Frequency and dc magnetic field dependences of dynamic susceptibility in
diluted paramagnets LiYF4:Ho3+ have been measured at liquid helium
temperatures in the ac and dc magnetic fields parallel to the symmetry axis of
a tetragonal crystal lattice. Experimental data are analyzed in the framework
of microscopic theory of relaxation rates in the manifold of 24
electron-nuclear sublevels of the lowest non-Kramers doublet and the first
excited singlet in the Ho3+ ground multiplet 5I8 split by the crystal
field of S4 symmetry. The one-phonon transition probabilities were computed
using electron-phonon coupling constants calculated in the framework of
exchange charge model and were checked by optical piezospectroscopic
measurements. The specific features observed in field dependences of the in-
and out-of-phase susceptibilities (humps and dips, respectively) at the
crossings (anti-crossings) of the electron-nuclear sublevels are well
reproduced by simulations when the phonon bottleneck effect and the cross-spin
relaxation are taken into account