262 research outputs found
Magnetic and electrical properties of dhcp NpPd3 and U(1-x)Np(x)Pd3
We have made an extensive study of the magnetic and electrical properties of
double-hexagonal closepacked NpPd3 and a range of U(1-x)Np(x)Pd3 compounds with
x=0.01, 0.02, 0.05, and 0.50 using magnetization, magnetic susceptibility,
electrical resistivity, and heat capacity measurements on polycrystalline
samples, performed in the temperature range 2-300 K and in magnetic fields up
to 9 T. Two transitions are observed in NpPd3 at T=10 and 30 K. Dilute Np
samples (x<0.05) exhibit quadrupolar transitions, with the transition
temperatures reduced from those of pure UPd3.Comment: 10 pages, 18 figure
Magnetic and electrical properties of (Pu,Lu)Pd3
We present measurements of the magnetic susceptibility, heat capacity and
electrical resistivity of PuLuPd, with =0, 0.1, 0.2, 0.5,
0.8 and 1. PuPd is an antiferromagnetic heavy fermion compound with
~K. With increasing Lu doping, both the Kondo and RKKY interaction
strengths fall, as judged by the Sommerfeld coefficient and N\'eel
temperature . Fits to a crystal field model of the resistivity also
support these conclusions. The paramagnetic effective moment
increases with Lu dilution, indicating a decrease in the
Kondo screening. In the highly dilute limit, approaches
the value predicted by intermediate coupling calculations. In conjunction with
an observed Schottky peak at 60~K in the magnetic heat capacity,
corresponding to a crystal field splitting of 12~meV, a mean-field
intermediate coupling model with nearest neighbour interactions has been
developed.Comment: 13 pages, 13 figure
Molecular characterization of calmodulin and calmodulin kinase II in the cockroach Periplaneta americana and their involvement in the modulation of the insect nicotinic receptors
The 5f localization/delocalization in square and hexagonal americium monolayers: A FP-LAPW electronic structure study
The electronic and geometrical properties of bulk americium and square and
hexagonal americium monolayers have been studied with the full-potential
linearized augmented plane wave (FP-LAPW) method. The effects of several common
approximations are examined: (1) non-spin polarization (NSP) vs. spin
polarization (SP); (2) scalar-relativity (no spin-orbit coupling (NSO)) vs.
full-relativity (i.e., with spin-orbit (SO) coupling included); (3)
local-density approximation (LDA) vs. generalized-gradient approximation (GGA).
Our results indicate that both spin polarization and spin orbit coupling play
important roles in determining the geometrical and electronic properties of
americium bulk and monolayers. A compression of both americium square and
hexagonal monolayers compared to the americium bulk is also observed. In
general, the LDA is found to underestimate the equilibrium lattice constant and
give a larger total energy compared to the GGA calculations. While spin orbit
coupling shows a similar effect on both square and hexagonal monolayer
calculations regardless of the model, GGA versus LDA, an unusual spin
polarization effect on both square and hexagonal monolayers is found in the LDA
results as compared with the GGA results. The 5f delocalization transition of
americium is employed to explain our observed unusual spin polarization effect.
In addition, our results at the LDA level of theory indicate a possible 5f
delocalization could happen in the americium surface within the same Am II (fcc
crystal structure) phase, unlike the usually reported americium 5f
delocalization which is associated with crystal structure change. The
similarities and dissimilarities between the properties of an Am monolayer and
a Pu monolayer are discussed in detail.Comment: 22 pages, 8 figure
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