18,988 research outputs found
Particle Filter Design Using Importance Sampling for Acoustic Source Localisation and Tracking in Reverberant Environments
Sequential Monte Carlo methods have been recently proposed to deal with the problem of acoustic source localisation and tracking using an array of microphones. Previous implementations make use of the basic bootstrap particle filter, whereas a more general approach involves the concept of importance sampling. In this paper, we develop a new particle filter for acoustic source localisation using importance sampling, and compare its tracking ability with that of a bootstrap algorithm proposed previously in the literature. Experimental results obtained with simulated reverberant samples and real audio recordings demonstrate that the new algorithm is more suitable for practical applications due to its reinitialisation capabilities, despite showing a slightly lower average tracking accuracy. A real-time implementation of the algorithm also shows that the proposed particle filter can reliably track a person talking in real reverberant rooms.This paper was performed while Eric A. Lehmann was working
with National ICT Australia. National ICT Australia
is funded by the Australian Government’s Department of
Communications, Information Technology, and the Arts,
the Australian Research Council, through Backing Australia’s
Ability, and the ICT Centre of Excellence programs
Detection of X-ray emission from the host clusters of 3CR quasars
We report the detection of extended X-ray emission around several powerful
3CR quasars with redshifts out to 0.73. The ROSAT HRI images of the quasars
have been corrected for spacecraft wobble and compared with an empirical
point-spread function. All the quasars examined show excess emission at radii
of 15 arcsec and more; the evidence being strong for the more distant objects
and weak only for the two nearest ones, which are known from other wavelengths
not to lie in strongly clustered environments. The spatial profiles of the
extended component is consistent with thermal emission from the intracluster
medium of moderately rich host clusters to the quasars. The total luminosities
of the clusters are in the range 4x10^44 - 3x10^45 erg/s, assuming a
temperature of 4keV. The inner regions of the intracluster medium are, in all
cases, dense enough to be part of a cooling flow.Comment: 21 pages including 4 figures and 4 tables. To be published in MNRA
Preparation, Structure, and Reactivity of Nonstabilized Organoiron Compounds. Implications for Iron-Catalyzed Cross Coupling Reactions
A series of unprecedented organoiron complexes of the formal oxidation states −2, 0, +1, +2, and +3 is presented, which are largely devoid of stabilizing ligands and, in part, also electronically unsaturated (14-, 16-, 17- and 18-electron counts). Specifically, it is shown that nucleophiles unable to undergo β-hydride elimination, such as MeLi, PhLi, or PhMgBr, rapidly reduce Fe(3+) to Fe(2+) and then exhaustively alkylate the metal center. The resulting homoleptic organoferrate complexes [(Me4Fe)(MeLi)][Li(OEt2)]2 (3) and [Ph4Fe][Li(Et2O)2][Li(1,4-dioxane)] (5) could be characterized by X-ray crystal structure analysis. However, these exceptionally sensitive compounds turned out to be only moderately nucleophilic, transferring their organic ligands to activated electrophiles only, while being unable to alkylate (hetero)aryl halides unless they are very electron deficient. In striking contrast, Grignard reagents bearing alkyl residues amenable to β-hydride elimination reduce FeXn (n = 2, 3) to clusters of the formal composition [Fe(MgX)2]n. The behavior of these intermetallic species can be emulated by structurally well-defined lithium ferrate complexes of the type [Fe(C2H4)4][Li(tmeda)]2 (8), [Fe(cod)2][Li(dme)]2 (9), [CpFe(C2H4)2][Li(tmeda)] (7), [CpFe(cod)][Li(dme)] (11), or [Cp*Fe(C2H4)2][Li(tmeda)] (14). Such electron-rich complexes, which are distinguished by short intermetallic Fe−Li bonds, were shown to react with aryl chlorides and allyl halides; the structures and reactivity patterns of the resulting organoiron compounds provide first insights into the elementary steps of low valent iron-catalyzed cross coupling reactions of aryl, alkyl, allyl, benzyl, and propargyl halides with organomagnesium reagents. However, the acquired data suggest that such C−C bond formations can occur, a priori, along different catalytic cycles shuttling between metal centers of the formal oxidation states Fe(+1)/Fe(+3), Fe(0)/Fe(+2), and Fe(−2)/Fe(0). Since these different manifolds are likely interconnected, an unambiguous decision as to which redox cycle dominates in solution remains difficult, even though iron complexes of the lowest accessible formal oxidation states promote the reactions most effectively
Sulfurization of near stoichiometric CuIn precursor and the influence of low temperature slopes on morphology and structural quality
Facile formation of iodocyclobutenes by a ruthenium-catalyzed enyne cycloisomerization
Enynes bearing an iodide (bromide) at their alkyne terminus react with catalytic amounts of [Cp*Ru(MeCN)3]PF6 in DMF to give strained iodo(bromo)cyclobutene derivatives in good to excellent yields
Fibrational induction meets effects
This paper provides several induction rules that can be used to prove properties of effectful data types. Our results are semantic in nature and build upon Hermida and Jacobs’ fibrational formulation of induction for polynomial data types and its extension to all inductive data types by Ghani, Johann, and Fumex. An effectful data type μ(TF) is built from a functor F that describes data, and a monad T that computes effects. Our main contribution is to derive induction rules that are generic over all functors F and monads T such that μ(TF) exists. Along the way, we also derive a principle of definition by structural recursion for effectful data types that is similarly generic. Our induction rule is also generic over the kinds of properties to be proved: like the work on which we build, we work in a general fibrational setting and so can accommodate very general notions of properties, rather than just those of particular syntactic forms. We give examples exploiting the generality of our results, and show how our results specialize to those in the literature, particularly those of Filinski and Støvring
Elementary Steps in Gold Catalysis: The Significance of gem-Diauration
Disturbing neighbors: Alkenylgold species with a heteroatom substituent are thought to be key intermediates in gold-catalyzed trans additions of protic nucleophiles to alkynes. One reason for the scarcity of such compounds lies in the non-innocence of the neighboring heteroatom, which may enforce the uptake of a second gold fragment with formation of surprisingly robust species with a gem-digold unit adjacent to a largely cationic center
Proton Lifetime and Baryon Number Violating Signatures at the LHC in Gauge Extended Models
There exist a number of models in the literature in which the weak
interactions are derived from a chiral gauge theory based on a larger group
than SU(2)_L x U(1)_Y. Such theories can be constructed so as to be
anomaly-free and consistent with precision electroweak measurements, and may be
interpreted as a deconstruction of an extra dimension. They also provide
interesting insights into the issues of flavor and dynamical electroweak
symmetry breaking, and can help to raise the mass of the Higgs boson in
supersymmetric theories. In this work we show that these theories can also give
rise to baryon and lepton number violating processes, such as nucleon decay and
spectacular multijet events at colliders, via the instanton transitions
associated with the extended gauge group. For a particular model based on
SU(2)_1 x SU(2)_2, we find that the violating scattering cross sections
are too small to be observed at the LHC, but that the lower limit on the
lifetime of the proton implies an upper bound on the gauge couplings.Comment: 36 page
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Profoundly reduced neovascularization capacity of bone marrow mononuclear cells derived from patients with chronic ischemic heart disease
Background— Cell therapy with bone marrow–derived stem/progenitor cells is a novel option for improving neovascularization and cardiac function in ischemic heart disease. Circulating endothelial progenitor cells in patients with coronary heart disease are impaired with respect to number and functional activity. However, whether this impairment also extends to bone marrow–derived mononuclear cells (BM-MNCs) in patients with chronic ischemic cardiomyopathy (ICMP) is unclea
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