1,753 research outputs found
Special issue on materials development by additive manufacturing techniques
Additive manufacturing (AM) processes are steadily gaining attention from many industrial fields, as they are revolutionizing components' designs and production lines. However, the full application of these technologies to industrial manufacturing has to be supported by the study of the AM materials' properties and their correlations with the feedstock and the building conditions. Furthermore, nowadays, only a limited number of materials processable by AM are available on the market. It is, therefore, fundamental to widen the materials' portfolio and to study and develop new materials that can take advantage of these unique building processes. The present special issue collects recent research activities on these topics
Microstructure and hardness evolution of solution annealed inconel 625/TiC composite processed by laser powder bed fusion
This study deals with the Inconel 625 (IN625) alloy reinforced with micro-TiC particles processed by laser powder bed fusion. The microstructure and hardness in the as-built and solution-annealed states were investigated. The microstructures of the as-built IN625 and IN625/TiC states were primarily made up of columnar grains along the building direction. After the solution annealing at 1150 °C for 2 h, the IN625 alloy consisted of equiaxed grains due to recrystallization and grain growth. On the contrary, the solution-annealed IN625/TiC composite still presented columnar grains. Therefore, the TiC particles hinder the recrystallization, indicating higher microstructure stability for the composite. For the IN625/TiC composite, both the reduced alteration of the grains and the more intensive formation of carbides prevent a remarkable hardness reduction in the so-lution-annealed state
Directed energy deposition of AISI 316L stainless steel powder: Effect of process parameters
During Laser Powder-Directed Energy Deposition (LP-DED), many complex phenomena occur. These phenomena, which are strictly related to the conditions used during the building process, can affect the quality of the parts in terms of microstructural features and mechanical behavior. This paper investigates the effect of building parameters on the microstructure and the tensile properties of AISI 316L stainless-steel samples produced via LP-DED. Firstly, the building parameters were selected starting from single scan tracks by studying their morphology and geometrical features. Next, 316L LP-DED bulk samples built with two sets of parameters were characterized in terms of porosity, geometrical accuracy, microstructure, and mechanical properties. The tensile tests data were analyzed using the Voce model and a correlation between the tensile properties and the dislocation free path was found. Overall, the data indicate that porosity should not be considered the unique indicator of the quality of an LP-DED part and that a mechanical characterization should also be performed
Investigating Complex Geometrical Features in LPBF-Produced Parts: A Material-Based Comparison Between Different Titanium Alloys
The Ti–6Al–4V (Ti64) alloy is a well-established material to be processed via laser powder bed fusion (LPBF). Recently,
other α + β titanium alloys are receiving attention, such as Ti–6Al–2Sn–4Zr–6Mo (Ti6246). Their typical industrial fields of
application (aerospace, automotive), often require critical design choices, such as low wall thicknesses and hollow channels.
Thus, a comparative analysis between these two competitor alloys in terms of processability was conducted in this work.
To do so, specific sample designs were developed. The specimens were analyzed in terms of geometrical compliance with
the initial design, porosity, and microstructure. A correlation between the width of the specimens and their porosity, micro-
structure and hardness was found. Overall, both the alloys proved to be well processable, even for very low wall thickness
(300 μm) and channel diameter (1 mm) values. Nevertheless, the Ti6246 alloy seemed to behave better in specific scenarios.
For instance, some Ti64 specimens provided delamination. The hollow channels proved to be challenging for both materi-
als, mainly due to the high amount of residual powder particles adhered to the upper part of the holes. This works aims at
giving a materials perspective on process-related issues, considering the LPBF-induced defectology and microstructural
variations in these Ti alloys
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Business model responses to digital piracy
Digital piracy challenges firms by reducing revenues and shifting consumption habits. Recently, some firms have successfully leveraged business models against piracy, but the understanding about this phenomenon still lacks depth and structure. This study examines the characteristics of digital piracy in some of the most affected industries, presents comparative case studies of two iconic firms, Spotify and Netflix, and analyzes their digital business model responses. We generalize their adoption to generic digital content distributors and explain how they contribute to generate and capture value. Theoretical and practical implications for technological innovation, firm diversification, and network competition are also discussed
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Driving performance via exploration in changing environments: Evidence from Formula One racing
Until recently, scholars have customarily lumped multiple dimensions of environmental change into single constructs, and usually ascertained that the more the context changes, the more value firms derive from higher levels of exploration. In sync with more recent studies focusing on specific dimensions of change, in this paper we borrow theoretical elements from systems theory to examine the possibility that the reward to developing innovative product components may itself be eroded by implicit and yet burgeoning costs to fit the new component technology into existing architectures, thereby dampening system performance. Specifically, we theoretically assess how varying magnitudes of industry regulatory changes affect the optimum level of firm exploration, and propose—counter-intuitively vis-à -vis past literature—that the more radical (i.e., competence-destroying), as opposed to incremental (i.e., competence-enhancing) these changes are, the more the optimum intensity of firm exploration recedes. Based on quantitative as well as qualitative empirical analyses from the Formula One racing industry, we precisely trace the observed performance outcomes back to the underlying logic of our theory, stressing that impaired capabilities to integrate the new component in the architecture re-design, as well as time-based cognitive limitations both operate to inhibit the otherwise positive relationship between firm exploration and performance. In the end, we offer new insights to theory and practice
Processability and Microstructural Evolution of W360 Hot Work Tool Steel by Directed Energy Deposition
Laser directed energy deposition (L-DED) was used to produce samples of the newly patented W360 hot work tool steel by Böhler. The process parameters were optimized to obtain nearly fully dense samples through the production and analysis of single deposited tracks and single layers. Subsequently, bulk samples underwent a hardening heat treatment, consisting of austenitizing, air quenching, and tempering. The samples were analysed in the as-built condition (AB), after quenching (Q) and following tempering cycles (HT) to observe the microstructural evolution. The microstructure was investigated using optical and scanning electron microscopes, energy dispersive X-ray analysis, and X-ray diffraction analysis. Furthermore, the microstructural evolution was analysed with differential scanning calorimetry, while the mechanical response was evaluated through microhardness test. It was found that the AB samples exhibited a dendritic-cellular microstructure with tempered martensite laths. The thermal history of the AB samples was completely modified by the austenitizing treatment followed by quenching, resulting in a fully martensitic Q sample that did not display the typical dendritic-cellular microstructure of the L-DED process. The completion of the heat treatment with tempering cycles revealed the presence of Mo-rich carbides dispersed in a martensitic matrix. The HT samples exhibited a mean microhardness of 634 HV, remaining constant along the entire building direction from the substrate to the last deposited layer, indicating a homogeneous microstructure. This high value, similar to other hot work tool steels such as H13, makes W360 a very promising candidate for tool build and repair purposes
Surface doping in T6/ PDI-8CN2 Heterostructures investigated by transport and photoemission measurements
In this paper, we discuss the surface doping in sexithiophene (T6) organic
field-effect transistors by PDI-8CN2. We show that an accumulation
heterojunction is formed at the interface between the organic semiconductors
and that the consequent band bending in T6 caused by PDI-8CN2 deposition can be
addressed as the cause of the surface doping in T6 transistors. Several
evidences of this phenomenon have been furnished both by electrical transport
and photoemission measurements, namely the increase in the conductivity, the
shift of the threshold voltage and the shift of the T6 HOMO peak towards higher
binding energies.Comment: 5 pages, 5 figure
BIOLOGICALLY STRUCTURED MATERIALS
Biomimetics, biomechanics, and tissue engineering are three multidisciplinary fields that have been contemplated in this research to attain the objective of improving prosthetic implants reliability. Since testing and mathematical methods are closely interlaced, a promising approach seemed to be the combination of in vitro and in vivo experiments with computer simulations (in silico). An innovative biomimetics and biomechanics approach, and a new synthetic structure providing a microenvironment, which is mechanically coherent and nutrient conducive for tissue osteoblast cell cultures used in regenerative medicine, are presented. The novel hybrid ceramic-polymeric nanocomposites are mutually investigated by finite element analysis (FEA) biomimetic modeling, anatomic reconstruction, quantitative-computed-tomography characterization, computer design of tissue scaffold. The starting base materials are a class of innovative highly bioactive hybrid ceramic-polymeric materials set-up by the proponent research group that will be used as a bioactive matrix for the preparation of in situ bio-mineralized techno- structured porous nanocomposites. This study treats biomimetics, biomechanics and tissue engineering as strongly correlated multidisciplinary fields combined to design bone tissue scaffolds. The growth, maintenance, and ossification of bone are fundamental and are regulated by the mechanical cues that are imposed by physical activities: this biomimetic/biomechanical approach will be pursued in designing the experimental procedures for in vitro scaffold mineralization and ossification. Bio-tissue mathematical modeling serves as a central repository to interface design, simulation, and tissue fabrication. Finite element computer analyses will be used to study the role of local tissue mechanics on endochondral ossification patterns, skeletal morphology and mandible thickness distributions using single and multi-phase continuum material representations of clinical cases of patients implanted with the traditional protocols. New protocols will be hypothesized for the use of the new biologically techno-structured hybrid materials
In situ alloying of a modified inconel 625 via laser powder bed fusion: Microstructure and mechanical properties
This study investigates the in situ alloying of a Ni-based superalloy processed by means of laser powder bed fusion (LPBF). For this purpose, Inconel 625 powder is mixed with 1 wt.% of Ti6Al4V powder. The modified alloy is characterized by densification levels similar to the base alloy, with relative density superior to 99.8%. The material exhibits Ti-rich segregations along the melt pool contours. Moreover, Ti tends to be entrapped in the interdendritic areas during solidification in the as-built state. After heat treatments, the modified Inconel 625 version presents greater hardness and tensile strengths than the base alloy in the same heat-treated conditions. For the solution annealed state, this is mainly attributed to the elimination of the segregations into the interdendritic structures, thus triggering solute strengthening. Finally, for the aged state, the further increment of mechanical properties can be attributed to a more intense formation of phases than the base alloy, due to elevated precipitation strengthening ability under heat treatments. It is interesting to note how slight chemical composition modification can directly develop new alloys by the LPBF process
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