1,581 research outputs found
Effect of polymer-polymer interactions on the surface tension of colloid-polymer mixtures
The density profile and surface tension for the interface of phase-separated
colloid-polymer mixtures have been studied in the framework of the square
gradient approximation for both ideal and interacting polymers in good solvent.
The calculations show that in the presence of polymer-polymer excluded volume
interactions the interfaces have lower widths and surface tensions compared to
the case of ideal polymers. These results are a direct consequence of the
shorter range and smaller depth of the depletion potential between colloidal
particles induced by interacting polymers.Comment: 12 pages, 5 figures, accepted for J. Chem. Phy
Structure and correlation effects in semiconducting SrTiO₃
We have investigated the effects of structure change and electron correlation on SrTiO₃ single crystals using angle-resolved photoemission spectroscopy. We show that the cubic to tetragonal phase transition at 105 K is manifested by a charge transfer from in-plane (dyz and dzx) bands to out-of-plane (dxy) band, which is opposite to the theoretical predictions. Along this second-order phase transition, we find a smooth evolution of the quasiparticle strength and effective masses. The in-plane band exhibits a peak-dip-hump lineshape, indicating a high degree of correlation on a relatively large (170 meV) energy scale, which is attributed to the polaron formation
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Polarization control at the microscopic and electronic structure observatory
The new Microscopic and Electronic Structure Observatory (MAESTRO) at the Advanced Light Source (ALS) in Berkeley provides X-rays of variable polarization, produced by an elliptically polarized undulator (EPU), for angle resolved photoemission (ARPES) and photoemission electron microscopy (PEEM) experiments. The interpretation of photoemission data, in particular of dichroism effects in ARPES, requires the precise knowledge of the exact polarization state. Numerical simulations show that the first harmonics of the EPU at MAESTRO provides soft X-rays of almost 100% on axis polarization. However, the higher harmonics as well as the downstream optical elements of the beamline, have a considerable impact on the polarization of the light delivered to the experimental end-station. Employing a simple reflective polarimeter, the polarization is characterized for variable EPU and beamline settings and the overall degree of polarization in the MAESTRO end-stations is estimated to be on the order of 83%
Cluster sum rules for three-body systems with angular-momentum dependent interactions
We derive general expressions for non-energy weighted and energy-weighted
cluster sum rules for systems of three charged particles. The interferences
between pairs of particles are found to play a substantial role. The
energy-weighted sum rule is usually determined by the kinetic energy operator,
but we demonstrate that it has similar additional contributions from the
angular momentum and parity dependence of two- and three-body potentials
frequently used in three-body calculations. The importance of the different
contributions is illustrated with the dipole excitations in He. The results
are compared with the available experimental data.Comment: 11 pages, 3 figures, 2 table
Charge fluctuations in nano-scale capacitors
The fluctuations of the charge on an electrode contain information on the
microscopic correlations within the adjacent fluid and their effect on the
electronic properties of the interface. We investigate these fluctuations using
molecular dynamics simulations in a constant-potential ensemble with histogram
reweighting techniques. This approach offers in particular an efficient,
accurate and physically insightful route to the differential capacitance that
is broadly applicable. We demonstrate these methods with three different
capacitors: pure water between platinum electrodes, and a pure as well as a
solvent-based organic electrolyte each between graphite electrodes. The total
charge distributions with the pure solvent and solvent-based electrolytes are
remarkably Gaussian, while in the pure ionic liquid the total charge
distribution displays distinct non-Gaussian features, suggesting significant
potential-driven changes in the organization of the interfacial fluid
Visualizing Atomic-Scale Negative Differential Resistance in Bilayer Graphene
We investigate the atomic-scale tunneling characteristics of bilayer graphene on silicon carbide using the scanning tunneling microscopy. The high-resolution tunneling spectroscopy reveals an unexpected negative differential resistance (NDR) at the Dirac energy, which spatially varies within the single unit cell of bilayer graphene. The origin of NDR is explained by two near-gap van Hove singularities emerging in the electronic spectrum of bilayer graphene under a transverse electric field, which are strongly localized on two sublattices in different layers. Furthermore, defects near the tunneling contact are found to strongly impact on NDR through the electron interference. Our result provides an atomic-level understanding of quantum tunneling in bilayer graphene, and constitutes a useful step towards graphene-based tunneling devices. DOI: 10.1103/PhysRevLett.110.036804X11109sciescopu
Molecular hydrodynamics from memory kernels
The memory kernel for a tagged particle in a fluid, computed from molecular dynamics simulations, decays algebraically as t−3/2. We show how the hydrodynamic Basset-Boussinesq force naturally emerges from this long-time tail and generalize the concept of hydrodynamic added mass. This mass term is negative in the present case of a molecular solute, which is at odds with incompressible hydrodynamics predictions. Lastly, we discuss the various contributions to the friction, the associated time scales, and the crossover between the molecular and hydrodynamic regimes upon increasing the solute radius
Dirac dispersion and non-trivial Berry's phase in three-dimensional semimetal RhSb3
We report observations of magnetoresistance, quantum oscillations and
angle-resolved photoemission in RhSb, a unfilled skutterudite semimetal
with low carrier density. The calculated electronic band structure of RhSb
entails a quantum number in analogy to
strong topological insulators, and inverted linear valence/conduction bands
that touch at discrete points close to the Fermi level, in agreement with
angle-resolved photoemission results. Transport experiments reveal an
unsaturated linear magnetoresistance that approaches a factor of 200 at 60 T
magnetic fields, and quantum oscillations observable up to 150~K that are
consistent with a large Fermi velocity ( ms), high
carrier mobility ( /Vs), and small three dimensional hole pockets
with nontrivial Berry phase. A very small, sample-dependent effective mass that
falls as low as bare masses scales with Fermi velocity, suggesting
RhSb is a new class of zero-gap three-dimensional Dirac semimetal.Comment: 9 pages, 4 figure
Semi-relativistic description of quasielastic neutrino reactions and superscaling in a continuum shell model
The so-called semi-relativistic expansion of the weak charged current in
powers of the initial nucleon momentum is performed to describe
charge-changing, quasielastic neutrino reactions at
intermediate energies. The quality of the expansion is tested by comparing with
the relativistic Fermi gas model using several choices of kinematics of
interest for ongoing neutrino oscillation experiments. The new current is then
implemented in a continuum shell model together with relativistic kinematics to
investigate the scaling properties of and cross
sections.Comment: 33 pages, 10 figures, to appear in PR
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