328 research outputs found

    A Superconductor Made by a Metal Heterostructure at the Atomic Limit Tuned at the "Shape Resonance": MgB2

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    We have studied the variation of Tc with charge density and lattice parameters in Mg1-xAlxB2 superconducting samples at low Al doping x<8%. We show that high Tc occurs where the chemical potential is tuned at a "superconducting shape resonance" near the energy Ec of the quantum critical point (QCP) for the dimensional transition from 2D to 3D electronic structure in a particular subband of the natural superlattice of metallic atomic boron layers. At the "shape resonance" the electrons pairs see a 2D Fermi surface at EF-w0 and a 3D Fermi surface at EF+wo, where wo is the energy cut off of the pairing interaction. The resonant amplification occurs in a narrow energy range where EF-Ec is in the range of 2wo.Comment: 16 page

    Photoionization efficiency spectroscopy and density functional theory investigations of RhHo2On, (n=0-2) clusters

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    The experimental and theoretical adiabatic ionization energies (IEs) of the rhodium-holmium bimetallic clusters RhHo(2)O(n) (n=0-2) have been determined using photoionization efficiency spectroscopy and density functional theory (DFT) calculations. Both sets of data show the IE of RhHo(2)O to be significantly lower than the values for RhHo(2) and RhHo(2)O(2), which are found to be similar. This indicates that there are significant changes in electronic properties upon sequential addition of oxygen atoms to RhHo(2). The DFT investigations show that the lowest energy neutral structures are a C(2v) triangle for RhHo(2), a C(2v) planar structure for RhHo(2)O where the O atom is doubly bridged to the Ho-Ho bond, and a C(2v) nonplanar structure for RhHo(2)O(2), where the O(2) is dissociative and each O atom is doubly bridged to the Ho-Ho bond in the cluster above and below the RhHo(2) trimer plane. Good correlation between the experimental and computational IE data imply that the lowest energy neutral structures calculated are the most likely isomers ionized in the molecular beam. In particular, the theoretical adiabatic IE for the dissociative RhHo(2)O(2) structure is found to compare better with the experimentally determined value than the corresponding lowest energy O(2) associative structure.Alexander S. Gentleman, Matthew A. Addicoat, Viktoras Dryza, Jason R. Gascooke, Mark A. Buntine, and Gregory F. Meth

    New forming method of manufacturing cylindrical parts with nano/ultrafine grained structures by power spinning based on small plastic strains

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    A new spinning method to manufacture the cylindrical parts with nano/ultrafine grained structures is proposed, which consists of quenching, power spinning and recrystallization annealing. The microstructural evolution during the different process stages and macroforming quality of the spun parts made of ASTM 1020 steel are investigated. The results show that the microstructures of the ferrites and pearlites in the ASTM 1020 steel are transformed to the lath martensites after quenching. The martensite laths obtained by quenching are refined to 87 nm and a small amount of nanoscale deformation twins with an average thickness of 20 nm is generated after performing a 3-pass stagger spinning with 55% thinning ratio of wall thickness, where the equivalent strain required is only 0.92. The equiaxial ferritic grains with an average size of 160 nm and nano-carbides are generated by subsequent recrystallization annealing at 480°C for 30 min. The spun parts with high dimensional precision and low surface roughness are obtained by the forming method developed in this work, combining quenching with 3-pass stagger spinning and recrystallization annealing
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