64 research outputs found
Theoretical study and experimental result of the RF coupler prototypes of Spiral2
JACoW web site THPCH160International audienceSpiral2 is a 40 MeV-5mA deuterons and a 14.5 MeV/u-1mA heavy ions superconducting linac under construction at GANIL. The RF couplers have to provide 12 kW CW power to the cavities at 88 MHz for an accelerating field of 6.5 MV/m. Two solutions corresponding to two different technologies have been designed and two prototypes have been built. We present the technical proposals ans issues as well as the results (manufacturing, test at low and high power, multipacting...) leading to the final choice
Nanoparticulate TiO2-promoted PtRu/C catalyst for methanol oxidation: TiO2 nanoparticles promoted PtRu/C catalyst for MOR
To improve the electrocatalytic properties of PtRu/C in methanol electrooxidation, nanoparticulate TiO2-promoted PtRu/C catalysts were prepared by directly mixing TiO2 nanoparticles with PtRu/C. Using cyclic voltammetry, it was found that the addition of 10 wt% TiO2 nanoparticles can effectively improve the electrocatalytic activity and stability of the catalyst during methanol electro-oxidation. The value of the apparent activation energy (Ea) for TiO2-PtRu/C was lower than that for pure PtRu/C at a potential range from 0.45 to 0.60 V. A synergistic effect between PtRu and TiO2 nanoparticles is likely to facilitate the removal of CO-like intermediates from the surface of PtRu catalyst and reduce the poisoning of the PtRu catalysts during methanol electrooxidation. Therefore, we conclude that the direct introduction of TiO2 nanoparticles into PtRu/ C catalysts offers an improved facile method to enhance the electrocatalytic performance of PtRu/C catalyst in methanol electrooxidation.Web of Scienc
The GUINEVERE project at the VENUS facility
Proc. on CD Rom log315International audienceThe GUINEVERE project is an international project in the framework of IP-EUROTRANS, the FP6 program which aims at addressing the main issues for ADS development in the framework of partitioning and transmutation for nuclear waste volume and radiotoxicity reduction. The GUINEVERE project is carried out in the context of domain 2 of IP-EUROTRANS, ECATS, devoted to specific experiments for the coupling of an accelerator, a target and a subcritical core. These experiments should provide an answer to the questions of online reactivity monitoring, sub-criticality determination and operational procedures (loading, start-up, shutdown, …) in an ADS by 2009-2010. The project has the objective to couple a fast lead core, within the VENUS building operated by the SCK•CEN, with a neutron generator able to work in three different modes: pulsed, continuous and continuous with beam interruptions at the millisecond scale. In order to achieve this goal, the VENUS facility has to be adapted and a modified GENEPI-3C accelerator has to be designed and constructed. The paper describes the main modifications to the reactor core and facility and to the accelerator, which will be executed during the years 2008 and 2009, and the experimental programme which will start in 2009
Unique CO-tolerance of Pt–WOx materials
Well-defined tungsten-oxide-supported platinum nanoparticles (Pt/WOx) were elaborated by impregnation-reduction of a platinum salt onto commercial monoclinic WO3. Field-emission gun scanning electron microscopy (FEG-SEM) and transmission electron microscopy (TEM) revealed that the Pt particles are well-distributed on the oxide support, present a narrow particle size distribution centered on ca. 2–3 nm and a low degree of agglomeration. Carbon black was added to ensure electronic percolation in the electrodes during the electrochemical measurements. COads electrooxidation currents were monitored at potentials as low as 0.1 V vs. RHE on Pt/WOx, demonstrating high CO-tolerance compared to carbon-supported Pt or PtRu catalysts. Keywords: CO-tolerance, Nanoparticle, Platinum, Tungsten oxide, PEMF
Biological surveillance programme for the monitoring of crop pests and indicators, French devices and European approach compared
Biological surveillance programme for the monitoring of crop pests and indicators in France
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