Shelf-Ocean material exchange influencing the Atlantic chemical composition off NW Iberian margin since the last glaciation

Rivers are the main conduit of sediment to the shelf. The basin geology, the drainage area and the discharge rate are the major factors that determine their sediment load (Milliman and Syvistski, 1992). Besides suspended particles, dissolved components may also give some information on the eroded crust. Sr isotopes in carbonate shells of biological organisms have been used to study, in the geological record, the influence exerted by the chemical weathering of the continental crust on the seawater composition (Macdougall, 1991). In this work, Sr isotope ratios obtained in tests of foraminifera representing the last 40 ka are presented and discussed in the scope of the palaeogeographical evolution of NW Iberia. This work aims to present and discuss the results of Sr isotope analyses (performed, by TIMS, in the Isotope Geology Laboratory of the University of Aveiro) of tests of two species of foraminifera, from nine samples taken along the OMEX core KC 024-19 (181 cm; 42°08’98’’N, 10°29´96’’W, and 2765m), collected in the Galicia Bank area, off Galicia. Taking into account that Sr contained in the carbonate tests is usually considered as preserving the signature of the contemporaneous seawater, one planktonic species (Globigerina bulloides) and one benthic species (Cibicides wuellerstorfi) were selected in order to try to detect Sr isotope variations both through time and between two different levels of the water column. The core age model, which records the last 40 ka, is based on a combination of oxygen isotope stratigraphy, eight AMS 14C datings and the synchronisation of the last four Heinrich Events in the Iberian Margin sedimentary records. As a whole, the obtained 87Sr/86Sr ratios vary between 0.709209 and 0.709108, with a mean 2σ error of 0.000025. These values lie within the range of modern marine Sr isotope ratios (0.70910-0.70922), as previously defined using analyses of both seawater and marine carbonates (see compilation by Faure and Mensing, 2005). Despite their small variation, the 87Sr/86Sr ratios obtained in G. bulloides seem to indicate that Sr dissolved in seawater at the KC 024-19 core site became slightly less radiogenic after the Last Glacial Maximum (LGM). This decrease is concomitant with diminishing amounts of the detrital components in the sediments (Fig. 1). Therefore, both the composition of dissolved Sr, as revealed by results on tests of planktonic foraminifera, and the proportions of suspended terrigenous particulate material arriving at the KC 024-19 site point to a decreasing importance of the contribution of the erosion of the Iberian Variscan crust since the Last Glacial Maximum and in the Holocene. The 87Sr/86Sr ratios measured in tests of benthic foraminifera (C. wuellerstorfi) are more erratic and no correlation can be established with palaeogeographical/palaeoclimatic constraints. The difference between the behaviour of Sr compositions in G. bulloides and C. wuellerstorfi may indicate that whilst the planktonic foraminifera should reproduce very closely the seawater composition, the benthic organisms should, in addition to the major role of seawater, also be affected by some sort of interaction with the sediments. As such, planktonic foraminifera are probably more reliable indicators of seawater composition in studies involving very small periods and corresponding very slight variations of the 87Sr/86Sr ratios. Taking into account that G. bulloides is a common planktonic species (living mostly in the first 50m of the water column), whose tests seem to be in equilibrium with sea water composition, variations in its 87Sr/86Sr ratios can be related with changes in the chemical composition of the water of the Atlantic Ocean off NW Iberian Margin. The highest 87Sr/86Sr values are contemporaneous with a period of low sea level (about -140 m; Dias et al., 2000) during the LGM. According to Dias et al. (2000) at 18 ka BP the shoreline was close to the shelf break. The summital parts of the Gerês and Estrela mountains were covered by local glaciers and close to the coast freezing occurred frequently. The river catchments, which extended far to the shelf, received more rainfall due to a longer, compared to present day conditions, wet season, which promoted both physical and chemical weathering. Higher pluviosity combined with the effect of spring ice melting maintained high river discharge and consequently caused very important sediment supply to the coastal zone. The extremely narrow shelf was a very energetic environment due to sea bottom inclination and very limited long wave refraction. Therefore, at that time, a long wet season and very competent rivers should have caused important erosion of the Variscan basement in NW Iberia. Additionally, then, the shoreline was much closer to the KC 024-19 site. The combination of all these factors favoured an important deposition of terrigenous sediments and the local slight enrichment in radiogenic Sr of the seawater. With sea level rise, after the deglaciation and during the Holocene, the river estuaries became progressively far away from the shelf break. Their competence of transport also became progressively reduced and the offshore transport of detrital sediments became progressively lower. Conversely the biogenic carbonate proportion in the sediments increased, due to lower dilution by the terrigenous particles. Simultaneously, the values of 87Sr/86Sr in the seawater at the KC 024-19 site became lower, as a consequence of a complete homogenization with the ocean global composition, which was now more effective with the increasing distance towards shoreline

Clonagem e expressão do gene bioinseticida TX4(6-1) em sistema heterologo.

bitstream/CNPMS/16145/1/Com_64.pd

Review and analysis of advances in functionalized, smart, and multifunctional asphalt mixtures

Road pavements are designed to withstand road traffic and weathering actions while ensuring comfortable and safe riding conditions as well as low costs and damage to the environment. When a road pavement has additional abilities or reacts to an external stimulus, it is considered to be smart and multifunctional. Examples of such abilities that have been investigated in asphalt mixtures are photocatalytic, superhydrophobic, self-cleaning, de-icing/anti-icing, self-healing, thermochromic, and latent heat thermal energy storage abilities. These abilities are developed using different materials such as nano/microparticles (including semiconductor materials and microcapsules), fibers, phase change materials (PCMs), and dyes, often using dissimilar techniques such as spray coating, volume incorporation, spreading, and asphalt binder modification. Owing to their large surface areas, road pavements are true recipients for large amounts of nano/micromaterials, and consequently, act as important “tools” to stimulate an emerging sector related to the scale of production of materials in the form of nanoparticles. Moreover, smart and multifunctional road pavements can be included in the domain of clean technology (e.g., photocatalytic pavements that promote the environmental depollution of NOx-type gases emitted as vehicle exhaust gases). In this context, they can contribute to materializing the transition to a novel socio-economic model known as “Green Recovery” that is environmentally friendly, sustainable, and inclusive. This model is a very important path toward economic and employment recovery, a vision to which many countries are strongly committed. Therefore, this work reviews new capabilities imparted to asphalt mixtures and provides recommendations.This work was supported by FCT (Fundação para a Ciência e a Tecnologia) under the framework of the Strategic Funding UIDB/04029/2020, UIDB/04650/2020, and UID/FIS/04650/2019, and the PTDC/FIS-MAC/6606/2020, PTDC/FIS/120412/2010, and PEst-OE/ECI/UI4047/2019. The first author would like to acknowledge the FCT for the Ph.D. scholarship (SFRH/BD/137421/2018) and the third author would like to thank CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico - for the PQ 1-D scholarship (308,360/2017–6)

Internal kinematics of spiral galaxies in distant clusters III. Velocity fields from FORS2/MXU spectroscopy

(Abridged) We study the impact of cluster environment on the evolution of spiral galaxies by examining their structure and kinematics. Rather than two-dimensional rotation curves, we observe complete velocity fields by placing three adjacent and parallel FORS2 MXU slits on each object, yielding several emission and absorption lines. The gas velocity fields are reconstructed and decomposed into circular rotation and irregular motions using kinemetry. To quantify irregularities in the gas kinematics, we define three parameters: sigma_{PA} (standard deviation of the kinematic position angle), Delta phi (the average misalignment between kinematic and photometric position angles) and k_{3,5} (squared sum of the higher order Fourier terms). Using local, undistorted galaxies from SINGS, these can be used to establish the regularity of the gas velocity fields. Here we present the analysis of 22 distant galaxies in the MS0451.6-0305 field with 11 members at z=0.54. In this sample we find both field (4 out of 8) and cluster (3 out of 4) galaxies with velocity fields that are both irregular and asymmetric. We show that these fractions are underestimates of the actual number of galaxies with irregular velocity fields. The values of the (ir)regularity parameters for cluster galaxies are not very different from those of the field galaxies, implying that there are isolated field galaxies that are as distorted as the cluster members. None of the deviations in our small sample correlate with photometric/structural properties like luminosity or disk scale length in a significant way. Our 3D-spectroscopic method successfully maps the velocity field of distant galaxies, enabling the importance and efficiency of cluster specific interactions to be assessed quantitatively.Comment: accepted for publication in A&A, high resolution version available at http://www.astro.rug.nl/~kutdemir/papers