201 research outputs found
Statistical mechanics of permanent random atomic and molecular networks: Structure and heterogeneity of the amorphous solid state
Under sufficient permanent random covalent bonding, a fluid of atoms or small
molecules is transformed into an amorphous solid network. Being amorphous,
local structural properties in such networks vary across the sample. A natural
order parameter, resulting from a statistical-mechanical approach, captures
information concerning this heterogeneity via a certain joint probability
distribution. This joint probability distribution describes the variations in
the positional and orientational localization of the particles, reflecting the
random environments experienced by them, as well as further information
characterizing the thermal motion of particles. A complete solution, valid in
the vicinity of the amorphous solidification transition, is constructed
essentially analytically for the amorphous solid order parameter, in the
context of the random network model and approach introduced by Goldbart and
Zippelius [Europhys. Lett. 27, 599 (1994)]. Knowledge of this order parameter
allows us to draw certain conclusions about the stucture and heterogeneity of
randomly covalently bonded atomic or molecular network solids in the vicinity
of the amorphous solidification transition. Inter alia, the positional aspects
of particle localization are established to have precisely the structure
obtained perviously in the context of vulcanized media, and results are found
for the analogue of the spin glass order parameter describing the orientational
freezing of the bonds between particles.Comment: 31 pages, 5 figure
One-step replica symmetry breaking solution of the quadrupolar glass model
We consider the quadrupolar glass model with infinite-range random
interaction. Introducing a simple one-step replica symmetry breaking ansatz we
investigate the para-glass continuous (discontinuous) transition which occurs
below (above) a critical value of the quadrupole dimension m*. By using a
mean-field approximation we study the stability of the one-step replica
symmetry breaking solution and show that for m>m* there are two transitions.
The thermodynamic transition is discontinuous but there is no latent heat. At a
higher temperature we find the dynamical or glass transition temperature and
the corresponding discontinuous jump of the order parameter.Comment: 10 pages, 3 figure
Universality and its Origins at the Amorphous Solidification Transition
Systems undergoing an equilibrium phase transition from a liquid state to an
amorphous solid state exhibit certain universal characteristics. Chief among
these are the fraction of particles that are randomly localized and the scaling
functions that describe the order parameter and (equivalently) the statistical
distribution of localization lengths for these localized particles. The purpose
of this Paper is to discuss the origins and consequences of this universality,
and in doing so, three themes are explored. First, a replica-Landau-type
approach is formulated for the universality class of systems that are composed
of extended objects connected by permanent random constraints and undergo
amorphous solidification at a critical density of constraints. This formulation
generalizes the cases of randomly cross-linked and end-linked macromolecular
systems, discussed previously. The universal replica free energy is
constructed, in terms of the replica order parameter appropriate to amorphous
solidification, the value of the order parameter is obtained in the liquid and
amorphous solid states, and the chief universal characteristics are determined.
Second, the theory is reformulated in terms of the distribution of local static
density fluctuations rather than the replica order parameter. It is shown that
a suitable free energy can be constructed, depending on the distribution of
static density fluctuations, and that this formulation yields precisely the
same conclusions as the replica approach. Third, the universal predictions of
the theory are compared with the results of extensive numerical simulations of
randomly cross-linked macromolecular systems, due to Barsky and Plischke, and
excellent agreement is found.Comment: 10 pages, including 3 figures (REVTEX
Goldstone fluctuations in the amorphous solid state
Goldstone modes in the amorphous solid state, resulting from the spontaneous
breaking of translational symmetry due to random localisation of particles, are
discussed. Starting from a microscopic model with quenched disorder, the broken
symmetry is identified to be that of relative translations of the replicas.
Goldstone excitations, corresponding to pure shear deformations, are
constructed from long wavelength distortions of the order parameter. The
elastic free energy is computed, and it is shown that Goldstone fluctuations
destroy localisation in two spatial dimensions, yielding a two-dimensional
amorphous solid state characterised by power-law correlations.Comment: 7 pages, 2 figure
Quantal Andreev billiards: Semiclassical approach to mesoscale oscillations in the density of states
Andreev billiards are finite, arbitrarily-shaped, normal-state regions,
surrounded by superconductor. At energies below the superconducting gap,
single-quasiparticle excitations are confined to the normal region and its
vicinity, the essential mechanism for this confinement being Andreev
reflection. This Paper develops and implements a theoretical framework for the
investigation of the short-wave quantal properties of these
single-quasiparticle excitations. The focus is primarily on the relationship
between the quasiparticle energy eigenvalue spectrum and the geometrical shape
of the normal-state region, i.e., the question of spectral geometry in the
novel setting of excitations confined by a superconducting pair-potential.
Among the central results of this investigation are two semiclassical trace
formulas for the density of states. The first, a lower-resolution formula,
corresponds to the well-known quasiclassical approximation, conventionally
invoked in settings involving superconductivity. The second, a
higher-resolution formula, allows the density of states to be expressed in
terms of: (i) An explicit formula for the level density, valid in the
short-wave limit, for billiards of arbitrary shape and dimensionality. This
level density depends on the billiard shape only through the set of
stationary-length chords of the billiard and the curvature of the boundary at
the endpoints of these chords; and (ii) Higher-resolution corrections to the
level density, expressed as a sum over periodic orbits that creep around the
billiard boundary. Owing to the fact that these creeping orbits are much longer
than the stationary chords, one can, inter alia, hear the stationary chords of
Andreev billiards.Comment: 52 pages, 15 figures, 1 table, RevTe
Cavity Approach to the Random Solid State
The cavity approach is used to address the physical properties of random
solids in equilibrium. Particular attention is paid to the fraction of
localized particles and the distribution of localization lengths characterizing
their thermal motion. This approach is of relevance to a wide class of random
solids, including rubbery media (formed via the vulcanization of polymer
fluids) and chemical gels (formed by the random covalent bonding of fluids of
atoms or small molecules). The cavity approach confirms results that have been
obtained previously via replica mean-field theory, doing so in a way that sheds
new light on their physical origin.Comment: 4 pages, 2 figure
Dephasing dynamics of Rydberg atom spin waves
A theory of Rydberg atom interactions is used to derive analytical forms for
the spin wave pair correlation function in laser-excited cold-atom vapors. This
function controls the quantum statistics of light emission from dense,
inhomogeneous clouds of cold atoms of various spatial dimensionalities. The
results yield distinctive scaling behaviors on the microsecond timescale,
including generalized exponential decay. A detailed comparison is presented
with a recent experiment on a cigar-shaped atomic ensemble [Y. Dudin and A.
Kuzmich, Science 336, 887 (2012)], in which Rb atoms are excited to a set of
Rydberg levels.Comment: 4 pages, Supplemental Material in Appendix, 4 figure
Random solids and random solidification: What can be learned by exploring systems obeying permanent random constraints?
In many interesting physical settings, such as the vulcanization of rubber,
the introduction of permanent random constraints between the constituents of a
homogeneous fluid can cause a phase transition to a random solid state. In this
random solid state, particles are permanently but randomly localized in space,
and a rigidity to shear deformations emerges. Owing to the permanence of the
random constraints, this phase transition is an equilibrium transition, which
confers on it a simplicity (at least relative to the conventional glass
transition) in the sense that it is amenable to established techniques of
equilibrium statistical mechanics. In this Paper I shall review recent
developments in the theory of random solidification for systems obeying
permanent random constraints, with the aim of bringing to the fore the
similarities and differences between such systems and those exhibiting the
conventional glass transition. I shall also report new results, obtained in
collaboration with Weiqun Peng, on equilibrium correlations and
susceptibilities that signal the approach of the random solidification
transition, discussing the physical interpretation and values of these
quantities both at the Gaussian level of approximation and, via a
renormalization-group approach, beyond.Comment: Paper presented at the "Unifying Concepts in Glass Physics" workshop,
International Centre for Theoretical Physics, Trieste, Italy (September
15-18, 1999
On the relevance of percolation theory to the vulcanization transition
The relationship between vulcanization and percolation is explored from the
perspective of renormalized local field theory. We show rigorously that the
vulcanization and percolation correlation functions are governed by the same
Gell--Mann-Low renormalization group equation. Hence, all scaling aspects of
the vulcanization transition are reigned by the critical exponents of the
percolation universality class.Comment: 9 pages, 2 figure
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