70 research outputs found
Dealloying of Cobalt from CuCo Nanoparticles under Syngas Exposure
International audienceThe structure and composition of core−shell CuCo nanoparticles were found to change as a result of cleaning pretreatments and when exposed to syngas (CO + H 2) at atmospheric pressure. In situ X-ray absorption and photoelectron spectroscopies revealed the oxidation state of the particles as well as the presence of adsorbates under syngas. Transmission electron microscopy was used for ex situ analysis of the shape, elemental composition, and structure after reaction. The original core−shell structure was found to change to a hollow CuCo alloy after pretreatment by oxidation in pure O 2 and reduction in pure H 2. After 30 min of exposure to syngas, a significant fraction (5%) of the particles was strongly depleted in cobalt giving copper-rich nanoparticles. This fraction increased with duration of syngas exposure, a phenomenon that did not occur under pure CO or pure H 2. This study suggests that Co and Cu can each individually contribute to syngas conversion with CuCo catalysts
Omnidirectional Vision for Monitoring of Traffic in Urban Environment
International audienceno abstrac
Computer-Assisted Elaboration of Job Histories
AbstractThree ways are proposed to help the occupational physician in constructing a worker’s job history or Curriculum Laboris (CL) with a PC. The quality and, therefore, the usefulness of any job history is greatly conditioned by the method and quality of data collection. The Curriculum Laboris method explained in a previous article has been briefly summarized as a basis of departure. Then, the workers who were submitted to special medical surveillance were considered. After this, the scrolling menu technique was applied in the elaboration of a job history. Finally, the authors show how the representation of company organization by means of a job exposure matrix (JEM) can help to efficiently elaborate job histories.</jats:p
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