Diels-Alder reactions using in situ generated quinones

High-yield syntheses of Diels-Alder adducts involving dienes and unstable quinones can be effected by generating the quinone in the presence of the diene with silver oxide

Conversion of lactones into ethers

Although tetrahydrofurans and tetrahydropyrans are important structural subunits of many classes of natural products,l comparatively few general synthetic methods are known? Since y- and &lactones are readily available: an efficient and versatile transformation to the ether would significantly extend current methodology. The conversion of a lactone to an ether has been accomplished by hydride reduction to a diol followed by cyclization by way of a monotosylate4 or other activated ester.

Determination of the eta'-proton scattering length in free space

Taking advantage of both the high mass resolution of the COSY-11 detector and the high energy resolution of the low-emittance proton-beam of the Cooler Synchrotron COSY we determine the excitation function for the pp --> pp eta' reaction close-to-threshold. Combining these data with previous results we extract the scattering length for the eta'-proton potential in free space to be Re(a_{p eta'}) = 0+-0.43 fm and Im(a_{p eta'}) = 0.37(+0.40)(-0.16) fm.Comment: 5 pages, 3 figures, accepted for publication in Phys. Rev. Let

Associated strangeness production in pp collisions near threshold

Motivated by the ongoing discussion concerning the nature of the scalar resonances f0(980) and a0(980), the COSY-11 collaboration has taken exclusive data on the pp->ppK+K- reaction near the production threshold. A first total cross section sigma=(1.80+-0.27+0.28-0.35)nb for the excess energy Q=17 MeV has been determined. In contrary to the eta, omega and eta' single meson production studies which clearly show the strong pp final state interaction (FSI), the cross section values obtained at COSY-11 and DISTO can be both described by a fit with a four-body phase space including the proton-proton final state interaction as well as with one-meson exchange calculations neglecting FSI effects. Therefore, one might think about a compensation of the strong pp interaction through a pK- FSI effect or an additional degree of freedom caused by the four-body final state. In the latter case, strong FSI effects can be expected at Q-values very close to the K+K- production threshold. Such a motivation triggered -- in combination with the investigation of the kaon-Antikaon interaction being relevant to the structure of the f0(980) -- further measurements at the excess energies Q=10 and Q=28 MeV at COSY-11.Comment: 5 pages, 4 figures, Presented at X. International Conference On Hadron Spectroscopy (Hadron 2003), Aschaffenburg, Germany, 31 Aug - 6 Sep 200

General thoughts to the Kaon pair production in the threshold region

Simple--minded thoughts about the cross sections for the reactions pp-->ppK+K- and pp-->ppK0K0 are presented, which certainly do not account for the complex coupled channel problem but rather provide some ideas into the mutual reaction dynamics.Comment: Talk given at 9th International Workshop on Meson Production, Properties and Interaction, Cracow, Poland, 9-13 June 2006. 3 pages, 2 figure