Spontaneous thermal expansion of nematic elastomers

We study the monodomain (single-crystal) nematic elastomer materials, all side-chain siloxane polymers with the same mesogenic groups and crosslinking density, but differing in the type of crosslinking. Increasing the proportion of long di-functional segments of main-chain nematic polymer, acting as network crosslinking, results in dramatic changes in the uniaxial equilibrium thermal expansion on cooling from isotropic phase. At higher concentration of main chains their behaviour dominates the elastomer properties. At low concentration of main-chain material, we detect two distinct transitions at different temperatures, one attributed to the main-chain, the other to the side-chain component. The effective uniaxial anisotropy of nematic rubber, r(T) proportional to the effective nematic order parameter Q(T), is given by the average of the two components and thus reflects the two-transition nature of thermal expansion. The experimental data is compared with the theoretical model of ideal nematic elastomers; applications in high-amplitude thermal actuators are discussed in the end

UV-isomerisation in nematic elastomers as a route to photo-mechanical transducer

The macroscopic shape of liquid crystalline elastomers strongly depends on the order parameter of the mesogenic groups. This order can be manipulated if photoisomerisable groups, e.g. containing N=N bonds, are introduced into the material. We have explored the large photo-mechanical response of such an azobenzene-containing nematic elastomer at different temperatures, using force and optical birefringence measurements, and focusing on fundamental aspects of population dynamics and the related speed and repeatability of the response. The characteristic time of ``on'' and ``off'' regimes strongly depends on temperature, but is generally found to be very long. We were able to verify that the macroscopic relaxation of the elastomer is determined by the nematic order dynamics and not, for instance, by the polymer network relaxation.Comment: Latex (EPJE class) 12 figure

Fast microwave-assisted oxidation of 1,4-dihydropyridines with FeCl 3.SiO 2

Pyridine derivatives are easily obtained in high yields by microwave-promoted rapid oxidation of the corresponding 1,4-dihydropyridines with ferric chloride hexahydrate and silica gel under solvent-free conditions

Nematic elastomers with aligned carbon nanotubes: new electromechanical actuators

We demonstrate, for the first time, the large electromechanical response in nematic liquid crystalline elastomers filled with a very low (~0.01%) concentration of carbon nanotubes, aligned along the nematic director at preparation. The nanotubes create a very large effective dielectric anisotropy of the composite. Their local field-induced torque is transmitted to the rubber-elastic network and is registered as the exerted uniaxial stress of order ~1kPa in response to a constant field of order ~1MV/m. We investigate the dependence of the effect on field strength, nanotube concentration and reproducibility under multiple field-on and -off cycles. The results indicate the potential of the nanotube-nematic elastomer composites as electrically driven actuators

Photonic gaps in cholesteric elastomers under deformation

Cholesteric liquid crystal elastomers have interesting and potentially very useful photonic properties. In an ideal monodomain configuration of these materials, one finds a Bragg-reflection of light in a narrow wavelength range and a particular circular polarization. This is due to the periodic structure of the material along one dimension. In many practical cases, the cholesteric rubber possesses a sufficient degree of quenched disorder, which makes the selective reflection broadband. We investigate experimentally the problem of how the transmittance of light is affected by mechanical deformation of the elastomer, and the relation to changes in liquid crystalline structure. We explore a series of samples which have been synthesized with photonic stop-gaps across the visible range. This allows us to compare results with detailed theoretical predictions regarding the evolution of stop-gaps in cholesteric elastomers

Investigation of poly(2-methoxy-5-(2 '-ethylhexyloxy)-1,4-phenylenevinylene) prepared via a chloro precursor route

We report the characterisation of an insoluble MEHPPV (I-MEHPPV) prepared via a chloro precursor route. Optical absorption and emission spectra are discussed with reference to those of the common soluble variant. PL quantum efficiencies are also reported. Results obtained for single ITO/I-MEHPPV/A1 and double layer ITO/I-MEHPPV/electron transport layer (ETL)/A1 LED structures are discussed. Peak luminances of 800cd/m(2) are found for the multilayer device and a peak EL external quantum efficiency of 0.1 1% (power conversion efficiency of 1.5x10(-5)W/W) is obtained

Critical fluctuations and random-anisotropy glass transition in nematic elastomers

We carry out a detailed deuterium NMR study of local nematic ordering in polydomain nematic elastomers. This system has a close analogy to the random-anisotropy spin glass. We find that, in spite of the quadrupolar nematic symmetry in 3-dimensions requiring a first-order transition, the order parameter in the quenched ``nematic glass'' emerges via a continuous phase transition. In addition, by a careful analysis of the NMR line shape, we deduce that the local director fluctuations grow in a critical manner around the transition point. This could be the experimental evidence for the Aizenman-Wehr theorem about the quenched impurities changing the order of discontinuous transition

Phase chirality and stereo-selective swelling of cholesteric elastomers

Cholesteric elastomers possess a macroscopic ``phase chirality'' as the director n rotates in a helical fashion along an optical axis $z$ and can be described by a chiral order parameter. This parameter can be tuned by changing the helix pitch p and/or the elastic properties of the network. The cholesterics also possess a local nematic order, changing with temperature or during solvent swelling. In this paper, by measuring the power of optical rotation, we discover how these two parameters vary as functions of temperature or solvent adsorbed by the network. The main result is a finding of pronounced stereo-selectivity of cholesteric elastomers, demonstrating itself in the retention of the ``correct'' chirality component of a racemic solvent. It has been possible to quantify the amount of such stereo-separation, as the basic dynamics of the effect