MATERIAL CHARACTERISATION OF A FLORENTINE PAINTER IN PORTUGAL IN THE LATE 19TH CENTURY: PAINTINGS BY GIORGIO MARINI

This paper presents the analytical characterisation of a series of paintings authored by Giorgio Marini (1836-1905) from the Museum of Évora. Marini was an Italian painter who lived in Portugal in the 19th century. He was a very prolific painter and his works, most of them portraits commissioned by urban and rural bourgeois and noble elites, are dispersed all over the country. The general good conservation state of most paintings prevented the collection of micro-samples for detailed study. Hence, material identification of the painting materials was performed primarily by XRF, given its non-destructive and non-invasive nature, and it was complemented when possible by auxiliary techniques optical microscopy, Raman spectroscopy, and SEM-EDX. Pigments and fillers such as yellow and red ochre, lead white, zinc white, barium white, chrome yellow and green chrome are among the identified pigments. This is the first time the palette used by Giorgio Marini was identified, helping to characterised the pigments used by foreign painters during the 19th century in Portuga

Biocontrol of Rust Fungi by Cladosporium tenuissimum

This chapter examines whether Cladosporium tenuissimum Cooke, a destructive hyperparasite of rust spores, can be exploited as a BCA of rust fungi. It reports on tests carried out to evaluate C. tenuissimum effectiveness against rusts in the genera Melampsora, Cronartium, Peridermium, Uromyces and Puccinia, focusing on its modes of action, the fine-level analysis of the fungal host\u2013hyperparasite interface, the antifungal compounds it produces, and its ability to reduce disease, both in vitro and in planta. Since effective biological control is impossible without due consideration of the ecology of the BCA, as well as of the other partners involved, and an examination of their spatial relationships and interaction with the environment, attention is also paid to the biological nature of the fungus, in particular to those characteristics that enable it to survive in natural habitats and retain activity under varying environmental conditions

Status of charcoal canker on oak trees at a site of community importance: case study of the relict castelfidardo forest (Sic area it520008, castelfidardo, an, Italy)

Oaks are dominant and key tree species in Mediterranean forest ecosystems. However, in recent decades, oak forests have been heavily impacted by oak decline, a worldwide phenomenon exacerbated by climate change. The charcoal disease agent Biscogniauxia mediterranea is involved in the decline of Mediterranean oak formations in a variety of contexts. Here, we investigated the impact and role of B. mediterranea in the decline of oaks in Castelfidardo Forest, a relict wood of the late Holocene and a Site of Community Importance. We established five plots within which we recorded tree positions, any symptoms and signs of decline, association of B. mediterranea to declining trees, and deadwood and associated mycota. Of 471 oaks inspected, 7.0% showed brownish exudates on the stems, 46.9% showed epicormic shoots along the main trunk, and 24.4% showed black carbonaceous stromata on diseased branches and trunks. The decline was most severe for Quercus cerris, which comprised plots #4 and #5, at 50.0% (81/162 trees) and 29.0% (33/114), respectively; then for Quercus robur for plot #3, at 40.0% (38/95); and finally for Quercus pubescens for plots #1 and #2, at 13.7% (7/51) and 12.3% (6/49), respectively. Bark tissues were collected from trees with charcoal cankers and taken to the laboratory for microscopic examination and identification by mycological and molecular methods. This investigation revealed a close association between oaks with pronounced reduction of vitality and incidence of B. mediterranea. Deadwood was equally distributed among the five plots, and was heavily colonized by Basidiomycota. The high incidence of the charcoal canker pathogen B. mediterranea appeared to be related to environmental stresses. However, the absence of silvicultural management, high competition among physiologically mature trees, and the geographic isolation of this residual forest may have predisposed oaks to decline

Immobilisation of Higher Activity Wastes from Nuclear Reactor Production of 99

A variety of intermediate- and low-level liquid and solid wastes are produced from reactor production of 99Mo using UAl alloy or UO2 targets and in principle can be collectively or individually converted into waste forms. At ANSTO, we have legacy acidic uranyl-nitrate-rich intermediate level waste (ILW) from the latter, and an alkaline liquid ILW, a U-rich filter cake, plus a shorter lived liquid stream that rapidly decays to low-level waste (LLW) standards, from the former. The options considered consist of cementitious products, glasses, glass-ceramics, or ceramics produced by vitrification or hot isostatic pressing for intermediate-level wastes. This paper discusses the progress in waste form development and processing to treat ANSTO’s ILW streams arising from 99Mo. The various waste forms and the reason for the process option chosen will be reviewed. We also address the concerns over adapting our chosen process for use in a hot-cell environment