Local atomic arrangement and martensitic transformation in Ni50_{50}Mn35_{35}In15_{15}: An EXAFS Study

Heusler alloys that undergo martensitic transformation in ferromagnetic state are of increasing scientific and technological interest. These alloys show large magnetic field induced strains upon martensitic phase change thus making it a potential candidate for magneto-mechanical actuation. The crystal structure of martensite is an important factor that affects both the magnetic anisotropy and mechanical properties of such materials. Moreover, the local chemical arrangement of constituent atoms is vital in determining the overall physical properties. Ni$_{50}$Mn$_{35}$In$_{15}$ is one such ferromagnetic shape memory alloy that displays exotic properties like large magnetoresistance at moderate field values. In this work, we present the extended x-ray absorption fine-structure measurements (EXAFS) on the bulk Ni$_{50}$Mn$_{35}$In$_{15}$ which reveal the local structural change that occurs upon phase transformation. The change in the bond lengths between different atomic species helps in understanding the type of hybridization which is an important factor in driving such Ni-Mn based systems towards martensitic transformation

Anomalous Magnetic Properties in Ni50Mn35In15

We present here a comprehensive investigation of the magnetic ordering in Ni50Mn35In15 composition. A concomitant first order martensitic transition and the magnetic ordering occurring in this off-stoichiometric Heusler compound at room temperature signifies the multifunctional character of this magnetic shape memory alloy. Unusual features are observed in the dependence of the magnetization on temperature that can be ascribed to a frustrated magnetic order. It is compelling to ascribe these features to the cluster type description that may arise due to inhomogeneity in the distribution of magnetic atoms. However, evidences are presented from our ac susceptibility, electrical resistivity and dc magnetization studies that there exists a competing ferromagnetic and antiferromagnetic order within crystal structure of this system. We show that excess Mn atoms that substitute the In atoms have a crucial bearing on the magnetic order of this compound. These excess Mn atoms are antiferromagnetically aligned to the other Mn, which explains the peculiar dependence of magnetization on temperature.Comment: Accepted in J. Phys. D.:Appl. Physic

Resistivity and Thermopower of Ni2.19Mn0.81Ga

In this paper, we report results of the first studies on the thermoelectric power (TEP) of the magnetic heusler alloy Ni$_{2.19}$Mn$_{0.81}$Ga. We explain the observed temperature dependence of the TEP in terms of the crystal field (CF) splitting and compare the observed behavior to that of the stoichiometric system Ni$_2$MnGa. The resistivity as a function of temperature of the two systems serves to define the structural transition temperature, T$_M$, which is the transition from the high temperature austenitic phase to low temperatures the martensitic phase. Occurrence of magnetic (Curie-Weiss) and the martensitic transition at almost the same temperature in Ni$_{2.19}$Mn$_{0.81}$Ga has been explained from TEP to be due to changes in the density of states (DOS) at the Fermi level.Comment: 12 pages, 4 figures, Accepted in Physical Review B vol 70, Issue 1

Role of Ni-Mn hybridization in magnetism of martensitic state of Ni-Mn-In shape memory alloys

Extended X-ray Absorption Fine Structure (EXAFS) studies on Ni$_{50}$Mn$_{25+x}$In$_{25-x}$ have been carried out at Ni and Mn K edge as a function of temperature. Thermal evolution of nearest neighbor Ni-Mn and Mn-Mn bond distances in the martensitic phase give a clear evidence of a close relation between structural and magnetic degrees of freedom in these alloys. In particular, the study highlights the role of Ni 3d - Mn 3d hybridization in the magnetism of martensitic phase of these alloys.Comment: Accepted for publication in EP

Reduction of Cd(II)-Itaconate & Cd(II)-Oxalate-Itaconate Complexes at d.m.e.

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Correlation between Local Structure Distortions and Martensitic Transformation in Ni-Mn-In alloys

The local structural distortions arising as a consequence of increasing Mn content in Ni_2Mn_1+xIn_1-x (x=0, 0.3, 0.4, 0.5 and 0.6) and its effect on martensitic transformation have been studied using Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. Using the room temperature EXAFS at the Ni and Mn K-edges in the above compositions, the changes associated with respect to the local structure of these absorbing atoms are compared. It is seen that in the alloys exhibiting martensitic transformation ($x \ge 0.4$) there is a significant difference between the Ni-In and Ni-Mn bond lengths even in the austenitic phase indicating atomic volume to be the main factor in inducing martensitic transformation in Ni-Mn-In Heusler alloys.Comment: 8 pages, 2 figure

Local Atomic Structure of Martensitic Ni2+x_{2+x}Mn1−x_{1-x}Ga: An EXAFS Study

The local atomic structure of Ni$_{2+x}$Mn$_{1-x}$Ga with 0 $\le$ $x$ $\le$ 0.16 alloys was explored using Mn and Ga K-edge Extended X-ray Absorption Fine Structure (EXAFS) measurement. Inorder to study the atomic re-arrangements that occur upon martensitic transformation, room temperature and low temperature EXAFS were recorded. The changes occurring in the L2$_1$ unit cell and the bond lengths obtained from the analysis enables us to determine the modulation amplitudes over which the constituent atoms move giving rise to shuffling of the atomic planes in the modulated structure. The EXAFS analysis also suggests the changes in hybridization of Ga-$p$ and Ni-$d$ orbitals associated with the local symmetry breaking upon undergoing martensitic transition.Comment: Accepted for publication in Physical Review