Chemical approaches to carbon dioxide utilization for manned Mars missions

Use of resources available in situ is a critical enabling technology for a permanent human presence in space. A permanent presence on Mars, e.g., requires a large infrastructure to sustain life under hostile conditions. As a resource on Mars, atmospheric CO2 is as follows: abundant; available at all points on the surface; of known presence; chemically simple; and can be obtained by simple compression. Many studies focus on obtaining O2 and the various uses for O2 including life support and fuel; discussion of CO, the coproduct from CO2 fixation revolves around its uses as a fuel, being oxidized back to CO2. Several new proposals are studied for CO2 fixation through chemical, photochemical, and photoelectrochemical means. For example, the reduction of CO2 to hydrocarbons such as acetylene (C2H2) can be accomplished with H2. C2H2 has a theoretical vacuum specific impulse of approx. 375 secs. Potential uses were also studied of CO2, as obtained or further reduced to carbon, as a reducing agent in metal oxide processing to form metals or metal carbides for use as structural or power materials; the CO2 can be recycled to generate O2 and CO

Material processing with hydrogen and carbon monoxide on Mars

Several novel proposals are examined for propellant production from carbon dioxide and monoxide and hydrogen. Potential uses were also examined of CO as a fuel or as a reducing agent in metal oxide processing as obtained or further reduced to carbon. Hydrogen can be reacted with CO to produce a wide variety of hydrocarbons, alcohols, and other organic compounds. Methanol, produced by Fischer-Tropsch chemistry may be useful as a fuel; it is easy to store and handle because it is a liquid at Mars temperatures. The reduction of CO2 to hydrocarbons such as methane or acetylene can be accomplished with hydrogen. Carbon monoxide and hydrogen require cryogenic temperatures for storage as liquids. Noncryogenic storage of hydrogen may be accomplished using hydrocarbons, inorganic hydrides, or metal hydrides. Noncryogenic storage of CO may be accomplished in the form of iron carbonyl (FE(CO)5) or other metal carbonyls. Low hydrogen content fuels such as acetylene (C2H2) may be effective propellants with low requirements for earth derived resources. The impact on manned Mars missions of alternative propellant production and utilization is discussed

Reactivity of pi-complexes of Ti, V, and Nb towards dithioacetic acid: Synthesis and structure of novel metal sulfur-containing complexes

In order to use sulfur-containing resources economically and with minimal environmental damage, it is important to understand the desulfurization processes. Hydrodesulfurization, for example, is carried out on the surface of a heterogeneous metal sulfide catalyst. Studies of simple, soluble inorganic systems provide information regarding the structure and reactivity of sulfur-containing compounds with metal complexes. Further, consistent with recent trends in materials chemistry, many model compounds warrant further study as catalyst precursors. The reactivity of low-valent organometallic sandwich pi-complexes toward dithiocarboxylic acids is described. For example, treatment of bisbenzene vanadium with CH3CSSH affords a divanadium tetrakis(dithioacetate) complex. The crystallographically determined V-V bond distance, 2.800(2), is nearly the same as the V-V bond distance in a V(mu-nu squared-S2)2V' unit in the mineral patonite (VS4)n. The stability of the V2S4 core in the dimer is demonstrated by evidence of V2S4(+) in the mass spectrum (70 eV, solid probe) of the vanadium dimer. Several other systems relevant to HDS catalysis are also discussed

Production and use of metals and oxygen for lunar propulsion

Production, power, and propulsion technologies for using oxygen and metals derived from lunar resources are discussed. The production process is described, and several of the more developed processes are discussed. Power requirements for chemical, thermal, and electrical production methods are compared. The discussion includes potential impact of ongoing power technology programs on lunar production requirements. The performance potential of several possible metal fuels including aluminum, silicon, iron, and titanium are compared. Space propulsion technology in the area of metal/oxygen rocket engines is discussed

The stochastic limit in the analysis of the open BCS model

In this paper we show how the perturbative procedure known as {\em stochastic limit} may be useful in the analysis of the Open BCS model discussed by Buffet and Martin as a spin system interacting with a fermionic reservoir. In particular we show how the same values of the critical temperature and of the order parameters can be found with a significantly simpler approach

Heated-Atmosphere Airship for the Titan Environment: Thermal Analysis

Future exploration of Saturn's moon Titan can be carried out by airships. Several lighter-than-atmosphere gas airships and passive drifting heated-atmosphere balloon designs have been studied, but a heated-atmosphere airship could combine the best characteristics of both. This work analyses the thermal design of such a heated-atmosphere vehicle, and compares the result with a lighter-than-atmosphere (hydrogen) airship design. A design tool was created to enable iteration through different design parameters of a heated-atmosphere airship (diameter, number of layers, and insulating gas pocket thicknesses) and evaluate the feasibility of the resulting airship. A baseline heated-atmosphere airship was designed to have a diameter of 6 m (outer diameter of 6.2 m), three-layers of material, and an insulating gas pocket thickness of 0.05 m between each layer. The heated-atmosphere airship has a mass of 161.9 kg. A similar mission making use of a hydrogen-filled airship would require a diameter of 4.3 m and a mass of about 200 kg. For a long-duration mission, the heated-atmosphere airship appears better suited. However, for a mission lifetime under 180 days, the less complex hydrogen airship would likely be a better option

Public engagement in local government: the voice and influence of citizens in online communicative spaces

The communications and engagement strategies of local councils play an important role in contributing to the public's understanding of local democracies, and their engagement with local issues. Based on a study of the local authority in the third largest city in the UK, Leeds, this article presents an empirically based analysis of the impact of new opportunities for public engagement afforded by digital media on the Council's communication with citizens. Drawing on over 20 face-to-face semi-structured interviews with elected politicians, Council strategists, Council communications specialists, mainstream journalists, and citizen journalists, the article explores perceptions of the Council's engagement and communication with citizens from the perspective of a range of actors involved in the engagement process. The research asks what the differing motivations behind the Council's communications and engagement strategies mean for the way that digital media are and might be used in the future to enhance the role of citizens in local governance. The research suggests that while there are no grounds for expecting digital media to displace existing channels of public engagement, digital media are beginning to play an important role in defining and reconfiguring the role of citizens within local governance

First-order super-radiant phase transitions in a multi-qubit--cavity system

We predict the existence of novel first-order phase transitions in a general class of multi-qubit-cavity systems. Apart from atomic systems, the associated super-radiant phase transition should be observable in a variety of solid-state experimental systems, including the technologically important case of interacting quantum dots coupled to an optical cavity mode.Comment: To appear in Phys. Rev. Let

Quantum measurements without macroscopic superpositions

We study a class of quantum measurement models. A microscopic object is entangled with a macroscopic pointer such that each eigenvalue of the measured object observable is tied up with a specific pointer deflection. Different pointer positions mutually decohere under the influence of a bath. Object-pointer entanglement and decoherence of distinct pointer readouts proceed simultaneously. Mixtures of macroscopically distinct object-pointer states may then arise without intervening macroscopic superpositions. Initially, object and apparatus are statistically independent while the latter has pointer and bath correlated according to a metastable local thermal equilibrium. We obtain explicit results for the object-pointer dynamics with temporal coherence decay in general neither exponential nor Gaussian. The decoherence time does not depend on details of the pointer-bath coupling if it is smaller than the bath correlation time, whereas in the opposite Markov regime the decay depends strongly on whether that coupling is Ohmic or super-Ohmic.Comment: 50 pages, 5 figures, changed conten

Solar Energy Systems for Lunar Oxygen Generation

An evaluation of several solar concentrator-based systems for producing oxygen from lunar regolith was performed. The systems utilize a solar concentrator mirror to provide thermal energy for the oxygen production process. Thermal energy to power a Stirling heat engine and photovoltaics are compared for the production of electricity. The electricity produced is utilized to operate the equipment needed in the oxygen production process. The initial oxygen production method utilized in the analysis is hydrogen reduction of ilmenite. Utilizing this method of oxygen production a baseline system design was produced. This baseline system had an oxygen production rate of 0.6 kg/hr with a concentrator mirror size of 5 m. Variations were performed on the baseline design to show how changes in the system size and process (rate) affected the oxygen production rate. An evaluation of the power requirements for a carbothermal lunar regolith reduction reactor has also been conducted. The reactor had a total power requirement between 8,320 to 9,961 W when producing 1000 kg/year of oxygen. The solar concentrator used to provide the thermal power (over 82 percent of the total energy requirement) would have a diameter of less than 4 m