Impact of Coulomb interaction and Kondo effect on transport in quantum dots

We examine the impact of Coulomb electron-electron interaction on transport in a junction with a quantum dot described by Kondo Hamiltonian. We analyze the Fermi liquid regime and consider the limit of zero temperature. With the help of Keldysh technique we calculate the non-linear current and shot noise as a function of applied voltage. We show that Coulomb interaction markable influences the universal effective charge of current-carrying particles e*=5/3e which can be measured in shot-noise experiments. The electron-electron interaction modifies this universal value by a factor (e*=5/3eF) which is less then one and also voltage dependent.Comment: 6 pages, 5 figures. Revised version with added calculations of shot noise and effectve charge. Complete 1/N expansion is presente

High-order current correlation functions in Kondo systems

We examine the statistics of current fluctuations in a junction with a quantum dot described by Kondo Hamiltonian. With the help of modified Keldish technique we calculate the third current cumulant. As a function of ratio $v=eV/T_{K}$ the 3rd cumulant was obtained for three different regimes: Fermi liquid regime (v>1). Unlike the case of noninteracting dot, 3rd cumulant shows strong non-linear voltage dependence. Only in the asymptotical limit of large voltages the linear dependence on $V$ is recovered.Comment: 5 pages, 2 figure

Photosensitized oxidation of unsaturated polymers

The photosensitized oxidation or singlet oxygenation of unsaturated hydrocarbon polymers and of their model compounds was reviewed. Emphasis was on cis and trans forms of 1,4-polyisoprene, 1,4-polybutadiene and 1,2-poly(1,4-hexadiene), and on 1,4-poly(2,3-dimethyl-1,3-butadiene). The microstructural changes which occur in these polymers on reaction with O2-1 in solution were investigated by infrared H-1 and C-13 NMR spectroscopy. The polymers were shown to yield allylic hydroperoxides with shifted double bonds according to the ene mechanism established for simple olefins. The photosensitized oxidation of the above unsaturated polymer exhibited zero order kinetics, the relative rates paralleling the reactivities of the corresponding simple olefins towards O2-1

Vacuum ultraviolet irradiation of polybutadiene final report

Vacuum ultraviolet irradiation of polybutadien

Photochemistry of unsaturated polymers

Radiation induced photochemical reactions in polyisoprene and polybutadiene thin films including microstructural change

Informality, Trade Policies And Smuggling In West Africa

In West Africa, recorded intra-regional trade is small but informal cross-border trade (ICBT) is pervasive, despite regional integration schemes intended to promote official trade. We argue that ICBT must be understood in light of two features of West African national boundaries: divergent economic policies between neighboring countries and the ease with which informal operators can ship goods across borders. We focus on two ICBT clusters: Senegal–The Gambia and Nigeria–Benin–Togo. Nigeria and Senegal have protected their domestic industries with high import barriers, whereas Benin, Togo and The Gambia have maintained lower import taxation. These differential trade policies, together with high mobility of goods and people across borders, lead to widespread smuggling, with goods imported legally in low-tax countries and re-exported unofficially to countries with higher import duties

Waste streams in a typical crewed space habitat: An update

A compilation of generation rates and chemical compositions of potential waste streams in a typical crewed space habitat, reported in a prior NASA Technical Memorandum and a related journal article, was updated. This report augments that compilation by the inclusion of the following new data: those data uncovered since completion of the prior report; those obtained from Soviet literature relevant to life support issues; and those for various minor human body wastes not presented previously (saliva, flatus, hair, finger- and toenails, dried skin and skin secretions, tears, and semen), but included here for purposes of completeness. These waste streams complement those discussed previously: toilet waste (urine, feces, etc.), hygiene water (laundry, shower/handwash, dishwasher water and cleansing agents), trash, humidity condensate, perspiration and respiration water, trace contaminants, and dust generation. This report also reproduces the latest information on the environmental control and life support system design parameters for Space Station Freedom

Generation rates and chemical compositions of waste streams in a typical crewed space habitat

A judicious compilation of generation rates and chemical compositions of potential waste feed streams in a typical crewed space habitat was made in connection with the waste-management aspect of NASA's Physical/Chemical Closed-Loop Life Support Program. Waste composition definitions are needed for the design of waste-processing technologies involved in closing major life support functions in future long-duration human space missions. Tables of data for the constituents and chemical formulas of the following waste streams are presented and discussed: human urine, feces, hygiene (laundry and shower) water, cleansing agents, trash, humidity condensate, dried sweat, and trace contaminants. Tables of data on dust generation and pH values of the different waste streams are also presented and discussed