Phase Equilibria Modeling of Low-Grade Metamorphic Martian Rocks

We report on modeling low-grade (up to 300 °C) metamorphic reactions with Martian starting materials

The Martian sources of the SNC meteorites (two, not one), and what can and can't be learned from the SNC meteorites

The SNC meteorites, which almost certainly originate in the Martian crust, have been inferred to come from a single impact crater site, but no known crater fits all criteria. Formation at two separate sites (S from one, NC from the other) is more consistent with the sum of petrologic, geochronologic, and cosmochronologic data. If the source craters for the SNC meteorites can be located, Mars science will advance considerably. However, many significant questions cannot be answered by the SNC meteorites. These questions await a returned sample

Hot Rocks! Near-Infrared Reflectances (and Emissivities) or Rocks at Venus Surface Temperatures

Venus surface can be viewed in emission through a few near-infrared (NIR) spectral windows (1 m) in its relatively opaque atmosphere [1]. Venus surface shows NIR emissivities that correlate with surface geology [2-4], and these emissivity variations are interpreted as differences in surface rock type (mafic vs. silicic) and/or extent of weathering (Fe2+ silicates vs. Fe3+-oxide-coated). To understand and quantify the observed variations in NIR emissivity, high-temperature (T) emissivity can be measured directly [5,6]. For example, emissivities of basalts in the wavelength range 0.85 1.2 m are ~0.95 [5-8]. This can be tested by measureing reflectance, because Kirchoffs Law holds that emissivity (e) = 1 reflectance (r). The r of basalt in the NIR is ~0.05 [o] consistent with a NIR e of ~0.95 [5-8]. High-T NIR es of silicic igneous rocks (granitic, rhyolite) have been reported to be 0.8-0.9 [5,6], which is inconsistent with r values of 0.3-0.8 of such rocks at 25C [9,10]. However, these measurements have been updated [7,8] and are consistent with the results here (see below and Fig. 3)

Lunar Meteorite NWA 11421: X-Ray Tomogrpahy & Preliminary Petrology

Lunar meteorite NWA 11421 is provisionally placed with the "NWA 8046 clan" of similar stones (the "Algerian Megafind") of which at least 33 kg has been recovered. NWA 11421 and pairs are feldspathic regolith breccias, with angular fragments of plagioclase-rich clasts in a dark glassy matrix. Most members of this clan contain < 5.5% FeO and < 0.3 ppm Th. To date, there have been no petrographic studies reported of these lunar meteorites. An 11.7 gm sample of NWA 11421 was purchased from Marcin Cimala, holder of the main mass - this sample is consistent in all respects with the formal meteorite description. This particular sample was selected because it appeared to contain a fragment of dunite

A Comprehensive Analysis on the Pion-Photon Transition Form Factor Beyond the Leading Fock State

We perform a comprehensive analysis of the pion-photon transition form factor $F_{\pi \gamma}(Q^2)$ involving the transverse momentum corrections with the present CLEO experimental data, in which the contributions beyond the leading Fock state have been taken into consideration. As is well-known, the leading Fock-state contribution dominates of $F_{\pi \gamma}(Q^2)$ at large momentum transfer ($Q^2$) region. One should include the contributions beyond the leading Fock state in small $Q^2$ region. In this paper, we construct a phenomenological expression to estimate the contributions beyond the leading Fock state based on its asymptotic behavior at $Q^2\to0$. Our present theoretical results agree well with the experimental data in the whole $Q^2$ region. Then, we extract some useful information of the pionic leading twist-2 distribution amplitude (DA) by comparing our results of $F_{\pi \gamma}(Q^2)$ with the CLEO data. By taking best fit, we have the DA moments, $a_2(\mu_0^2)=0.002^{+0.063}_{-0.054}$, $a_4(\mu_0^2)=-0.022_{-0.012}^{+0.026}$ and all of higher moments, which are closed to the asymptotic-like behavior of the pion wavefunction.Comment: 25 pages, 7 figures. Typo error correcte

Phase Equilibria Modeling of Low-grade Metamorphic Martian Rocks

Hydrous phases have been identified to be a significant component of martian mineralogy. Particularly prehnite, zeolites, and serpentine are evidence for low‐grade metamorphic reactions at elevated temperatures in mafic and ultramafic protoliths. Their presence suggests that at least part of the martian crust is sufficiently hydrated for low‐grade metamorphic reactions to occur. A detailed analysis of changes in mineralogy with variations in fluid content and composition along possible martian geotherms can contribute to determine the conditions required for subsurface hydrous alteration, fluid availability and rock properties in the martian crust. In this study, we use phase equilibria models to explore low‐grade metamorphic reactions covering a pressure‐temperature range of 0‐0.5 GPa and 150‐450 °C for several martian protolith compositions and varying fluid content. Our models replicate the detected low‐grade metamorphic/hydrothermal mineral phases like prehnite, chlorite, analcime, unspecified zeolites, and serpentine. Our results also suggest that actinolite should be a part of lower‐grade metamorphic assemblages, but actinolite may not be detected in reflectance spectra for several reasons. By gradually increasing the water content in the modeled whole rock composition, we can estimate the amount of water required to precipitate low‐grade metamorphic phases. Mineralogical constraints do not necessarily require an elevated geothermal gradient for the formation of prehnite. However, restricted crater excavation depths even for large impact craters are not likely sampling prehnite along colder gradients, either suggesting a geotherm of ~ 20 °C/km in the Noachian or an additional heat source such as hydrothermal or magmatic activity

Pigeonholing planetary meteorites: The lessons of misclassification of EET87521 and ALH84001

The last few years have provided two noteworthy examples of misclassifications of achondritic meteorites because the samples were new kinds of meteorites from planetary rather than asteroidal parent bodies. Basaltic lunar meteorite EET87521 was misclassified as a eucrite and SNC (martian) orthopyroxenite ALH84001 was misclassified as a diogenite. In classifying meteorites we find what we expect: we pigeonhole meteorites into known categories most of which were derived from the more common asteroidal meteorites. But the examples of EET8752 and ALH84001 remind us that planets are more complex than asteroids and exhibit a wider variety of rock types. We should expect variety in planetary meteorites and we need to know how to recognize them when we have them. Our intent here is to show that our asteroidal perspective is inappropriate for planetary meteorites

Conference on Early Mars: Geologic and Hydrologic Evolution, Physical and Chemical Environments, and the Implications for Life

Topics considered include: Geology alteration and life in an extreme environment; developing a chemical code to identify magnetic biominerals; effect of impacts on early Martin geologic evolution; spectroscopic identification of minerals in Hematite-bearing soils and sediments; exopaleontology and the search for a Fossil record on Mars; geochemical evolution of the crust of Mars; geological evolution of the early earth;solar-wind-induced erosion of the Mars atmosphere. Also included geological evolution of the crust of Mars

A Unique Amphibole- and Magnetite-Rich Carbonaceous Chondrite from Almahata Sitta

Almahata Sitta (AhS) 202 from the UoK collection represents a clast from the polymict breccia asteroid 2008 TC3. AhS 202 was recognized as a unique carbonaceous chondrite (CC) with a high magnetite content. Here we report that it also contains a significant amount of amphibole, a mineral that is very rare in chondrites and has not previously been reported in significant abundance in a CC. We present new petrographic, oxygen isotope, and micro-FTIR data. We discuss petrogenesis and possible relationships to known CC

Mineral Surface and Fluid Chemistry in Nakhlite Analog Water-Rock Reactions

We report on experiments with Mars analog materials under diagenetic conditions and find characteristic chemical surface changes in correspondence with the fluid conditions