602 research outputs found
Dielectric behavior of Copper Tantalum Oxide
A thorough investigation of the dielectric properties of Cu2Ta4O12, a
material crystallizing in a pseudo-cubic, perovskite-derived structure is
presented. We measured the dielectric constant and conductivity of single
crystals in an exceptionally broad frequency range up to GHz frequencies and at
temperatures from 25 - 500 K. The detected dielectric constant is unusually
high (reaching values up to 105) and almost constant in a broad frequency and
temperature range. Cu2Ta4O12 possesses a crystal structure similar to
CaCu3Ti4O12, the compound for which such an unusually high dielectric constant
was first observed. An analysis of the results using a simple equivalent
circuit and measurements with different types of contact revealed that
extrinsic interfacial polarization effects, derived from surface barrier
capacitors are the origin of the observed giant dielectric constants. The
intrinsic properties of Cu2Ta4O12 are characterized by a (still relatively
high) dielectric constant in the order of 100 and by charge transport via
hopping conduction of Anderson-localized charge carriers.Comment: 18 pages, 6 figures, submitted to Jouranl of Physical Chemestr
Modelling and filtering almost periodic signals by time-varying fourier series with application to near-infrared spectroscopy
We propose a new approach to modelling almost periodic signals and to model-based estimation of such signals from noisy observations. The signal model is based on Fourier series where both the coefficients and the fundamental frequency can continuously change over time. This signal model can be represented by a factor graph which we use to derive message passing algorithms to estimate the time-dependent model parameters from the observed samples
Evidence for a Ru Kondo Lattice in LaCuRuO
Rare -electron derived heavy-fermion properties of the solid-solution
series LaCuRuTiO were studied for by
resistivity, susceptibility, specific-heat measurements, and magnetic-resonance
techniques. The pure ruthenate () is a heavy-fermion metal characterized
by a resistivity proportional to at low temperatures . The coherent
Kondo lattice formed by the localized Ru 4 electrons is screened by the
conduction electrons leading to strongly enhanced effective electron masses. By
increasing titanium substitution the Kondo lattice becomes diluted resulting in
single-ion Kondo properties like in the paradigm -based heavy-fermion
compound CeLaCuSi [M. Ocko {\em et al.}, Phys. Rev. B
\textbf{64}, 195106 (2001)]. In LaCuRuTiO the
heavy-fermion behavior finally breaks down on crossing the metal-to-insulator
transition close to .Comment: 9 pages, 8 figure
Transport, magnetic, thermodynamic and optical properties in Ti-doped Sr_2RuO_4
We report on electrical resistivity, magnetic susceptibility and
magnetization, on heat capacity and optical experiments in single crystals of
Sr_2Ru_(1-x)Ti_xO_4. Samples with x=0.1 and 0.2 reveal purely semiconducting
resistivity behavior along c and the charge transport is close to localization
within the ab-plane. A strong anisotropy in the magnetic susceptibility appears
at temperatures below 100 K. Moreover magnetic ordering in c-direction with a
moment of order 0.01 mu_B/f.u. occurs at low temperatures. On doping the
low-temperature linear term of the heat capacity becomes reduced significantly
and probably is dominated by spin fluctuations. Finally, the optical
conductivity reveals the anisotropic character of the dc resistance, with the
in-plane conductance roughly following a Drude-type behavior and an insulating
response along c
Intake of silica nanoparticles by giant lipid vesicles: influence of particle size and thermodynamic membrane state
The uptake of nanoparticles into cells often involves their engulfment by the plasma membrane and a fission of the latter. Understanding the physical mechanisms underlying these uptake processes may be achieved by the investigation of simple model systems that can be compared to theoretical models. Here, we present experiments on a massive uptake of silica nanoparticles by giant unilamellar lipid vesicles (GUVs). We find that this uptake process depends on the size of the particles as well as on the thermodynamic state of the lipid membrane. Our findings are discussed in the light of several theoretical models and indicate that these models have to be extended in order to capture the interaction between nanomaterials and biological membranes correctly
Intake of silica nanoparticles by giant lipid vesicles: influence of particle size and thermodynamic membrane state
The uptake of nanoparticles into cells often involves their engulfment by the plasma membrane and a fission of the latter. Understanding the physical mechanisms underlying these uptake processes may be achieved by the investigation of simple model systems that can be compared to theoretical models. Here, we present experiments on a massive uptake of silica nanoparticles by giant unilamellar lipid vesicles (GUVs). We find that this uptake process depends on the size of the particles as well as on the thermodynamic state of the lipid membrane. Our findings are discussed in the light of several theoretical models and indicate that these models have to be extended in order to capture the interaction between nanomaterials and biological membranes correctly
Cryptosporidium, Enterocytozoon, and Cyclospora Infections in Pediatric and Adult Patients with Diarrhea in Tanzania.
Cryptosporidiosis, microsporidiosis, and cyclosporiasis were studied in four groups of Tanzanian inpatients: adults with AIDS-associated diarrhea, children with chronic diarrhea (of whom 23 of 59 were positive [+] for human immunodeficiency virus [HIV]), children with acute diarrhea (of whom 15 of 55 were HIV+), and HIV control children without diarrhea. Cryptosporidium was identified in specimens from 6/86 adults, 5/59 children with chronic diarrhea (3/5, HIV+), 7/55 children with acute diarrhea (0/7, HIV+), and 0/20 control children. Among children with acute diarrhea, 7/7 with cryptosporidiosis were malnourished, compared with 10/48 without cryptosporidiosis (P < .01). Enterocytozoon was identified in specimens from 3/86 adults, 2/59 children with chronic diarrhea (1 HIV+), 0/55 children with acute diarrhea, and 4/20 control children. All four controls were underweight (P < .01). Cyclospora was identified in specimens from one adult and one child with acute diarrhea (HIV-). Thus, Cryptosporidium was the most frequent and Cyclospora the least frequent pathogen identified. Cryptosporidium and Enterocytozoon were associated with malnutrition. Asymptomatic fecal shedding of Enterocytozoon in otherwise healthy, HIV children has not been described previously
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