4,293 research outputs found

    Radiator design system computer programs

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    Minimum weight space radiator subsystems which can operate over heat load ranges wider than the capabilities of current subsystems are investigated according to projected trends of future long duration space vehicles. Special consideration is given to maximum heat rejection requirements of the low temperature radiators needed for environmental control systems. The set of radiator design programs that have resulted from this investigation are presented in order to provide the analyst with a capability to generate optimum weight radiator panels or sets of panels from practical design considerations, including transient performance. Modifications are also provided for existing programs to improve capability and user convenience

    Magnetic quantum tunnelling in Fe8 with excited nuclei

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    We investigate the effect of dynamic nuclear spin fluctuation on quantum tunneling of the magnetization (QTM) in the molecular magnet Fe8 by increasing the nuclei temperature using radio frequency (RF) pulses before the hysteresis loop measurements. The RF pulses do not change the electrons spin temperature. Independently we show that the nuclear spin-spin relaxation time T2 has strong temperature dependence. Nevertheless, we found no effect of the nuclear spin temperature on the tunneling probability. This suggests that in our experimental conditions only the hyperfine field strength is relevant for QTM. We demonstrate theoretically how this can occur.Comment: 4 pages, 4 figure

    Challenges in the development of the orbiter radiator system

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    Major technical challenges which were met in the design and development of the Space Shuttle Orbiter Radiator System are discussed. This system rejects up to 30 kW of waste heat from eight individual radiators having a combined surface area of 175 sq m. The radiators, which are deployable, are mounted on the inside of the payload bay doors for protection from aerodynamic heating during ascent and re-entry. While in orbit the payload bay doors are opened to expose the radiators for operation. An R21 coolant loop accumulates waste heat from various components in the Orbiter and delivers the heat to the radiators for rejection to space. Specific challenges included high acoustically induced loads during lift-off, severe radiating area constraints, demanding heat load control requirements, and long life goals. Details of major design and analysis efforts are discussed. The success of the developed hardware in satisfying mission objectives showed how well the design challenge was met

    Electronic spectroscopy of trans-azomethane by electron impact

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    The electron impact excitation of trans-azomethane (i.e., trans-dimethyl diazine CH3ā€“Nā€“Nā€“CH3) has been studied by both trapped electron (TE) and differential electron scattering (DES) techniques. The nature of the excited state in each of several transitions has been identified by the energy and angular dependences of the excitation cross section. Two previously unreported singlet-->triplet transitions are observed with maxima at 2.75 and 4.84 eV. Theoretical calculations on the parent compound, trans-diimide (Hā€“N=Nā€“H), suggest that these are the Ļ‡ 1Ag-->1 3Bg (produced by excitation of an electron from an n + molecular orbital to a pi* molecular orbital) and the Ļ‡ 1Ag-->1 3Bu (pi-->pi*) transitions, respectively. The Ļ‡ 1Ag-->1 1Bg (n + -->pi*) transition is observed with a peak at 3.50 eV in the DES studies. A strong peak at 6.01 eV in the TE spectra appears as a weak shoulder in the DES studies and is interpreted as either a symmetry-forbidden or Rydberg-like singlet-->singlet transition. Allowed singlet-->singlet features overlap each other in the transition energy range from 6 to 10 eV. Peaks are seen in the DES spectra at 6.71, 7.8, and 9.5 eV and in the TE spectrum at 8.0 eV. Several significant differences between the TE and the DES spectra are analyzed on the basis of the different nature of the two experiments

    Alkali and Alkaline Earth Metal Compounds: Core-Valence Basis Sets and Importance of Subvalence Correlation

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    Core-valence basis sets for the alkali and alkaline earth metals Li, Be, Na, Mg, K, and Ca are proposed. The basis sets are validated by calculating spectroscopic constants of a variety of diatomic molecules involving these elements. Neglect of (3s,3p)(3s,3p) correlation in K and Ca compounds will lead to erratic results at best, and chemically nonsensical ones if chalcogens or halogens are present. The addition of low-exponent pp functions to the K and Ca basis sets is essential for smooth convergence of molecular properties. Inclusion of inner-shell correlation is important for accurate spectroscopic constants and binding energies of all the compounds. In basis set extrapolation/convergence calculations, the explicit inclusion of alkali and alkaline earth metal subvalence correlation at all steps is essential for K and Ca, strongly recommended for Na, and optional for Li and Mg, while in Be compounds, an additive treatment in a separate `core correlation' step is probably sufficient. Consideration of (1s)(1s) inner-shell correlation energy in first-row elements requires inclusion of (2s,2p)(2s,2p) `deep core' correlation energy in K and Ca for consistency. The latter requires special CCVnnZ `deep core correlation' basis sets. For compounds involving Ca bound to electronegative elements, additional dd functions in the basis set are strongly recommended. For optimal basis set convergence in such cases, we suggest the sequence CV(D+3d)Z, CV(T+2d)Z, CV(Q+dd)Z, and CV5Z on calcium.Comment: Molecular Physics, in press (W. G. Richards issue); supplementary material (basis sets in G98 and MOLPRO formats) available at http://theochem.weizmann.ac.il/web/papers/group12.htm

    Differences in lateral gene transfer in hypersaline versus thermal environments

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    <p>Abstract</p> <p>Background</p> <p>The role of lateral gene transfer (LGT) in the evolution of microorganisms is only beginning to be understood. While most LGT events occur between closely related individuals, inter-phylum and inter-domain LGT events are not uncommon. These distant transfer events offer potentially greater fitness advantages and it is for this reason that these "long distance" LGT events may have significantly impacted the evolution of microbes. One mechanism driving distant LGT events is microbial transformation. Theoretically, transformative events can occur between any two species provided that the DNA of one enters the habitat of the other. Two categories of microorganisms that are well-known for LGT are the thermophiles and halophiles.</p> <p>Results</p> <p>We identified potential inter-class LGT events into both a thermophilic class of Archaea (Thermoprotei) and a halophilic class of Archaea (Halobacteria). We then categorized these LGT genes as originating in thermophiles and halophiles respectively. While more than 68% of transfer events into Thermoprotei taxa originated in other thermophiles, less than 11% of transfer events into Halobacteria taxa originated in other halophiles.</p> <p>Conclusions</p> <p>Our results suggest that there is a fundamental difference between LGT in thermophiles and halophiles. We theorize that the difference lies in the different natures of the environments. While DNA degrades rapidly in thermal environments due to temperature-driven denaturization, hypersaline environments are adept at preserving DNA. Furthermore, most hypersaline environments, as topographical minima, are natural collectors of cellular debris. Thus halophiles would in theory be exposed to a greater diversity and quantity of extracellular DNA than thermophiles.</p
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