16 research outputs found
Composés à groupement redox, leur utilisation comme additif d'électrolyte, composition d'électrolyte et systèmes électrochimiques les contenant
In situ redox functionalization of composite electrodes for high power-high energy electrochemical storage systems via a non-covalent approach
The growing demand for new global resources of clean and sustainable energy emerges as the greatest challenge in today\u27s society. For numerous applications such as hybrid vehicles, electrochemical storage systems simultaneously require high energy and high power. For this reason, intensive researches focus on proposing alternative devices to conventional Li battery and supercapacitors. Here, we report a proof of concept based on non-covalent redox functionalization of composite electrodes that may occur either during the calendar life or during the device functioning. The active material, a multi-redox pyrene derivative, is initially contained in the electrolyte. No additional benchmarking step is therefore required, and it can, in principle, be readily applied to any type of composite electrode (supercapacitors, battery, semi-solid flow cell etc.). Accordingly, a practical carbon fiber electrode that is 10 mg cm(-2) loaded can deliver up to 130 kW kg(electrode)(-1) and 130 Wh kg(electrode)(-1) with negligible capacity loss over the first 60 000 charge/discharge cycles
New Concept to Boost Energy and Power Peformance of Practical Electrochemical Devices
International audienc
New concept and electrochemistry of in situ non-covalent immobilization of redox molecules for energy storage applications
International audienc