33 research outputs found
Cross-relaxation and phonon bottleneck effects on magnetization dynamics in LiYF4:Ho3+
Frequency and dc magnetic field dependences of dynamic susceptibility in
diluted paramagnets LiYF:Ho have been measured at liquid helium
temperatures in the ac and dc magnetic fields parallel to the symmetry axis of
a tetragonal crystal lattice. Experimental data are analyzed in the framework
of microscopic theory of relaxation rates in the manifold of 24
electron-nuclear sublevels of the lowest non-Kramers doublet and the first
excited singlet in the Ho ground multiplet split by the crystal
field of S symmetry. The one-phonon transition probabilities were computed
using electron-phonon coupling constants calculated in the framework of
exchange charge model and were checked by optical piezospectroscopic
measurements. The specific features observed in field dependences of the in-
and out-of-phase susceptibilities (humps and dips, respectively) at the
crossings (anti-crossings) of the electron-nuclear sublevels are well
reproduced by simulations when the phonon bottleneck effect and the cross-spin
relaxation are taken into account
Numerical adiabatic potentials of orthorhombic Jahn-Teller effects retrieved from ultrasound attenuation experiments. Application to the SrF2:Cr crystal
A methodology is worked out to retrieve the numerical values of all the main
parameters of the six-dimensional adiabatic potential energy surface (APES) of
a polyatomic system with a quadratic T-term Jahn-Teller effect (JTE) from
ultrasound experiments. The method is based on a verified assumption that
ultrasound attenuation and speed encounter anomalies when the direction of
propa- gation and polarization of its wave of strain coincides with the
characteristic directions of symmetry breaking in the JTE. For the SrF2:Cr
crystal, employed as a basic example, we observed anomaly peaks in the
temperature dependence of attenuation of ultrasound at frequencies of 50-160
MHz in the temperature interval of 40-60 K for the wave propagating along the
[110] direction, for both the longitudinal and shear modes, the latter with two
polarizations along the [001] and [110] axes, respectively. We show that these
anomalies are due to the ultrasound relaxation by the system of non-interacting
Cr2+ JT centers with orthorhombic local distortions. The interpretation of the
ex- perimental findings is based on the T2g (eg +t2g) JTE problem including the
linear and quadratic terms of vibronic interactions in the Hamiltonian and the
same-symmetry modes reduced to one interaction mode. Combining the experimental
results with a theoretical analysis we show that on the complicated
six-dimensional APES of this system with three tetragonal, four trigonal, and
six orthorhombic extrema points, the latter are global minima, while the former
are saddle points, and we estimate numerically all the main parameters of this
surface, including the linear and quadratic vibronic coupling constants, the
primary force constants, the coordinates of all the extrema points and their
energies, the energy barrier between the orthorhombic minima, and the tunneling
splitting of the ground vibrational states.Comment: 8 pages, 3 figure
Freezing-in of molecular mobility of small molecules (probes) in glassy polymers and secondary relaxation transitions
RedWater: A Rodwell System to Extract Water from Martian Ice Deposits
The ability to mine ice water in situ is of vital importance to enable future manned exploration of the solar system. In the past decade, orbital measurements have revealed that a third of the Martian surface contains shallow ground ice. Mars reconnaissance orbiter (MRO) shallow subsurface radar (SHARAD) data indicates the presence of debris-covered glaciers as well as buried ice sheets in the Arcadia Planitia (30°N–45°N) that are up to 170 m thick, consist of nearly pure ice, and are covered by at most 20 m of overburden. This data supports the implementation of two proven terrestrial technologies—coiled tube (CT) drilling and a Rodriguez well (RodWell)—for drilling and water extraction on Mars. Honeybee’s RedWater system combines these two technologies into one by first using a CT drilling approach to create a hole, and then, once the hole is made to depth, using the coiled tubing left in the hole as a conduit for water extraction. Models for system performance in this mode have been refined from a combination of U.S. Army Cold Regions Research and Engineering Laboratory (CRREL) research, data collected from Antarctic RodWells, and Honeybee testing. Honeybee plans to validate RedWater’s mechanism designs and extraction models through thermal-vacuum testing to TRL5 in 2020
Laboratory Rational of Changes in the Crystal Lattice of Nickel-Titanium Endodontic Rotary Files in Autoclaving
Objectives. The aim of this study was to investigate the changes of the crystal lattice of NiTi instruments after repeated autoclave sterilization cycles based on the results to conclude about the influence of multiple sterilization on the characteristics of ProTaper clinical use. Methods. 21 samples of ProTaper Universal rotary files were divided into 3 groups of 7 samples. After 1, 4, and 7 cycles of sterilization, the samples were observed using еnergy-dispersive X-ray spectroscopy (EDX), X-ray powder diffraction (XRD), and scanning electron microscopy (SEM). Results. EDS analysis confirmed that all samples were composed mainly of nickel and titanium, also Fe (presumably steel), Cr, Co, and Zn were found. The percentage of nickel and titanium was affected by repeated sterilization cycles. The mass fraction of Fe, Co, Zn, and Cr decreased after 1, 4, and 7 sterilization cycles. According to the results of the second study, it was found that, with increasing autoclaving cycles, the percentage of Fe decreased. There were changes in the three obtained diffractograms, which indicated an increase in the number of the martensitic phase and a decrease in austenitic. The cutting efficiency of the ProTaper is also reduced during repeated sterilization cycles, which can be caused by the austenitic and martensitic phase displacement. Conclusion. Manufacturing features and repeated sterilization cycles increase the internal deformation in the structure of NiTi alloy, which increases the risk of fracture. © 2020 Zurab Khabadze et al