2010–15416, CSD2006-00041, and CGL2009–09727 (Spain), CGL2008–03474-E, 07- TOPO_EUROPE_FP-006 (ESF Eurocores) and EAR-0808939 (US, NSF).Peer Reviewe