153 research outputs found
Electronic structure, magnetic and optical properties of intermetallic compounds R2Fe17 (R=Pr,Gd)
In this paper we report comprehensive experimental and theoretical
investigation of magnetic and electronic properties of the intermetallic
compounds Pr2Fe17 and Gd2Fe17. For the first time electronic structure of these
two systems was probed by optical measurements in the spectral range of 0.22-15
micrometers. On top of that charge carriers parameters (plasma frequency and
relaxation frequency) and optical conductivity s(w) were determined.
Self-consistent spin-resolved bandstructure calculations within the
conventional LSDA+U method were performed. Theoretical interpetation of the
experimental s(w) dispersions indicates transitions between 3d and 4p states of
Fe ions to be the biggest ones. Qualitatively the line shape of the theoretical
optical conductivity coincides well with our experimental data. Calculated by
LSDA+U method magnetic moments per formula unit are found to be in good
agreement with observed experimental values of saturation magnetization.Comment: 16 pages, 5 figures, 1 tabl
Ab initio exchange interactions and magnetic properties of Gd2Fe17 iron sublattice: rhombohedral vs. hexagonal phases
In the framework of the LSDA+U method electronic structure and magnetic
properties of the intermetallic compound Gd2Fe17 for both rhombohedral and
hexagonal phases have been calculated. On top of that, ab initio exchange
interaction parameters within the Fe sublattice for all present nearest and
some next nearest Fe ions have been obtained. It was found that for the first
coordination sphere direct exchange interaction is ferromagnetic. For the
second coordination sphere indirect exchange interaction is observed to be
weaker and of antiferromagnetic type. Employing the theoretical values of
exchange parameters Curie temperatures Tc of both hexagonal and rhombohedral
phases of Gd2Fe17 within Weiss mean-field theory were estimated. Obtained
values of Tc and its increase going from the hexagonal to rhombohedral crystal
structure of Gd2Fe17 agree well with experiment. Also for both structures
LSDA+U computed values of total magnetic moment coincide with experimental
ones.Comment: 20 pages, 2 figures; V2 as published in PR
Influence of aluminum impurity on the electronic structure and optical properties of the TbNi5 intermetallic compound
The electronic structure of the TbNi5 - xAlx intermetallic compounds (x = 0, 1, 2) is calculated in the local electron density approximation with the correction to strong electron correlations in 4f shell of terbium ions. Spectral properties of these compounds are measured by ellipsometry in a wavelength range of 0. 22-16 μm. Frequency dependences of optical conductivity in the region of interband optical absorption are interpreted based on the results of calculations of electron densities of states. The relaxation and plasma frequencies of conduction electrons are determined. © 2013 Pleiades Publishing, Ltd
Copper-doping effects in electronic structure and spectral properties of SmNi5
The electronic structure and optical properties of the SmNi5-xCux (x = 0, 1, 2) compounds are studied. The band spectra of the studied intermetallics were calculated with LDA + U + SO method supplementing the local density approximation with a correction for strong electron interaction on the shell of the rare-earth element. Optical properties were studied by ellipsometry method in the wide wavelength range. It was found that the substitution of copper for nickel leads to local changes in the optical conductivity spectra. Both the spectroscopic measurements and theoretical calculations demonstrate the presence of a broad absorption band around 4 eV associated with the Cu 3d → Ni 3d electron transitions and increasing with the grown of copper content. The experimental dispersion curves of optical conductivity in the interband absorption region were interpreted using the results of the calculations. © 2015 AIP Publishing LLC
Magnetic properties of the GdFeSi - GdTiSi solid solutions
The GdFe1-xTixSi, x=0-0.2 intermetallic compounds with a tetragonal crystal structure of the CeFeSi (P4/nmm)-type have been studied. It was obtained that the lattice parameter c and the Curie temperature increase quickly, whereas the lattice parameter a is almost unchanged in the system with increasing of Ti content. The GdFeSi compound is easily magnetized along the [001] axis, the field of magnetic anisotropy equals to ∼3.8 kOe at T = 90 K. The saturation magnetization does not change in the GdFe1-xTi x Si system. © Published under licence by IOP Publishing Ltd.Russian Science Foundation, RSF: 18-72-10098Support by RSF (Project No. 18-72-10098) is acknowledged
The Total Synthesis of Convolutamydine a in the Conditions of the Catalysis by β-Aminoalcohols of Pinane and Carane Structure
This work was supported by the Russian Foundation of Basic Research (grant № 15-03-09352 A)
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