Different environmentaly-friendly strategies for loading waterborne polyurethane and polyurethane-urea dispersions

The environmental awareness has increased the research and development of eco-friendly green synthesis routes for many different applications, such as the waterborne polymer systems. Among others, waterborne polyurethanes (WBPU) and waterborne polyurethane-ureas (WBPUU) have gained attention due to their versatility in terms of composition and properties, making them suitable in a wide range of applications [1]. WBPU and WBPUU synthesis process is based on the incorporation of internal emulsifiers covalently bonded to the polymer obtaining stable water dispersions over months. Furthermore, the waterborne character of the dispersions provides the opportunity of incorporating water dispersible nanoentities and water soluble additives, enhancing or even providing additional properties. In this context, the use of renewable derivatives opens the possibility of enhancing the environmentally-friendly character. Among them, cellulose nanocrystals (CNC) are presented as a suitable candidate for the preparation of nanocomposites, considering their unique properties in the nanoscale dimension, provided by their high length/diameter aspect ratio and high specific mechanical properties [2]. Otherwise, the incorporation of natural water soluble additives has focused attention on extracts obtained from plants, consisting in biologically active compounds [3], whose antimicrobial character can determine the antimicrobial behavior of the WBPU and WBPUU. Therefore, in this work, different strategies have been analyzed for the preparation of WBPU-CNC nanocomposites and WBPUU-plant extracts varying their content as well as their incorporation route.info:eu-repo/semantics/publishedVersio

Development of waterborne polyurethane-ureas added with plant extracts: Study of different incorporation routes and their influence on particle size, thermal, mechanical and antibacterial properties

Polyurethane-ureas are a versatile family of polymers which can be employed in a wide range of applications. Among them, waterborne polyurethane-urea (WBPUU) dispersions are gaining relevance in the field of environmentally-friendly products since their productive process adopts green synthesis routes, avoiding the use of organic solvents. Furthermore, their waterborne character can be exploited to incorporate several water compatible ingredients able to confer functional properties to the final materials. Among them, plant extracts, which are known to have relevant bioactivities, can be viewed as interesting candidates. Therefore, in this work, two extracts known to present antimicrobial activity (Melissa officinalis L. and Salvia officinalis L.) were obtained by the infusion method and incorporated into the WBPUU (1, 3 and 5 wt%) following different incorporation routes comprising its adding during different phases of the productive process (post-, in-situ and pre- methods). Thereafter films were prepared by solvent-casting and characterized from the viewpoint of physicochemical, thermal, mechanical, thermomechanical and antibacterial properties and morphologically. The studied incorporation routes resulted in different intercalation mechanisms that varied from extract positioned among the polyurethane-urea nanoparticles (post-method) to extract partially embedded inside them (in-situ and pre-methods), which produced stiffening or flexibilizing effects in the produced films, enhancing in general the antimicrobial characteristics of films after 4 days of incubation comparing with base WBPUU, especially when the extract is embedded.Financial support from the Basque Government (IT-776-13), the Spanish Ministry of Economy and Competitiveness (MINECO) (MAT2016-76294-R), POCI-01-0145-FEDER-006984 (LA LSRE-LCM) funded by ERDF through POCI-COMPETE2020 and FCT and NORTE-01-0145-FEDER-000006, funded by NORTE 2020, under PT2020 through ERDF is gratefully acknowledged. We also wish to acknowledge the “Macrobehaviour- Mesostructure-Nanotechnology” SGIker units from the University of the Basque Country, for their technical support. A.S-E thanks the University of the Basque Country for Ph.D. grant (PIF/UPV/12/201).Financial support from the Basque Government (IT-776-13), the Spanish Ministry of Economy and Competitiveness (MINECO) (MAT2016-76294-R), POCI-01-0145-FEDER-006984 (LA LSRE-LCM) funded by ERDF through POCI-COMPETE2020 and FCT and NORTE- 01-0145-FEDER-000006, funded by NORTE 2020, under PT2020 through ERDF is gratefully acknowledged. We also wish to acknowledge the “Macrobehaviour- Mesostructure-Nanotechnology” SGIker units from the University of the Basque Country, for their technical support. A.S-E thanks the University of the Basque Country for Ph.D. grant (PIF/UPV/12/201).info:eu-repo/semantics/publishedVersio

Convection-parameterized and convection-permitting modelling of heavy precipitation in decadal simulations of the greater Alpine region with COSMO-CLM

Heavy precipitation is a challenging phenomenon with high impact on human lives and infrastructure, and thus a better modelling of its characteristics can improve understanding and simulation at climate timescales. The achievement of convection-permitting modelling (CPM) resolutions (Δx&lt;4 km) has brought relevant advancements in its representation. However, further research is needed on how the very high resolution and switching-off of the convection parameterization affects the representation of processes related to heavy precipitation. In this study, we evaluate reanalysis-driven simulations for the greater Alpine area over the period 2000–2015 and assess the differences in representing heavy precipitation and other model variables in a CPM setup with a grid size of 3 km and a regional climate model (RCM) setup at 25 km resolution using the COSMO-CLM model. We validate our simulations against high-resolution observations (E-OBS (ENSEMBLES observations), HYRAS (Hydrometeorologische Rasterdatensätze), MSWEP (Multi-Source Weighted-Ensemble Precipitation), and UWYO (University of Wyoming)). The study presents a revisited version of the precipitation severity index (PSI) for severe event detection, which is a useful method to detect severe events and is flexible for prioritizing long-lasting events and episodes affecting typically drier areas. Furthermore, we use principal component analysis (PCA) to obtain the main modes of heavy precipitation variance and the associated synoptic weather types (WTs). The PCA showed that four WTs suffice to explain the synoptic situations associated with heavy precipitation in winter, due to stationary fronts and zonal flow regimes. Whereas in summer, five WTs are needed to classify the majority of heavy precipitation events. They are associated with upper-level elongated troughs over western Europe, sometimes evolving into cutoff lows, or with winter-like situations of strong zonal circulation. The results indicate that CPM represents higher precipitation intensities, better rank correlation, better hit rates for extremes detection, and an improved representation of heavy precipitation amount and structure for selected events compared to RCM. However, CPM overestimates grid point precipitation rates, which agrees with findings in past literature. CPM systematically represents more precipitation at the mountain tops. However, the RCMs may show large intensities in other regions. Integrated water vapour and equivalent potential temperature at 850 hPa are systematically larger in RCM compared to CPM in heavy precipitation situations (up to 2 mm and 3 K, respectively) due to wetter mid-level conditions and an intensified latent heat flux over the sea. At the ground level, CPM emits more latent heat than RCM over land (15 W m−2), bringing larger specific humidity north of the Alps (1 g kg−1) and higher CAPE (convective available potential energy) values (100 J kg−1). RCM, on the contrary simulates a wetter surface level over Italy and the Mediterranean Sea. Surface temperatures in RCM are up to 2 ∘C higher in RCM than in CPM. This causes outgoing longwave radiation to be larger in RCM compared to CPM over those areas (10 W m−2). Our analysis emphasizes the improvements of CPM for heavy precipitation modelling and highlights the differences against RCM that should be considered when using COSMO-CLM climate simulations.</p

Effect of the biobased polyols chemical structure on high performance thermoset polyurethane properties

The sustainability of the polymeric materials has become a fundamental challenge; therefore, the development of new biobased formulations has gained increasing interest. Thermoset polyurethanes (PURs) present high performance and are a competitive solution for structural composites. However, polyols used in the PUR synthesis are typically from petrochemical origin. Nowdays, a broad range of biobased polyols is available in the market, but there is not yet a specific formulation for high performance PURs composites. The aim of this work was to study the effect of biobased polyols' characteristics in the PUR processing and final properties. In addition, biobased polyol features to synthesize BIO-PURs suitable for structural applications were stablished. The viscosity and reactivity were studied by means of rheology and differential scanning calorimetry (DSC). Thermal and mechanical properties were studied through thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and flexural tests. The results obtained demonstrated the dramatic influence of polyols’ nature on BIO-PUR/PUR properties and their effect on the crosslink density. It was observed that using a high functionality and high hydroxyl index biobased polyol, it was possible to synthesize high performance BIO-PUR suitable for structural composites.We gratefully acknowledge the Basque Government for the financial support through the ELKARTEK 2021 (Project NEOMAT KK-2021/00059) program and in the frame of Grupos Consolidados (IT-1690-22). The authors also acknowledge the University of the Basque Country (UPV/EHU) in the frame of GIU18/216 Research Group and the Macrobehavior-Mesostructure-Nanotechnology SGIker unit

A quality assurance process of a surface wind database in Eastern Canada

Presentación realizada para las XXXII Jornadas Científicas de la Asociación Meteorológica Española y 13º Encuentro Hispano-Luso de Meteorología celebrados en Alcobendas (Madrid), del 28 al 30 de mayo de 2012

Bacteriostatic ecffect of waterborne polyurethane-ureia films containing bioactive plant extracts incorporated by different routes

The environmental awarenessh as promoted the development of new materiats towards eco-friendty systems based on both,green synthesis processes as well as the renewable origin of the raw compounds. In this way,focusing on synthesis methods, the use of waterborne polyurethane-urea dispersions have gained attention due to their versatility leading to a wide variety of apptications broadening the range of appLications. In addition, it is worth nothing that the dispersibitity in water offers the possibitity of incorporating soluble additives such as plant extracts. Therefore, in this work Melissa officinalis L . ptant was setected in order to obtain bioactive plant extract, in order to be incorporated to a waterborne polyurethane-urea disspersion varying their content as well as using three differernt incorporation routes. These dispersions were characterized and employed in the preparation of films which were analyzed from the viewpoint of physicochemical, thermal and mechanical properties, among others. Finatty, the antibacterial properties of the films were analyzed after 1 and 4 days of incubation. Where it was observed that the content and incorporation route of the extract influenced in the behavior of the films against common pathogens (Staphylococcus aureus, Escherichio coli ond Pseudomonas aeruginosa.info:eu-repo/semantics/publishedVersio

Banbuaren karakterizazio mekanikoa eta kimikoa

The bamboo, a tubular geometry plant, it is a promising replacement of traditional synthetic materials in the construction sector. In addition, it is renewable and environmentally sustainable. However, in order to promote its use, mechanical and chemical properties of bamboo must be known. This work analyses chemical and mechanical characteristics of three bamboo species not used in the construction sector, but widely used for other purposes: Phyllostachys aurea (PA), Arundinaria amabilis (AA) and Dendrocalamus strictus (DS). TAPPI standards have been used for the chemical analysis, while mechanical properties have been studied in compression and three-point flexion tests. The results have shown that the density of bamboo has a direct influence on mechanical properties, both in resistance and stiffness: for the analysed three bamboo species, the higher density the higher resistance and stiffness.; Banbuak, geometria tubularreko landareak, material sintetiko tradizionalen ordezko aukera interesgarriak aurkezten ditu eraikuntzaren sektorerako. Gainera, ingurumenaren aldetik jasangarria eta berriztagarria da. Hala ere, bere erabilera sustatzeko, beharrezkoa da banbuen propietate mekanikoak eta kimikoak ezagutzea. Lan honek gaur egun eraikuntzan ezezagunak diren baina tradizionalki oso erabiliak izan diren hiru espezie aztertzen ditu, kimikoki eta mekanikoki: dendrocalamus strictus (DS), Arundinaria amabilis (AA) eta Phyllostachys aurea (PA). Azterketa kimikorako, TAPPI arauak erabili dira, eta ezaugarri mekanikoak konpresioan eta dinamometroarekin makurdura hiru puntutan neurtuta aztertu dira. Propietate mekanikoen emaitzek erakutsi dute banbuaren dentsitateak eragin zuzena duela bai erresistentzian, bai zurruntasunean. Aztertutako hiru banbu-espezieetan, dentsitatea zenbat eta handiagoa izan, erresistentzia eta zurruntasuna orduan eta handiagoak direla ikusi da

Variabilidad y predictibilidad del viento a escala regional: modelos dinámico y estadístico sobre terreno complejo

Ponencia presentada en: XXXI Jornadas Científicas de la AME y el XI Encuentro Hispano Luso de Meteorología celebrado en Sevilla, del 1 al 3 de marzo de 2010

Banbuaren karakterizazio mekanikoa eta kimikoa

The bamboo, a tubular geometry plant, it is a promising replacement for traditional synthetic materials in the construction sector. In addition, it is renewable and environmentally sustainable. However, in order to promote its use, mechanical and chemical properties of bamboo must be known. This work analyses chemical and mechanical characteristics of three bamboo species not used in the construction sector, but widely used for other purposes: Dendrocalamus strictus (DS), Arundinaria amabilis (AA) and Phyllostachys aurea (PA). TAPPI standards have been used for the chemical analysis, while mechanical properties have been studied in compression and three-point flexion tests. The results have shown that the density of bamboo has a direct influence on mechanical properties, both in resistance and stiffness: for the analysed three bam-boo species, the higher density the higher resistance and stiffness.; Banbua, geometria tubularra duen landarea den aldetik, hautagai interesgarria da eraikuntzaren sektorerako material sintetiko tradizionalen ordezko gisa erabiltzeko. Gainera, iraunkorra eta berriztagarria da ingurumenarekiko arretari dagokionez. Hala ere, haren erabilera sustatzeko, beharrezkoa da dituen propietate mekanikoak eta kimikoak ezagutzea. Lan honek kimikaren eta mekanikaren ikuspegitik aztertzen ditu gaur egun eraikuntzan ezezagunak diren baina tradizionalki oso erabiliak izan diren hiru banbu-espezie: Dendrocalamus strictus (DS), Arundinaria amabilis (AA) eta Phyllostachys aurea (PA). Azterketa kimikorako TAPPI arauak erabili dira, eta ezaugarri mekanikoak konpresioan eta dinamometroa baliatuz makurdura hiru puntutan neurtuta aztertu dira. Propietate mekanikoen emaitzek erakutsi dute banbuaren dentsitateak eragin zuzena duela bai erresistentzian eta bai zurruntasunean. Aztertutako hiru banbu espezieetan, dentsitatea zenbat eta handiagoa izan, erresistentzia eta zurruntasuna handiagoak direla ikusi da