1,475 research outputs found
Radical Fluoroalkylation Reactions
Recent protocols and reactions for catalytic radical perfluoroalkylations will be described. The production of perfluoroalkyl radicals (RF = CnF2n+1, n â„ 2), which effect both addition and substitution reactions on organic substrates, can be realized through a range of diverse methods such as the well-established visible-light transition-metal-mediated photocatalysis, organic-dye-photocatalyzed reactions, electron donor-acceptor complexes, and more recently frustrated Lewis pairs. Thus, perfluoroalkylation reactions of carbon-carbon multiple bonds, isocyanides, nitrones, hydrazones, ÎČ-keto esters, α-cyano arylacetates, sulfides, and (hetero)arenes will be described. Special emphasis will be placed on examples published after 2015, where higher fluorinated series of fluoroalkylating reagents are studied.Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y BioquĂmica. Departamento de QuĂmica OrgĂĄnica; Argentina. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas; ArgentinaFil: Cooke, MarĂa Victoria. Universidad de Buenos Aires. Facultad de Farmacia y BioquĂmica. Departamento de QuĂmica OrgĂĄnica; Argentina. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas; ArgentinaFil: Postigo, A.. Universidad de Buenos Aires. Facultad de Farmacia y BioquĂmica. Departamento de QuĂmica OrgĂĄnica; Argentin
The GRB 030328 host: another case of a blue starburst galaxy
We present for the first time the detection of the GRB 030328 host galaxy in
four optical bands equivalent to UBRI. The host galaxy spectral energy
distribution is consistent with a low extinction (E(B-V) < 0.21) starburst
galaxy. The restframe B-band magnitude of the host is M_B ~ -20.4Comment: 4 pages, 2 figures, accepted for publication in Il nuovo cimento (4th
Workshop Gamma-Ray Bursts in the Afterglow Era, Rome, 18-22 October 2004
Reliable channel-adapted error correction: Bacon-Shor code recovery from amplitude damping
We construct two simple error correction schemes adapted to amplitude damping noise for Bacon-Shor codes and investigate their prospects for fault-tolerant implementation. Both consist solely of Clifford gates and require far fewer qubits, relative to the standard method, to achieve correction to a desired order in the damping rate. The first, employing on
Reliable channel-adapted error correction: Bacon-Shor code recovery from amplitude damping
We construct two simple error correction schemes adapted to amplitude damping noise for Bacon-Shor codes and investigate their prospects for fault-tolerant implementation. Both consist solely of Clifford gates and require far fewer qubits, relative to the standard method, to achieve exact correction to a desired order in the damping rate. The first, employing one-bit teleportation and single-qubit measurements, needs only one-fourth as many physical qubits, while the second, using just stabilizer measurements and Pauli corrections, needs only half. The improvements stem from the fact that damping events need only be detected, not corrected, and that effective phase errors arising due to undamped qubits occur at a lower rate than damping errors. For error correction that is itself subject to damping noise, we show that existing fault-tolerance methods can be employed for the latter scheme, while the former can be made to avoid potential catastrophic errors and can easily cope with damping faults in ancilla qubits
Confined photon modes with triangular symmetry in hexagonal microcavities in 2D photonic Crystals
We present theoretical and experimental studies of the size and thickness
dependencies of the optical emission spectra from microcavities with hexagonal
shape in films of two-dimensional photonic crystal. A semiclassical plane-wave
model, which takes into account the electrodynamic properties of quasi-2D
planar photonic microcavity, is developed to predict the eigenfrequencies of
the confined photon modes as a function of both the hexagon-cavity size and the
film thickness. Modes with two different symmetries, triangular and hexagonal,
are critically analyzed. It is shown that the model of confined photon modes
with triangular symmetry gives a better agreement between the predicted
eigenmodes and the observed resonances.Comment: 14 pages, 6 figure
A young stellar environment for the superluminous supernova PTF12dam
The progenitors of super luminous supernovae (SLSNe) are still a mystery.
Hydrogen-poor SLSN hosts are often highly star-forming dwarf galaxies and the
majority belongs to the class of extreme emission line galaxies hosting young
and highly star-forming stellar populations. Here we present a resolved
long-slit study of the host of the hydrogen-poor SLSN PTF12dam probing the kpc
environment of the SN site to determine the age of the progenitor. The galaxy
is a "tadpole" with uniform properties and the SN occurred in a star-forming
region in the head of the tadpole. The galaxy experienced a recent star-burst
superimposed on an underlying old stellar population. We measure a very young
stellar population at the SN site with an age of ~3 Myr and a metallicity of
12+log(O/H)=8.0 at the SN site but do not observe any WR features. The
progenitor of PTF12dam must have been a massive star of at least 60 M_solar and
one of the first stars exploding as a SN in this extremely young starburst.Comment: submitted to MNRAS letters. 5 pages, 3 figures, supplementary
material: 2 figures, 2 table
Multi-wavelength analysis of the field of the dark burst GRB 031220
We have collected and analyzed data taken in different spectral bands (from
X-ray to optical and infrared) of the field of GRB031220 and we present results
of such multiband observations. Comparison between images taken at different
epochs in the same filters did not reveal any strong variable source in the
field of this burst. X-ray analysis shows that only two of the seven Chandra
sources have a significant flux decrease and seem to be the most likely
afterglow candidates. Both sources do not show the typical values of the R-K
colour but they appear to be redder. However, only one source has an X-ray
decay index (1.3 +/- 0.1) that is typical for observed afterglows. We assume
that this source is the best afterglow candidate and we estimate a redshift of
1.90 +/- 0.30. Photometric analysis and redshift estimation for this object
suggest that this GRB can be classified as a Dark Burst and that the
obscuration is the result of dust extinction in the circum burst medium or
inside the host galaxy.Comment: 7 pages, 5 figures, accepted for publication on A&
Active Transcriptional Repression by the RbâE2F Complex Mediates G1 Arrest Triggered by p16INK4a, TGFÎČ, and Contact Inhibition
AbstractRb inhibits progression from G1 to S phase of the cell cycle. It associates with a number of cellular proteins; however, the nature of these interactions and their relative significance in cell cycle regulation are still unclear. We present evidence that Rb must normally interact with the E2F family of transcription factors to arrest cells in G1, and that this arrest results from active transcriptional repression by the RbâE2F complex, not from inactivation of E2F. Thus, a major role of E2F in cell cycle regulation is assembly of this repressor complex. We demonstrate that active repression by RbâE2F mediates the G1 arrest triggered by TGFÎČ, p16INK4a, and contact inhibition
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