4,008 research outputs found
Optical transitions and energy relaxation of hot carriers in Si nanocrystals
Dynamics of hot carriers confined in Si nanocrystals is studied theoretically
using atomistic tight binding approach. Radiative, Auger-like and
phonon-assisted processes are considered. The Auger-like energy exchange
between electrons and holes is found to be the fastest process in the system.
However the energy relaxation of hot electron-hole pair is governed by the
single optical phonon emission. For a considerable number of states in small
nanocrystals single-phonon processes are ruled out by energy conservation law.Comment: 3 pages, 4 figure
Cascade-Exciton Model Analysis of Nucleon-Induced Fission Cross Sections of Lead and Bismuth at Energies from 45 to 500 MeV
An extended version of the Cascade-Exciton Model (CEM) of nuclear reactions
is applied to analyze nucleon-induced fission cross sections for Bi-209 and
Pb-208 nuclei in the 45-500 MeV energy range. The available data on linear
momentum transfer are analyzed as well. The results are compared with
analytical approximations resulting from a comparative critical analysis of all
available experimental data. Systematic discrepancies between calculations and
experimental data are revealed. A modification of the CEM is proposed, which
significantly improves the model predictions for projectile energies above 100
MeV.Comment: 38 pages, 16 figures, 7 tables, LaTeX, submitted to Nucl. Sci. En
Detailed Geant4 simulations of the ANITA and ANITA-CUP neutron facilities
Simulations of the ANITA spallation neutron source at The Svedberg Laboratory (TSL) are described. Neutron radiation calculations show close agreement with measurements at both standard and close user positions. Gamma radiation characteristics are also predicted
Energy transfer processes in Er-doped SiO2 sensitized with Si nanocrystals
We present a high-resolution photoluminescence study of Er-doped SiO2
sensitized with Si nanocrystals (Si NCs). Emission bands originating from
recombination of excitons confined in Si NCs and of internal transitions within
the 4f-electron core of Er3+ ions, and a band centered at lambda = 1200nm have
been identified. Their kinetics have been investigated in detail. Based on
these measurements, we present a comprehensive model for energy transfer
mechanisms responsible for light generation in this system. A unique picture of
energy flow between subsystems of Er3+ and Si NCs is developed, yielding truly
microscopic information on the sensitization effect and its limitations. In
particular, we show that most of the Er3+ ions available in the system are
participating in the energy exchange. The long standing problem of apparent
loss of optical activity of majority of Er dopants upon sensitization with Si
NCs is clarified and assigned to appearance of a very efficient energy exchange
mechanism between Si NCs and Er3+ ions. Application potential of SiO2:Er
sensitized by Si NCs is discussed in view of the newly acquired microscopic
insight.Comment: 30 pages 13 figure
Evidence of a bond-nematic phase in LiCuVO4
Polarized and unpolarized neutron scattering experiments on the frustrated
ferromagnetic spin-1/2 chain LiCuVO4 show that the phase transition at HQ of 8
Tesla is driven by quadrupolar fluctuations and that dipolar correlations are
short-range with moments parallel to the applied magnetic field in the
high-field phase. Heat-capacity measurements evidence a phase transition into
this high-field phase, with an anomaly clearly different from that at low
magnetic fields. Our experimental data are consistent with a picture where the
ground state above HQ has a next-nearest neighbour bond-nematic order along the
chains with a fluid-like coherence between weakly coupled chains.Comment: 5 pages, 4 figures. To appear in Phys. Rev. Let
Anisotropic Exchange in LiCuVO probed by ESR
We investigated the paramagnetic resonance in single crystals of LiCuVO
with special attention to the angular variation of the absorption spectrum. To
explain the large resonance linewidth of the order of 1 kOe, we analyzed the
anisotropic exchange interaction in the chains of edge-sharing CuO
octahedra, taking into account the ring-exchange geometry of the
nearest-neighbor coupling via two symmetric rectangular Cu-O bonds. The
exchange parameters, which can be estimated from theoretical considerations,
nicely agree with the parameters obtained from the angular dependence of the
linewidth. The anisotropy of this magnetic ring exchange is found to be much
larger than it is usually expected from conventional estimations which neglect
the bonding geometry. Hence, the data yield the evidence that in copper oxides
with edge-sharing structures the role of the orbital degrees of freedom is
strongly enhanced. These findings establish LiCuVO as one-dimensional
compound at high temperatures.
PACS: 76.30.-v, 76.30.Fc, 75.30.EtComment: 18 pages, 6 figure
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