55 research outputs found

    Infant mortality in mid-19th century Amsterdam:Religion, social class, and space

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    This study uses a unique historical GIS dataset compiled from birth, death, and population register records for infants born in the city of Amsterdam in 1851 linked to microā€level spatial data on housing, infrastructure, and health care. Cox's proportional hazards models and the concept of egocentric neighbourhoods were used to analyse the effects of various sociodemographic characteristics, residential environment, water supply, and healthā€care variables on infant mortality and stillbirth. The analyses confirm the favourable position of the Jewish population with respect to infant mortality as found in other studies and show the unfavourable position of orthodox Protestant minorities. Infant mortality rate differences are much smaller between social classes than between religions. The exact role of housing and neighbourhood conditions visā€aā€vis infant mortality is still unclear; however, we ascertained that effects of environmental conditions are more pronounced in later stages of infancy and less important in the early stages of infancy

    Self-Consistent Field study of Polyelectrolyte Brushes

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    We formulate a self-consistent field theory for polyelectrolyte brushes in the presence of counterions. We numerically solve the self-consistent field equations and study the monomer density profile, the distribution of counterions, and the total charge distribution. We study the scaling relations for the brush height and compare them to the prediction of other theories. We find a weak dependence of the brush height on the grafting density.We fit the counterion distribution outside the brush by the Gouy-Chapman solution for a virtual charged wall. We calculate the amount of counterions outside the brush and find that it saturates as the charge of the polyelectrolytes increases

    The Link Between Suggestibility, Compliance, and False Confessions: A Review using Experimental and Field Studies

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    Expert witnesses and scholarssometimesdisagree on whether suggestibility and compliance are related to peopleā€™s tendency to falsely confess. Hence, the principal aim of this review was to amass the available evidence on the link between suggestibility and complianceand false confessions. We reviewed experimental data in which false confessions were experimentally evoked and suggestibilityand compliancewere measured. Furthermore, we reviewed field data ofpotential false confessions and their relationship with suggestibility and compliance. These diverse databases converge to the same conclusion. We unequivocally found that high levels of suggestibility (andto a lesser extentcompliance)were associated with an increased vulnerability to falsely confess. Suggestibility measurements might be informative for expert witnesses who must evaluate the false confession potential in legal cases

    Salt Dependence of the Tribological Properties of a Surface-Grafted Weak Polycation in Aqueous Solution

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    The nanoscopic adhesive and frictional behaviour of end-grafted poly[2-(dimethyl amino)ethyl methacrylate] (PDMAEMA) films (brushes) in contact with gold- or PDMAEMA-coated atomic force microscope tips in potassium halide solutions with different concentrations up to 300Ā mM is a strong function of salt concentration. The conformation of the polymers in the brush layer is sensitive to salt concentration, which leads to large changes in adhesive forces and the contact mechanics at the tipā€“sample contact, with swollen brushes (which occur at low salt concentrations) yielding large areas of contact and frictionā€“load plots that fit JKR behaviour, while collapsed brushes (which occur at high salt concentrations) yield sliding dominated by ploughing, with conformations in between fitting DMT mechanics. The relative effect of the different anions follows the Hofmeister series, with I āˆ’ collapsing the brushes more than Br āˆ’ and Cl āˆ’ for the same salt concentration
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